Production of light superpartners in π0 radiative decays

The production rate of light photinos in radiative pion decay \(\pi ^0 \to \gamma \tilde \gamma \tilde \gamma\) is calculated. Experimental constraints on masses and mass splittings of scalar quarks imply the following upper bound on the decay rate \(BR(\pi ^0 \to \gamma \tilde \gamma \tilde \gamma ) \lesssim 10^{ - 16}\) .     

Pseudo-cross-conjugated mesomeric betaines. 1. Synthesis of pseudo-cross-conjugated mesomeric betaines from quinoxaline derivatives

A new method for the synthesis of pseudo-cross-conjugated mesomeric betainic heterocyclic compounds with an angular nitrogen atom has been developed consisting in the reaction of 1,4-dielectrophile — -carbethoxy-2-(3-chloro)quinoxalylacetonitrile with azoles. Experimental regularities have been studied and a reaction mechanism has been proposed including the stage of formation of an ylide from a quaternary azolium salt. A pseudo-crossconjugated mesomeric betainic heterocyclic compound containing a thiazole ring compound has been synthesized for the first time.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1528–1533, November, 1992.     

Synthesis and photochemical properties of the indoline series fulgides

Using the Stobbe condensation fulgides that undergo E, Z-isomerization on exposure to UV radiation are obtained from diethyl [2-(1,3,3-trimethyindoline-2-ilidene)ethylidene]succinate, and benzaldehyde and its derivatives; and from 1,2-dimethyl-3-formylindole and -formyl-1,3,3-trimethyl-2-methyleneindoline. The structure and photochemical changes of the fulgides were investigated by means of PMR.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 55–60, January, 1992.     

Radiative decays of ρ and ω mesons

The results of the measurements of radiative decays of ρ and ω mesons with the Neutral Detector at thee ⁺ e ^? collider VEPP-2M are presented. The branching ratio of the decay ω→π ⁰γ was measured with higher than in previous experiments accuracy: $${\rm B}(\omega \to \pi ^0 \gamma ) = 0.0888 \pm 0.0062$$ . The ρ⁰→π ⁰ γ branching ratio was measured for the first time: $$B(\rho ^0 \to \pi ^0 \gamma ) = (7.9 \pm 2.0) \cdot 10^{ - 4} $$ . The decays ρ, ω→ηγ were studied. Their branching ratios with the assumption of constructive ρ?ω interference are: $$\begin{gathered} B(\omega \to \eta \gamma ) = (7.3 \pm 2.9) \cdot 10^{ - 4} , \hfill \\ B(\rho \to \eta \gamma ) = (4.0 \pm 1.1) \cdot 10^{ - 4} \hfill \\ \end{gathered} $$ . The branching ratios of ρ, ω→ηγ and ω→e ⁺ e ^? decays were also measured: $$\begin{gathered} B(\omega \to \pi ^ + \pi ^ - \pi ^0 ) = 0.8942 \pm 0.0062, \hfill \\ B(\omega \to e^ + e^ - ) = (7.14 \pm 0.36) \cdot 10^{ - 5} \hfill \\ \end{gathered} $$ . The upper limit for the ω→π ⁰ π ⁰ γ branching ratio was placed: B(ω→π ⁰ π ⁰ γ)<4·10^?4 at 90% confidence level.     

Forward-backward multiplicity correlations in σ+ p,K + p andpp collisions at 250 GeV/c

Forward-backward multiplicity correlations in σ⁺,K ⁺ p andpp collisions at 250 GeV/c ( \(\sqrt s \) =22 GeV) are given for all charges and for the different charge combinations. The correlations are found to be caused predominantly by centrally produced particles. It is demonstrated that this result is an agreement with observations at the ISR and the CERNp \(\bar p\) -Collider. The results are compared to expectations from LUND, DPM and FRITIOF Monte Carlo models and a geometrical picture relating correlations in hadron-hadron collisions toe ⁺ e ^? data in terms of impact parameters is tested.     

异烟肼及其代谢产物的串联质谱分析

报道了血样中异烟肼的串联质谱快速分析，利用这种分析方法，证实了一男性死者血样中异烟肼及其代谢产物的存在，从而为法庭诉讼提供了可靠的证据。这种方法具有快速性，高灵敏度和高选择性，适合于需要快速分析的场合。     

XPS investigations of ink‐jet printed paper

Different ink‐jet printed paper materials were investigated using X‐ray photoelectron spectroscopy (XPS) yielding the elemental composition of the near‐surface region of the papers. We found significant differences with respect to the detected elements and their atomic concentrations in the different inks studied here. Two different groups of inks could be identified by means of a lower ratio of the O and C atomic concentrations and lower concentrations in specific trace elements like Mg, Na and Si. High‐resolution spectra of C 1s and O 1s core levels allowed a detailed determination of the chemical state of the respective elements. On the basis of a detailed deconvolution of these XPS signals, significant differences between all the investigated ink‐jet printed papers were found, thereby allowing their discrimination. The applicability of the measurements and, more generally, the XPS technique for forensic investigations of paper are discussed. Copyright © 2007 John Wiley & Sons, Ltd.     

3, 3, 3-Trifluoropropyl(methyl)cyclosiloxanes

The influence of the number of 3, 3, 3-trifluoropropyl(methyl)siloxane links (/) in the cyclotetrasiloxanes _mD_4-m, where D represents the dimethylsiloxane link and m=0–4, on the rearrangement of these compounds in acetone solution under the action of sodium siloxanolate has been studied. The rearrangement takes place with the formation of a linear polysiloxane the degradation of which yields, in addition to the initial ring, cyclosiloxanes with a different structure. The rate of rearrangement of _mD_4-m and of the formation of a linear polysiloxane rises with an increase in m from 0 to 3. The equilibrium concentration of the linear polysiloxane formed from _mD_4-m is inversely proportional to m. Results have been obtained on the kinetics of the formation of the cyclosiloxanes _mD_n, where m=0–5, n=0–5, and m+n=3–6, in the rearrangement of the rings D₃, ₂D₂, ₃D, and ₄. The reactivity of the siloxane links rises in the sequence (CH₃)₂Si-O-Si(CH₃)₂ < (CF₃CH₂CH₂)-(CH₃) Si-O-Si(CH₃)₂ <(CF₃CH₂CH₂) (CH₃)Si-O-Si(CH₃) (CH₂CH₂CF₃) . Because of the negative inductive effect transferred through the siloxane links, the 3, 3, 3-trifluoropropyl groups strongly activate the siloxane ring with respect to nucleophiiic reagents.For part I, see [3].     

微波常压法合成水杨酸酯

在浓硫酸催化下，采用微波常压法由水杨酸分别与正丁醇、异丁醇、正戊醇和异戊醇反应合成相应的水杨酸酯。结果表明：当水杨酸：醇：Ｈ２ＳＯ４＝１：５．５：０．３（摩尔比）时，采用５６０Ｗ微波辐射２２ｍｉｎ，水杨酸酯的产率可达８８．７％￣９６．４％，反应速度至少是常规反应的１４倍。