Fe掺杂Mn/TiO2低温脱硝催化剂的催化性能研究

采用氧化沉淀-浸渍法制备了不同含量Fe掺杂的Fe-Mn/TiO2低温脱硝催化剂,考察了催化剂在80~180 ℃范围内的脱硝能力并通过XRD、BET、TG、H2-TPR、NH3-TPD等测试手段,对催化剂的物理化学性质进行了表征.实验结果表明,Fe的加入并没有改变Mn/TiO2的主要晶相,仍是锐钛矿型的TiO2,MnOx和FeOx均以非晶态结构高度分散于载体表面,而且Fe的加入可以有效地改善催化剂的微观形貌、比表面积及表面酸性位点,从而提高其低温脱硝性能.Fe掺量在Fe/Ti为0.10时催化剂具有最佳性能,在120 ℃时脱硝率可达90;以上.     

Characterization of beam-induced reactions occurring in liquid secondary ion mass spectrometry/fast-atom bombardment by tandem mass spectrometry

Department of General and Physical Chemistry, University of Liege, Liege, Belgium A specific beam-induced secondary reaction involving the condensation of hydroxylic matrices with some organic groups (aldehydes, ketones, etc.) accompanied by the loss of a water molecule was investigated by liquid secondary ion mass spectrometry/fast-atom bombardment (LSIMS/FAB). A mechanistic scheme and a structure of the induced product are proposed. The features of this secondary reaction were studied and the influence of the types of solutes, acidic additives, and matrices analyzed. Rather than a drawback, LSIMS/FAB mass spectrometry can take advantage of this matrix effect to infer analytical information through tandem mass spectrometry experiments. Specific neutral loss scans can be conducted to highlight beam-induced reactive molecules, even when the detection of these species is prevented in normal scan spectra by other surface-active components.     

Laser pulse fluorometry as a tool in polymer research

A time-resolved fluorescence spectrometer with laser excitation and picosecond time-correlated single photon counting detection is described. The parameter recovery from experimental data is discussed in detail. Correction methods for errors in the time-correlated single photon counting technique are indicated. Applications of this photophysical tool to polymer research are given.     

The Second Noether Theorem in the formalism of jet-bundles: Symmetries and degeneration

By means of the jet-bundle formalism, the Second Noether Theorem is formulated for a general first-order Lagrangian field theory with infinitesimal local symmetries. These symmetries are implemented by a linear differential operator acting between the sections of a vector bundle and vector fields on the configuration bundle. The problem of the degeneration of the Lagrangian system is examined from a covariant and an instantaneous (i.e. space+time split) viewpoint. It is shown that in the instantaneous approach the presence of infinitesimal local symmetries leads to degeneration of the theory. Vertical local symmetries are shown to imply degeneration also in the covariant formalism. These results can be extended to higher-order Lagrangians as well.     

In vivo 1H-NMR procedure to determine several rat cerebral metabolite levels simultaneously, undisturbed by water and lipid signals

Methods developed for in vivo 1H-NMR spectroscopy are evaluated and applied using conscious rats. Good quality 1H-spectra of the brain are obtained using a surface coil and a spin echo pulse sequence with the binomial 1-1 and 2-2 water suppression pulses. However, comparing spectra from various rats with each other the water and lipid signals, which cause spectral overlap problems, may differ while the other spectral peaks agree well. Spatially one- and two-dimensional 1H spectroscopic imaging of the rat brain shows that the former signals stem from distinct spatial regions localized close to the rf coil. From a spectroscopic image, a spectrum over a limited spatial region is constructed in which the water signals are strongly reduced, the lipid signals are eliminated and lactic acid can be observed clearly simultaneously with other metabolites.     

三类有向三元系之间关系的一种猜想

一个Mendelsohn (Directed, 或Hybrid)三元系 MTS$(v, \lambda)$~(DTS$(v, \lambda)$,或HTS$(v,\lambda))$, 是由$v$元集$X$ 上的一些循环（可迁,或循环和可迁）三元组(简称区组)构成的集合${\cal B}$, 使得$X$上每个由不同元素组成的有序对都恰在 ${\cal B}$的$\lambda$个区组中出现.本文主要讨论了这三类有向三元系之间的一种关联关系,给出猜想：任意MTS$(v,\lambda)$的区组关联图$G(\     

一类具有阶段结构和时滞的非自治捕食系统

本文研究一类具有阶段结构和时滞的非自治捕食系统解的渐近性质 ,在适当条件下 ,得到系统是持续生存的且全局渐近稳定的     

利用三角形及其九点圆的摄像机标定

提出基于三角形及其九点圆的摄像机标定方法.利用了三角形九点圆中其九个点的特殊性,并且利用透视投影变换保二次曲线不变性,得到其像点在像平面共椭圆,从而可以通过九点的映射关系将透视投影变换的非线性问题线性化.图像分割和角点提取的误差会直接影响标定的精度,在此三角形及其九点圆中的点特别是算法中的关键点三角形顶点和垂心都是三条直线的交点,减小图像分割与提取时造成的误差.DLT方法的不精确就源于图像分割和角点提取的误差,方法克服了DLT方法的不足.张的方法无法保证单应性矩阵的正交性,因此为了保证正交性和提高精度需要优化.与传统方法相比操作简单,应用九点圆定理,仿射变换的引入将透视投影非线性问题线性化,避免了参数之间的非线性方程求解,降低了参数求解的复杂性,因此其定标过程快捷,准确.模板的构造,减少了图像分割和交点提取误差,算法实现保证旋转矩阵的正交性.综合上述分析,理论上表明方法的有效性.同时实验表明,标定方法操作简单,不需要计算机视觉的专业知识,快速,精度高,鲁棒性好.     

拓扑线性空间中的Drop定理和Phelps引理以及Ekeland变分原理

将Phelps引理,Ekland变分原理,Pareto有效性定理推广到拓扑线性空间,同时证明了这三个定理与郑喜印证明的拓扑线性空间中的Drop定理彼此等价.