Simultaneous Densitometric TLC Analysis of Olmesartan Medoxomil and Hydrochlorothiazide in the Tablet Dosage Form

JPC – Journal of Planar Chromatography – Modern TLC - A simple, rapid, and selective densitometric thin-layer chromatographic (TLC) method has been established and validated for...     

Parallelizing Tabu Search on a Cluster of Heterogeneous Workstations

In this paper, we present the parallelization of tabu search on a network of workstations using PVM. Two parallelization strategies are integrated: functional decomposition strategy and multi-search threads strategy. In addition, domain decomposition strategy is implemented probabilistically. The performance of each strategy is observed and analyzed. The goal of parallelization is to speedup the search in finding better quality solutions. Observations support that both parallelization strategies are beneficial, with functional decomposition producing slightly better results. Experiments were conducted for the VLSI cell placement, an NP-hard problem, and the objective was to achieve the best possible solution in terms of interconnection length, timing performance (circuit speed), and area. The multiobjective nature of this problem is addressed using a fuzzy goal-based cost computation.     

Electrodialysis performance when recycling dilute nickel solutions directly into a plating bath

This work was performed to determine membrane performance characteristics when using low current electrodialysis to recover and recycle nickel (salts) from dilute waste waters. Results showed that nickel at typical plating rinse concentrations (3000 p.p.m.) can be transferred electrically across commercially available membranes, and directly into a concentrated Watt's nickel plating bath (72,000 p.p.m.). Recovery at approximately 90% current efficiency was possible at current densities as low as 3.0 mA/cm². Nickel and co-transported water were routinely recycled as a relatively concentrated solution which would not cause dilution, since it was well above plating bath strength at all but the lowest current densities.     

Mn55(p,p′γ)Mn55 reaction low proton energies

Angular distributions of gamma rays following the inelastic scattering of protons from Mn⁵⁵ have been measured at proton energies below 2.50 MeV. The mixture multipole orders for the transition 983→126 keV and 1,530→0 in Mn⁵⁵ have been obtained.     

X-ray detected magnetic resonance at the Fe K-edge in YIG: Forced precession of magnetically polarized orbital components

X-ray detected magnetic resonance (XDMR) has been measured for the first time on exciting the Fe K-edge in a high-quality yttrium iron garnet film epitaxially grown on a gadolinium gallium garnet substrate. This challenging experiment required resonant pumping of yttrium iron garnet at high microwave power, i.e., in the foldover regime. X-ray magnetic circular dichroism (XMCD) was used to probe the change in the longitudinal component of the magnetization M _Z induced by the precession of magnetic moments located at the iron sites. Since XMCD at the Fe K-edge refers mostly to the equilibrium contribution of magnetically polarized 4p orbital components, XDMR at the Fe K-edge should reflect the precessional dynamics of the latter orbital moments. From the measured precession angle, we show that there is no dynamical quenching of the polarized orbital components at the iron sites in yttrium iron garnet.     

PtCl2-catalyzed cycloisomerizations of 5-en-1-yn-3-ol systems

5-En-1-yn-3-ol substrates bearing a free hydroxyl group or an acyl group are highly versatile partners for PtCl2-catalyzed cycloisomerizations. Electrophilic activation of the alkyne moiety triggers at wish a hydride or an O-acyl migration yielding at the end to regioisomeric keto derivatives. The efficient preparation of Sabina ketone, an important monoterpene precursor, has been worked out.     

Hypericin and Pseudohypericin. Purity Criteria and Quantitative Determination in Extracts of Saint John’s Wort (Hypericum perforatum)

Summary. Hypericin and pseudohypericin in extracts of St. Johns Wort (Hypericum perforatum) are assayed using UV-Vis, measuring the absorbance at 588nm of a methanolic solution of the compounds. The value of the absorption coefficient is difficult to define insofar as none of the routine purity criteria can be applied to these two compounds. Analysis of the entire UV-Vis spectrum from 220 to 740nm would seem to be a reliable way of comparing different samples. A UV-Vis spectrum was recorded for each of the compounds using a Photodiode array detection system. A more accurate way of determining the levels of hypericin and pseudohypericin in extracts of St. Johns Wort using these reference spectra is described.     

Non-linear actuation of cantilevers using giant magnetostrictive thin films

In the present paper, we report the first results concerning a centimetre cantilever driven through non-linear effects in thin magnetostrictive films. Bimorph centimetre beams (24 mm x 5 mm) were designed using 160 microns thick glass and 0.4 micron thick multilayer TbFe/Fe films deposited via RF sputtering, using several sputtering conditions. Dynamic magneto-elastic excitations were studied experimentally on the few eigenresonance modes of the cantilevers. Sub-harmonic excitation at half or one-third of the frequency of an eigenresonance mode has been achieved near the spin reorientation transition and the efficiency is as good as for eigenfrequency excitation. Specific magnetic properties of the samples led to a model of the thermodynamic potentials and behaviour of the excited resonator.     

Multiscale hygroviscoelastic approach to predicting the internal stresses in composite materials

A self-consistent approach is used to estimate the internal stresses induced by moisture absorption in composite materials with a viscoelastic matrix and linear elastic fibers. A strong influence of the behavior of the viscoelastic matrix and humidity on the internal stresses in the structures at macroscopic and local scales is found to exist.     

Two-dimensional problem of a two-temperature generalized thermoelastic half-space subjected to ramp-type heating

In this work, we will consider a half-space filled with an elastic material, which has constant elastic parameters. The governing equations are taken in the context of the theory of two-temperature generalized thermoelasticity. A linear temperature ramping function is used to more realistically model thermal loading of the half-space surface. The medium is assumed initially quiescent. Laplace and Fourier transform techniques are used to obtain the general solution for any set of boundary conditions. The general solution obtained is applied to a specific problem of a half-space subjected to ramp-type heating. The inverse Fourier transforms are obtained analytically while the inverse Laplace transforms are computed numerically using a method based on Fourier expansion techniques. Some comparisons have been shown in figures to estimate the effect of the ramping parameter of heating.