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Reisdorf W Andronic A Gobbi A Hartmann ON Herrmann N Hildenbrand KD Kim YJ Kirejczyk M Koczoń P Kress T Leifels Y Schüttauf A Tymiński Z Xiao ZG Alard JP Barret V Basrak Z Bastid N Benabderrahmane ML Caplar R Crochet P Dupieux P Dzelalija M Fodor Z Grishkin Y Hong B Kecskemeti J Korolija M Kotte R Lebedev A Lopez X Merschmeyer M Mösner J Neubert W Pelte D Petrovici M Rami F de Schauenburg B Seres Z Sikora B Sim KS Simion V Siwek-Wilczyńska K Smolyankin V Stockmeier M Stoicea G Wagner P 《Physical review letters》2004,92(23):232301
We present a complete systematics (excitation functions and system-size dependences) of global stopping and side flow for heavy ion reactions in the energy range between 0.09A and 1.93A GeV. For the heaviest system, Au+Au, we observe a plateau of maximal stopping extending from about 0.2A to 0.8A GeV with a fast drop on both sides. The degree of stopping, which is shown to remain significantly below the expectations of a full stopping scenario, is found to be highly correlated to the amount of side flow. 相似文献
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Więckowska Anna Bajda Marek Więckowski Krzysztof Malawska Barbara 《平面色谱法杂志一现代薄层色谱法》2010,23(5):359-364
JPC – Journal of Planar Chromatography – Modern TLC - This paper reports an investigation of physicochemical properties of four series of carbamates of 3-hydroxy and... 相似文献
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Joanna Wiśniewska Hasan Marai Andrzej Karocki Konrad Szaciłowski Ewa Kita Zofia Stasicka 《Journal of photochemistry and photobiology. A, Chemistry》2010,209(2-3):121-127
Irradiation of chromium(III) complexes with oxalate and pyridinedicarboxylate ligands (pda = 2,3-, 2,4-, or 2,5-dicarboxylate) leads to diverse behaviors, dictated by light energy, presence of oxygen and the ligand nature. Irradiation within the MC bands is unaffected by O2 and results in ligand substitution. The LMCT excitation is effective only when oxalate is coordinated to Cr(III); then electron transfer from oxalate to central ion generates an intermediate, consisted of a Cr(II)species and the C2O4? radicals. The species undergo fast redox reactions dependent on the presence of O2 and the pda ligand.(1) In anoxic medium the fast outersphere electron transfer from Cr(II) to solvent, generates hydrated electrons and re-oxidizes the chromium centre to CrIII. Then geminate recombination regenerates substrate, whereas competitive release of the C2O4? radical leads to substitution of one oxalate ligand by two water molecules (aquation induced by the LMCT excitation). In the presence of the pda ligand the outersphere electron transfer is accompanied by the innersphere CT, generating Cr(III) coordinated to two radical ligands: C2O4? and pda3?; the intermediate releases also eaq?, but this reaction is slower than that of the homoleptic oxalate complex. Hydrated electrons are scavenged also by the released radicals. All these processes are completed within microseconds and in consequence, the Cr(III) complexes irradiated in deoxygenated solutions are insensitive to subsequent oxygenation.(2) When UV-irradiation is carried out in oxygenated medium reaction of Cr(II) species with molecular oxygen competes with the outer- or inner electron transfer observed in anoxic medium. Both these pathways result in generation of chromate(VI). Quantum yield of the Cr(VI) production is sensitive to the presence and structure of pda ligand, decreasing within the series 2,3-pda > 2,4-pda > 2,5-pda. 相似文献
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A solid-state rotational-echo double resonance (REDOR) NMR method was introduced to identify the ?- and ψ-torsion angle from a 1H–15N or 1H–13C′ spin system of alanine-like residues in a selectively, uniformly, or extensively 15N-/13C-labeled peptide. When a Cα(i) or a 15N peak is site-specifically obtainable in the NMR spectrum of a uniformly 15N/13C-labeled sample system, the ψ- or ?-torsion angle specified by the conformational structure of peptide geometry involving 15N(i)–1Hαi–15N(i + 1) or 13C′(i − 1)–1HNi–13C′(i) spin system can be identified based on 13Cα- or 15N-detected 1Hα–15N or 1HN–13C REDOR experiment. This method will conveniently be utilized to identify major secondary motifs, such as α-helix, β-sheet, and β-turn, from a uniformly 15N-/13C-labled peptide sample system. When tested on a 13C-/15N-labeled model system of a three amino acid peptide Gly–[U–13C, 15N]Ala–[U–13C, 15N]Leu, the ψ-angle of alanine obtained experimentally, ψ = −40 ± 30°, agreed reasonably well with the X-ray determined angle, ψ = −39°. 相似文献
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Okunev VD Samoilenko ZA Szewczyk A Szymczak R Szymczak H Lewandowski SJ Aleshkevych P Wi?ckowski J Khmelevskaya VS Antoshina IA 《J Phys Condens Matter》2011,23(41):415702
We have reinforced local superconductivity in ferromagnetic Fe(67)Cr(18)B(15) metallic glasses by ion irradiation. Superconductivity in this medium appears due to the presence of large-scale layered clusters of metallic Fe-Cr phase, 150-230 ? in size, with a ferromagnetic (or superparamagnetic) Fe-rich core and nonmagnetic Cr-rich superconducting shell. Here we show that due to the intensification of concentration phase separation in the Fe-Cr clusters under ion (Ar(+)) irradiation, the volume of the superconducting phase increases from the initial 0.4-0.5% up to 7-8%. After irradiation, the resistivity jump Δρ/ρ in the temperature range T=3.1-3.6 K increases ~14 times, reaching 19%, as compared to 1.36% for the initial sample. In the interval of T=3.1-3.6 K, the rate of resistance change reaches 79% K(-1) for the irradiated sample instead of 3.6% K(-1) for the initial sample. In the same temperature interval, the rate of magnetoresistance change increases from 3% K(-1) for the initial sample up to 70% K(-1) after irradiation. 相似文献
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Youngjin Bae 《Israel Journal of Mathematics》2014,204(1):417-430
We study the growth rate of a sequence which measures the uniform norm of the differential under the iterates of maps. On symplectically hyperbolic manifolds, we show that this sequence has at least linear growth for every non-identical symplectomorphisms which are symplectically isotopic to the identity. 相似文献