全文获取类型
收费全文 | 10658篇 |
免费 | 553篇 |
国内免费 | 80篇 |
专业分类
化学 | 7958篇 |
晶体学 | 86篇 |
力学 | 190篇 |
数学 | 1066篇 |
物理学 | 1991篇 |
出版年
2023年 | 54篇 |
2022年 | 152篇 |
2021年 | 208篇 |
2020年 | 167篇 |
2019年 | 186篇 |
2018年 | 162篇 |
2017年 | 148篇 |
2016年 | 342篇 |
2015年 | 304篇 |
2014年 | 375篇 |
2013年 | 648篇 |
2012年 | 741篇 |
2011年 | 883篇 |
2010年 | 522篇 |
2009年 | 458篇 |
2008年 | 701篇 |
2007年 | 594篇 |
2006年 | 624篇 |
2005年 | 519篇 |
2004年 | 464篇 |
2003年 | 392篇 |
2002年 | 410篇 |
2001年 | 204篇 |
2000年 | 200篇 |
1999年 | 131篇 |
1998年 | 91篇 |
1997年 | 104篇 |
1996年 | 110篇 |
1995年 | 82篇 |
1994年 | 78篇 |
1993年 | 64篇 |
1992年 | 72篇 |
1991年 | 50篇 |
1990年 | 69篇 |
1989年 | 73篇 |
1988年 | 50篇 |
1987年 | 42篇 |
1986年 | 34篇 |
1985年 | 69篇 |
1984年 | 60篇 |
1983年 | 43篇 |
1982年 | 46篇 |
1981年 | 38篇 |
1980年 | 34篇 |
1979年 | 40篇 |
1978年 | 34篇 |
1977年 | 44篇 |
1976年 | 34篇 |
1975年 | 31篇 |
1973年 | 39篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
981.
Yi Liu Tao Zou Fen Wang Chang-Hui Li Lin Zheng Young Sun 《Physica B: Condensed Matter》2011,406(6-7):1263-1266
We report on exotic dielectric properties of composite materials consisting of traditional ferroelectric BaTiO3 and electronic ferroelectric LuFe2O4. The composites were synthesized by a simple ceramic processing method with properties that can be tailored by adjusting LuFe2O4 concentration. A percolative effect was observed at the volume fraction of ~0.26, which led to an abrupt increase in the dielectric permittivity. For composites with high LuFe2O4 fractions, a giant dielectric tunability was observed over a broad temperature interval, which is in strong contrast to traditional ferroelectrics. 相似文献
982.
Abstract
The photoinduced electron transfer from chlorophyll a through the interface of positively charged dioctadecyltrimethylammonium chloride (DODAC), neutral dipalmitoylphosphatidylcholine (DPPC) and negatively charged dihexadecylphosphate (DHP) headgroup of the lipid bilayers was studied. The photoinduced radicals were identified by electron spin resonance (ESR) and radical yields of chlorophyll a were determined by double integration of the ESR spectra. The formation of vesicles was identified indirectly by measuring change of the λ max value of optical absorption spectrophotometer from diethyl ether solution to vesicle solutions, and observed directly with scanning and transmission electron microscopic images. The interaction distance between chlorophyll a and interface water (D2O) determined by deuterium modulation depth with electron spin echo modulation (ESEM) showed a decreasing order DODAC > DPPC > DHP. The interface charge of each vesicle was determined with zeta potential measurement. The interface charge of the lipid bilayers affected the radical yields of chlorophyll a more critically than the interaction distance between chlorophyll a and interface water. 相似文献983.
Min Hwan Lee Kyung Min Kim Seul Ji Song Sang Ho Rha Jun Yeong Seok Ji Sim Jung Gun Hwan Kim Jung Ho Yoon Cheol Seong Hwang 《Applied Physics A: Materials Science & Processing》2011,102(4):827-834
The bipolar resistive switching mechanisms of a p-type NiO film and n-type TiO2 film were examined using local probe-based measurements. Scanning probe-based current–voltage (I–V) sweeps and surface potential/current maps obtained after the application of dc bias suggested that resistive switching is
caused mainly by the surface redox reactions involving oxygen ions at the tip/oxide interface. This explanation can be applied
generally to both p-type and n-type conducting resistive switching films. The contribution of oxygen migration to resistive
switching was also observed indirectly, but only in the cases where the tip was in (quasi-) Ohmic contact with the oxide. 相似文献
984.
A combination of infrared spectroscopy, X-ray photoelectron spectroscopy and density functional theory has been used to investigate the adsorption behavior of glycine at the Ge(100) ? 2 × 1 surface under ultrahigh vacuum conditions. Comparison of experimental and simulated IR spectra indicates that at 310 K, glycine adsorbs on Ge(100) ? 2 × 1 via O–H dissociation, with some fraction of the products also forming an N dative bond to a neighboring germanium atom. O–Ge dative bonding is not observed. As coverage increases, the surface concentration of the monodentate O–H dissociated adduct increases, while that of the N dative-bonded species appears constant. XPS data support and clarify the IR findings and reveal new insights, including the presence at higher coverage of a minor product that has undergone dual O–H and N–H dissociation. These findings are supported by the calculated energy diagrams, which indicate that the reaction of a glycine molecule on the Ge(100) ? 2 × 1 surface via O–H dissociation and interdimer N dative bonding is both kinetically and thermodynamically favorable and that N–H dissociation of this adduct is feasible at room temperature given incomplete thermal accommodation along the reaction pathway. 相似文献
985.
We investigate the high-frequency timing jitter spectral density of mode-locked fiber lasers in different mode-locked regimes. Quantum-noise-limited timing jitter spectra of mode-locked-regime-switchable Yb fiber lasers are measured up to the Nyquist frequency with sub-100-as resolution. The integrated rms timing jitter of soliton, stretched-pulse, and self-similar Yb fiber lasers is measured to be 1.8, 1.1, and 2.9 fs, respectively, when integrated from 10 kHz to 40 MHz. The distinct behavior of jitter spectral density related to pulse formation mechanisms is revealed experimentally for the first time. 相似文献
986.
Jung Tae ParkJoo Hwan Koh Jin Ah SeoYong Soo Cho Jong Hak Kim 《Applied Surface Science》2011,257(20):8301-8306
We report on the novel ternary hybrid materials consisting of semiconductor (TiO2), metal (Ag) and polymer (poly(oxyethylene methacrylate) (POEM)). First, a hydrophilic polymer, i.e. POEM, was grafted from TiO2 nanoparticles via the surface-initiated atom transfer radical polymerization (ATRP) technique. These TiO2-POEM brush nanoparticles were used to template the formation of Ag nanoparticles by introduction of a AgCF3SO3 precursor and a NaBH4 aqueous solution for reduction process. Successful grafting of polymeric chains from the surface of TiO2 nanoparticles and the in situ formation of Ag nanoparticles within the polymeric chains were confirmed using transmission electron microscopy (TEM), UV-vis spectroscopy, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). FT-IR spectroscopy also revealed the specific interaction of Ag nanoparticles with the CO groups of POEM brushes. This study presents a simple route for the in situ synthesis of both metal and polymer confined within the semiconductor, producing ternary hybrid inorganic-organic nanomaterials. 相似文献
987.
Properties of two-dimensional thermal radiation are investigated as a function of sample size and temperature. The two-dimensional thermal radiation is different from two-dimensional blackbody radiation when the size of the sample becomes small due to the uncertainty principle, which shows the allowed minimum energy can?t be neglected. The energy density is shown as a function of sample size at a constant temperature. The energy density is also shown as a function of temperature at a constant size. It is shown that our prediction can be measured from the thermal radiation of graphene. 相似文献
988.
We study the cross-correlations of buy and sell volumes on the Korean stock market in high frequency. We observe that the pulling effects of volumes are as small as that of returns. The properties of the correlations of buy and sell volumes differ. They are explained by the degree of synchronization of stock volumes. Further, the pulling effects on the minimal spanning tree are studied. In minimal spanning trees with directed links, the large pulling effects are clustered at the center, not uniformly distributed. The Epps effect of buy and sell volumes are observed. The reversal of the cross-correlations of buy and sell volumes is also detected. 相似文献
989.
Sanghyun AhnJaewon Choi Gyuchang LimKil Young Cha Sooyong KimKyungsik Kim 《Physica A》2011,390(11):1991-2001
We investigate the structure of the cross-correlation in the Korean stock market. We analyze daily cross-correlations between price fluctuations of 586 different Korean stock entities for the 6-year time period from 2003 to 2008. The main purpose is to investigate the structure of group correlation and its stability by undressing the market-wide effect using the Markowitz multi-factor model and the network-based approach. We find the explicit list of significant firms in the few largest eigenvectors from the undressed correlation matrix. We also observe that each contributor is involved in the same business sectors. The structure of group correlation can not remain constant during each 1-year time period with different starting points, whereas only two largest eigenvectors are stable for 6 years 8-9 eigenvectors remain stable for half-year. The structure of group correlation in the Korean financial market is disturbed during a sufficiently short time period even though the group correlation exists as an ensemble for the 6-year time period in the evolution of the system. We verify the structure of group correlation by applying a network-based approach. In addition, we examine relations between market capitalization and businesses. The Korean stock market shows a different behavior compared to mature markets, implying that the KOSPI is a target for short-positioned investors. 相似文献
990.
We correct some statements in the paper mentioned in the title. 相似文献