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In this study, the effects of an (NH4)2Sx treatment on the surface work function (SWF) and roughness of indium-tin-oxide (ITO) have been investigated. From the observed X-ray photoelectron spectroscopy results, optical transmittance measurements, atomic force microscopy measurements and four-point probe measurements, it is suggested that the surface chemical changes and an increase in the sheet resistance had strong effects on the SWF of ITO. We find that the S occupation of oxygen vacancies near the ITO surface after (NH4)2Sx treatment may result in a marked increase in the SWF and a slight increase in the surface roughness. 相似文献
145.
Xinzheng Zhang Jingmin Zhang Li Chen Jun Xu Liping You Dapeng Yu 《Applied Physics A: Materials Science & Processing》2008,92(3):669-672
In order to well understand the growth mechanism of the diverse morphology of the ZnO nanostructures, in situ analysis of
the formation of different ZnO nanostructures, such as nanowires, nanocombs, and nanosheets, has been conducted in an environmental
scanning electron microscope (ESEM). It is found that both nanocombs and nanosheets grew in two-stage heating processes on
parent nanowires. The difference is that the nanocombs were synthesized in extremely high pressure of zinc vapor via a self-catalyzed
vapor-liquid-solid process, while the ZnO nanosheets were grown in relatively low pressure of zinc vapor. All the growth processes
were revealed in real time imaging. It is demonstrated that the change in the growth environments can influence the thickness
of the ZnO polycrystalline surface of the zinc powder, which alters the pressure of the zinc vapor and in turn determines
the morphology of the final nanostructures. 相似文献
146.
A novel perylene tetracarboxylic acid bisimide(PTCBI) in-chain polyethylene(PE) was first prepared via acyclic diene metathesis(ADMET) polymerization of PTCBI-functionalized α,ω-diene monomer. The polymers could spontaneously self-assemble into hollow cylindrical structures in which the π-π interaction between adjacent PTCBI moieties was enhanced and the electron mobility was possibly promoted. The hydrogenation of as-obtained polymer was readily accomplished, affording the desired precision PTCBI in-chain PE with a saturated backbone, which showed high glass transition temperature(Tg = 63 °C), relatively wide range of light absorption(λ = 200-575 nm), and higher LUMO level(-3.62 e V). It can therefore serve as a superior model for facile construction of functional polyolefin and soluble PTCBI polymer with ordered architecture. 相似文献
147.
A local environment approach is used to calculate the sizes of the magnetic moments in ordered Fe3Al. A simple model based on a LCAO model and Stoner theory gives results in good agreement with experiment. Calculations were performed self-consistently using the recursion method. The role of the aluminium is investigated and it is shown that it is essential to include the aluminium sp band but the results are insensitive to its details. 相似文献
148.
利用KrF激光泵浦高压H_2,在同轴前向的受激拉曼散射(SRS)作用下,产生受激拉曼放大,1阶Stokes光对泵浦光的转换效率为17.2%,并对影响放大过程和转换效率的若干因素作了分析。 相似文献
149.
碘-四氯化碳萃取光度法间接测定食品中的痕量过氧化氢 总被引:5,自引:0,他引:5
在 p H1.0— 3.0稀硫酸介质中 ,一定的反应条件下 ,过氧化氢与碘化钾反应 ,释放出一定量的碘 ,建立了碘 -四氯化碳萃取光度法间接测定痕量过氧化氢。共存离子基本上不干扰测定 ,过氧化氢的检测限为0 .0 5 μg·m L-1;回收率在 94 %— 98%之间 ,结果令人满意 相似文献
150.