Summary: The photo‐crosslinking of carbazole dendrimers was analyzed by UV and IR spectroscopic methods. Photoirradiation results in the formation of a film that is insoluble in toluene and benzene. Time‐of‐flight mass spectrometry studies revealed that the photoirradiation lead to an oligomerization of the dendrimer through crosslinking. The resulting insoluble dendrimer film could be applied as a hole‐transport layer in efficient polymer electroluminescence devices (PLEDs).
Luminance‐voltage characteristics for PLEDs wherein PEDOT:PSS and CbzG3 complex with SnCl2 were employed as the hole transport layer (ITO/HTL/EML/Ca/Ag). 相似文献
We study the branch divisors on the boundary of the canonical toroidal compactification of ball quotients. We show a criterion, the low slope cusp form trick, for proving that ball quotients are of general type. Moreover, we classify when irregular cusps exist in the case of the discriminant kernel and construct concrete examples for some arithmetic subgroups. As another direction of study, when a complex ball is embedded into a Hermitian symmetric domain of type IV, we determine when regular or irregular cusps map to regular or irregular cusps studied by Ma. 相似文献
NiII 3,7,13,17-tetrapyridyl-5,15-diazaporphyrin serves as a double tridentate ligand to PdII ions to provide a pincer-type bispalladium complex. Electrochemical analysis revealed that the bispalladium complex shows excellent ability to accept electrons and reversible redox properties due to the coordination of the two cationic PdII centers to the meso-nitrogen atoms. We isolated and characterized one- and two-electron reduction species of the bispalladium complex. The 20π antiaromatic nature of the two-electron reduction species was confirmed by 1H NMR spectroscopy, UV/Vis-near-IR (NIR) absorption spectra, and density functional theory (DFT) calculations. X-ray diffraction revealed highly twisted structures for the bispalladium complexes regardless of the oxidation state. 相似文献
