全文获取类型
收费全文 | 94篇 |
免费 | 4篇 |
专业分类
化学 | 69篇 |
数学 | 5篇 |
物理学 | 24篇 |
出版年
2019年 | 1篇 |
2018年 | 3篇 |
2017年 | 1篇 |
2016年 | 2篇 |
2015年 | 1篇 |
2014年 | 4篇 |
2013年 | 10篇 |
2012年 | 5篇 |
2011年 | 4篇 |
2010年 | 2篇 |
2009年 | 3篇 |
2008年 | 7篇 |
2007年 | 2篇 |
2006年 | 3篇 |
2005年 | 5篇 |
2004年 | 8篇 |
2003年 | 5篇 |
2002年 | 2篇 |
2001年 | 4篇 |
2000年 | 4篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1991年 | 1篇 |
1983年 | 1篇 |
1981年 | 3篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1972年 | 1篇 |
1969年 | 1篇 |
1967年 | 1篇 |
1928年 | 1篇 |
1925年 | 1篇 |
排序方式: 共有98条查询结果,搜索用时 0 毫秒
91.
92.
Shigehiro Takahashi Yu Aikawa Tomotaka Kudo Tetsuya Ono Yoshitomo Kashiwagi Jun-ichi Anzai 《Colloid and polymer science》2014,292(3):771-776
The decomposition of layer-by-layer (LbL) thin films composed of 2,2,6,6-tetramethylpiperidine-1-oxyl free radical-appended poly(acrylic acid) (TEMPO-PAA) and poly(ethylenimine) (PEI) was studied by using a quartz crystal microbalance (QCM) and cyclic voltammetry. The electrode potential of the (PEI/TEMPO-PAA)4/PEI film-coated Au resonator was scanned from +0.2 to +0.8 V vs Ag/AgCl. The CV showed that the oxidation peak current decreased as the number of scans increased. The change in the resonance frequency of the QCM increased after electrolysis, indicating that the film was decomposed by electrolysis. The positive charges originating from the oxoammonium ions probably destabilized the (PEI/TEMPO-PAA)4/PEI film. Furthermore, the release of 5,10,15,20-tetraphenyl-21H,23H-porphine tetrasulfonic acid (TPPS) from TPPS-loaded (PEI/TEMPO-PAA)4/PEI-coated ITO electrodes was investigated. TPPS was released at electrode potentials greater than +0.6 V by the decomposition of the film. The results suggest that TEMPO-PAA/PEI LbL films are suitable for electrochemically controlled drug delivery systems. 相似文献
93.
Hiroshi Kamitakahara Akihiro Baba Arata Yoshinaga Ryo Suhara Toshiyuki Takano 《Cellulose (London, England)》2014,21(5):3323-3338
This article describes the first observation of crystallization-induced microphase separation in thin film and bulk cellulose triacetate-block-poly(γ-benzyl-l-glutamate) (PBLG) [cellulose triacetate (CTA)-b-PBLG] via copper-catalyzed azide–alkyne cycloaddition (CuAAC) between azido-functionalized CTA at the reducing end and alkyne-functionalized PBLG at the C-terminus. The reactivity of the amino group at the C-1 position of the glucosyl residue at the reducing end for the initiation reaction of the ring-opening polymerization (ROP) of γ-benzyl-l-glutamate N-carboxyanhydride was compared to that of the azido group at the reducing end of CTA for CuAAC, with PBLG bearing an alkyne group at the C-terminus. Although the amino group at the reducing end of CTA exhibited no reactivity as a macroinitiator for ROP of BLG, the azido group at the reducing end of CTA reacted with the alkyne group at the C-terminus of PBLG to afford CTA-b-PBLG. The structure of CTA-b-PBLG was characterized by 1H- and 13C-nuclear magnetic resonance spectroscopies, infrared spectroscopy, differential scanning calorimetry, and wide angle X-ray diffractometry. Microphase separation of the film and bulk of CTA-b-PBLG was clearly shown by atomic force microscopy, field-emission scanning electron microscopy, and transmission electron microscopy. 相似文献
94.
Luo L Carson JD Molnar KS Tuske SJ Coales SJ Hamuro Y Sung CM Sudakin V Auger KR Dhanak D Jackson JR Huang PS Tummino PJ Copeland RA 《Journal of the American Chemical Society》2008,130(24):7584-7591
Human kinesin spindle protein (KSP)/hsEg5, a member of the kinesin-5 family, is essential for mitotic spindle assembly in dividing human cells and is required for cell cycle progression through mitosis. Inhibition of the ATPase activity of KSP leads to cell cycle arrest during mitosis and subsequent cell death. Ispinesib (SB-715992), a potent and selective inhibitor of KSP, is currently in phase II clinical trials for the treatment of multiple tumor types. Mutations that attenuate Ispinesib binding to KSP in vitro have been identified, highlighting the need for inhibitors that target different binding sites and inhibit KSP activity by novel mechanisms. We report here a small-molecule modulator, KSPA-1, that activates KSP-catalyzed ATP hydrolysis in the absence of microtubules yet inhibits microtubule-stimulated ATP hydrolysis by KSP. KSPA-1 inhibits cell proliferation and induces monopolar-spindle formation in tumor cells. Results from kinetic analyses, microtubule (MT) binding competition assays, and hydrogen/deuterium-exchange studies show that KSPA-1 does not compete directly for microtubule binding. Rather, this compound acts by driving a conformational change in the KSP motor domain and disrupts productive ATP turnover stimulated by MT. These findings provide a novel mechanism for targeting KSP and perhaps other mitotic kinesins. 相似文献
95.
Johnson AR Okawachi Y Levy JS Cardenas J Saha K Lipson M Gaeta AL 《Optics letters》2012,37(5):875-877
By fabricating high-Q silicon-nitride spiral resonators, we demonstrate frequency combs spanning over 200 nm with free spectral ranges (FSRs) of 80, 40, and 20 GHz using cascaded four-wave mixing. We characterize the RF beat note for the 20 GHz FSR comb, and the measured linewidth of 3.6 MHz is consistent with thermal fluctuations in the resonator due to amplitude noise of the pump source. These combs represent an important advance towards developing a complementary metal-oxide-semiconductor (CMOS)-based system capable of linking the optical and electronic regimes. 相似文献
96.
Yoshitomo Okada 《Mathematische Zeitschrift》1925,23(1):62-71
Ohne Zusammenfassung 相似文献
97.
98.
T. Suhara 《Laser \u0026amp; Photonics Reviews》2009,3(4):370-393
This paper reviews the quasi‐phase‐matched (QPM) waveguide nonlinear‐optic device technologies for generation of quantum‐entangled twin photons indispensable for quantum‐information techniques. After a brief introduction to the concept of entanglement, quantum theory analysis of twin‐photon generation (TPG) is outlined to clarify the properties of twin photons. Then, methods for entangled‐photon generation are discussed. Practical design and theoretical performances of LiNbO3 waveguide QPM TPG devices, as well as the fabrication techniques, are described. Finally, experimental demonstrations of polarization‐entangled twin‐photon generation by waveguide Type‐I and Type‐II QPM TPG devices are presented. 相似文献