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41.
Anodic electrodeposition of highly oriented zirconium phosphate and polyaniline-intercalated zirconium phosphate films 总被引:1,自引:0,他引:1
Takei T Kobayashi Y Hata H Yonesaki Y Kumada N Kinomura N Mallouk TE 《Journal of the American Chemical Society》2006,128(51):16634-16640
Films of highly oriented alpha-zirconium phosphate and polyaniline-intercalated zirconium phosphate with controllable thickness in the micrometer range were grown anodically on Pt electrodes. To optimize the electrodeposition conditions, the exfoliation of alpha-zirconium phosphate by tetrabutylammonium (TBA) salts was investigated in several nonaqueous solvents. Acetonitrile was found to be the best solvent for making crack-free, oriented films because of its high vapor pressure, low viscosity, and relatively high permittivity. With TBA salts of neutral or weakly acidic anions (TBACl, TBABr, TBAI, TBA(HSO4), or TBA(H2PO4)), full exfoliation did not occur and alpha-zirconium phosphate and/or polyaniline were deposited as rough films. With basic anions (TBAF or TBAOH), dense, adherent films were obtained. X-ray diffraction patterns of the films showed that they were highly oriented along the stacking axis. The thickness could be controlled, up to about 40 microm, by limiting the time of the electrodeposition reaction. At monomer concentrations below 1.0 x 10(-2) mol/dm3, the emeraldine form of the intercalated polymer was obtained. Electrodeposition thus provides a thick film alternative to layer-by-layer assembly for intercalation compounds of alpha-zirconium phosphate with a conducting polymer. 相似文献
42.
43.
Akinori Ohshita Masaaki Okuhara Chiharu Matsuya Koichi Hata Kazuo Iida 《Mikrochimica acta》2006,155(1-2):225-228
A new electron holographic method is presented to directly visualize pure phase objects such as electromagnetic microfields,
which is achieved by superposition of two kinds of electron holograms. The method is very simple and is twice as sensitive
as the conventional double-exposure electron holography and the four-electron-wave interference. Using this technique, an
electric field around a charged latex sphere and a magnetic field around a barium ferrite particle have been directly observed. 相似文献
44.
Yuko Hata Toyoko Suzuki Hideto Minami Masayoshi Okubo 《Colloid and polymer science》2008,286(13):1561-1567
Hollow polymer particles with multiple holes in the shell were prepared by aqueous microsuspension polymerization of micrometer-sized,
monodisperse divinylbenzene/n-hexadecane droplets in the presence of sodium dodecyl sulfate (SDS) at concentrations above 4 mM utilizing the Self-assembling Phase-Separated Polymer (SaPSeP) method developed by the authors. The total surface area of the holes per particle increased with an increase
in the SDS concentration. At [SDS] = 10 mM, “flower-like” non-spherical particles were formed.
Part CCCXV of series “Studies on Suspension and Emulsion” 相似文献
45.
Molecularly Designed Nanoparticles by Dispersion of Self‐Assembled Organosiloxane‐Based Mesophases 下载免费PDF全文
Shigeru Sakamoto Yasuhiro Tamura Dr. Hideo Hata Dr. Yasuhiro Sakamoto Prof. Atsushi Shimojima Prof. Kazuyuki Kuroda 《Angewandte Chemie (International ed. in English)》2014,53(35):9173-9177
The design of siloxane‐based nanoparticles is important for many applications. Here we show a novel approach to form core–shell silica nanoparticles of a few nanometers in size through the principle of “dispersion of ordered mesostructures into single nanocomponents”. Self‐assembled siloxane–organic hybrids derived from amphiphilic alkyl‐oligosiloxanes were postsynthetically dispersed in organic solvent to yield uniform nanoparticles consisting of dense lipophilic shells and hydrophilic siloxane cores. In situ encapsulation of fluorescent dyes into the nanoparticles demonstrated their ability to function as nanocarriers. 相似文献
46.
Dr. Toru Amaya Dai Hata Dr. Toshiyuki Moriuchi Prof. Dr. Toshikazu Hirao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(46):16427-16433
A reduced form of polyaniline has been shown to induce direct arylation of an arenediazonium salt with an arene (Gomberg–Bachmann reaction) to give the cross‐coupling product in moderate to good yields under mild conditions. Various arenediazonium salts and arenes, including heteroarenes such as furans, thiophenes, and pyrroles, are employed for the reaction. The most favorable combination of substrates is an electron‐poor arenediazonium salt with an electron‐rich heteroarene. Investigation of the mechanism by reactions with radical scavengers and experiments on kinetic isotope effects indicated the occurrence of a radical chain reaction initiated by one‐electron reduction of an arenediazonium salt by the polyaniline. Only 1 mol % (based on aniline tetramer) of the polyaniline is required for the cross‐coupling reaction to occur. This reaction proceeds under metal‐free conditions and with no need for photonic activation. 相似文献
47.
Okada S Arayama K Murayama R Ishizuka T Hara K Hirone N Hata T Urabe H 《Angewandte Chemie (International ed. in English)》2008,47(36):6860-6864
48.
Victor V. Borovkov Michael Anikin Kiyotaka Wasa Yoshiteru Sakata 《Photochemistry and photobiology》1996,63(4):477-482
Abstract— Structurally controlled aggregation course for five porphyrins (etioporphyrin [EP], 5-mono- and 5,15-di-[ p -tol-yl]etioporphyrin [TP and DTP], 5,10,15,20-tetrakis[ p -tol-y1]porphin [TTP], and 5,10,15,20-tetrakis[3,5-di- tert -bu-tylphenyl]porphin [TBP]) in dipalmitoyl-phosphatidyl-choline liposomes has been monitored by fluorescence and absorption spectroscopy. While TBP shows no tendency to aggregate in liposomes, EP, TP, DTP and TTP form a porphyrin-enriched domain in membrane interior with time. The further aggregation steps within porphyrin clusters resulting in formation of stacked porphyrin aggregates have been observed for EP, TP and DTP. 相似文献
49.
Direct beta-glucosidation between benzyl alcohol and D-glucose (5) using the immobilized beta-glucosidase from almonds with the synthetic prepolymer ENTP-4000 gave a benzyl beta-D-glucoside (1) in 53% yield. The coupling of the benzyl beta-D-glucopyranoside congener (8) derived from 1 with phenyl 2,3,4-tri-O-acetyl-1-thio-beta-D-xylopyranoside (9), ethyl 2,3,4-tri-O-acetyl-1-thio-alpha-L-rhamnopyranoside (13), and 2,3,4-tri-O-acetyl-alpha-L-arabinopyranosyl bromide (15) afforded 10, 14, and 16, respectively, as coupled products. Deprotection of 10, 14, and 16 provided the synthetic benzyl beta-D-xylopyranosyl-(1-->6)-beta-D-glucopyranoside (2), benzyl alpha-L-rhamnopyranosyl-(1-->6)-beta-D-glucopyranoside (3), and benzyl alpha-L-arabinopyranosyl-(1-->6)-beta-D-glucopyranoside (4), respectively. 相似文献
50.
The phase diagrams of the CuGaS2-CuI and CuGaSe2-CuI pseudobinary systems are investigated. Both systems show eutectic behavior; liquids along the liquids curves for solute concentrations of more than 15 mol% are shown to be single phase and solids in equilibrium with the liquids are demonstrated to be CuGaS2 and CuGaSe2 chalcopyrite compounds. On the basis of the results, bulk crystals of CuGaS2 and CuGaSe2 are prepared from CuI solutions using the Bridgman technique. The photoluminescence spectra of these crystals are nearly the same as those of the crystals grown by iodine transport method. 相似文献