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101.
Signal denoising and baseline correction by discrete wavelet transform for microchip capillary electrophoresis 总被引:1,自引:0,他引:1
Signal denoising and baseline correction using discrete wavelet transform (DWT) are described for microchip capillary electrophoresis (MCE). DWT was performed on an electropherogram describing a separation of nine tetramethylrohodamine-5-isothiocyanate labeled amino acids, following MCE with laser-induced fluorescence detection, using Daubechies 5 wavelet at a decomposition level of 6. The denoising efficiency was compared with, and proved to be superior to, other commonly used denoising techniques such as Fourier transform, Savitzky-Golay smoothing and moving average, in terms of noise removal and peak preservation by directly visual inspection. Novel strategies for baseline correction were proposed, with a special interest in baseline drift that frequently occurred in chromatographic and electrophoretic separations. 相似文献
102.
Studer A Amrein S Matsubara H Schiesser CH Doi T Kawamura T Fukuyama T Ryu I 《Chemical communications (Cambridge, England)》2003,(10):1190-1191
4-[(Trimethylstannyl)diphenylsilyl]butanoyl radical, arising from the corresponding 3-(stannylsilyl)propyl radical and CO, undergoes an SHi reaction at Si with extrusion of trimethyltin radical to give silacyclopentanone. The parent 3-(stannylsilyl)propyl radical was also found to isomerize to (3-stannylpropyl)silyl radical via a 1,4-Sn shift from Si to C with a rate constant of 9.3 x 10(4) s-1 at 80 degrees C. Ab initio and DFT MO calculations support a front-side attack mechanism. 相似文献
103.
Yokoyama Y Shiraishi H Tani Y Yokoyama Y Yamaguchi Y 《Journal of the American Chemical Society》2003,125(24):7194-7195
Introduction of an asymmetric center to C-2 of one of the benzothiophene rings of bisbenzothienylperfluorocyclopentene results in a highly diastereoselective photochromic system. The stereogenic center bears a hydrogen atom, a methyl group, and a methoxymethoxy group. The steric as well as the electronic repulsions gave an 87-88% diastereomer excess in various solvents at room temperature with 80-85% conversion to the colored form. The enantioselective synthesis was also carried out. Upon photoirradiation in hexane, a change in optical rotation at 820 nm, where neither the open form nor the colored form absorbs light, was observed repeatedly. 相似文献
104.
In order to investigate the space environment, a new neutron monitor has been prepared. The sensor consists of scintillation fibers (FIB) and will be on board the exposed facility of the Japanese Experimental module (Kibo) of the International Space Station (ISS). The sensor is one of the instruments which measures the particle and plasma environment around the ISS. The sensor will be used by the cosmonauts who work on the ISS, to help them avoid a strong particle radiation which may arrive soon. We believe that such an alert is necessary for the cosmonauts to prevent unnecessary radiation from the sun. Furthermore, the sensor will be very useful in understanding the particle acceleration mechanism at the solar surface. The design of the Engineering Model (EM) was finished and its properties were investigated. This report discusses these results. 相似文献
105.
T. Kunimatsu T. Sato K. Izumina A. Matsubara Y. Sasaki M. Kubota O. Ishikawa T. Mizusaki Yu. M. Bunkov 《JETP Letters》2007,86(3):216-220
The orientation of the order parameter in the A-like and B-like phases of superfluid 3He immersed in uniaxially compressed aerogel is reported. With the use of NMR methods, it is found that the orbital momentum
of the A-and B-like phases is oriented along the deformation. In the A-like phase, a relatively narrow NMR line with an anomalously
large negative frequency shift is observed. The Leggett frequency in the A-like phase, which shows the same energy gap suppression
as in the B-like phase, is measured.
The text was submitted by the authors in English. 相似文献
106.
107.
An intramolecular conjugate addition of γ- and δ-trichloroacetimidoyloxy-α,β-unsaturated esters, a new way to construct 1,2-amino or 1,3-amino alcohol moieties in an acyclic system, is described. Very concise synthesis of d-vancosamine and 3-epi-d-vancosamine derivatives was also achieved utilizing this methodology. 相似文献
108.
109.
A new effective copper catalyzed CO coupling reaction using excess amount of strongly coordinating monodentate ligands was successfully developed. Among the DMAP-type monodentate ligands, 4-pyrrolidinopyridine afforded the best results. The developed reaction is widely applicable for the synthesis of various hindered or acyclic secondary alkyl-aryl ethers. In this study, a novel and remarkable acceleration of the coupling reaction using excess amount of monodentate ligands was discovered. 相似文献
110.