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151.
Nobuhiro Sugihara Yoshiro Ogoma Koji Abe Yoshiyuki Kondo Toshihiro Akaike 《先进技术聚合物》1998,9(5):307-313
P-450cam (camphor-induced cytochrome P-450) was immobilized on an indium tin oxide (ITO) electrode by polypyrrole and its activity was controlled electrochemically. The results showed that P-450cam was immobilized on the ITO electrode without denaturing and the amount of P-450cam could be easily controlled. When, the electric potential was swept repeatedly between 0.4 and 0 V, the remarkable decrease of oxygen in the reaction mixture solution was observed only in the presence of camphor. In addition, hydroxycamphor was detected only in the same system by means of gas chromatography/mass spectroscopy. These results suggested that immobilized P-450cam catalyzed the hydroxylation of camphor by the supply of electron from the electrode. The effect of pH and ionic strength on the activity was examined, and it was found that the high activity expressed at the pH of 6.0 – 7.0 and KCl concentration of 0.1 – 0.2 M . The paper is the first report that P-450 enzyme activity could be controlled artificially. © 1998 John Wiley & Sons, Ltd. 相似文献
152.
We investigated the root mean square (RMS) timing jitter and RMS intensity noise of the wavelength tunable femtosecond soliton pulses using the technique of radio-frequency spectrum analysis. We obtained interesting results that the generated solitons have almost constant RMS timing jitter and RMS intensity noise of approximately 410 fs and 0.03% in the wavelength region of 1600-1750 nm. It is therefore believed that the magnitudes of the jitter and noise are not greatly increased in the process of wavelength tunable soliton pulse generation. The wavelength tunable soliton pulse is confirmed to be stable and useful for practical applications. 相似文献
153.
Seiji Yamaguchi Keiko Orito Noriko Shimizu Katsunori Taniguchi Hideo Saitoh Masahide Kurosaki Hajime Yokoyama Yoshiro Hirai Shunsaku Shiotani 《Journal of heterocyclic chemistry》1999,36(1):81-94
Furo[2,3-b:4,5-c‘]- 1a , -[3,2-b:4,5-c’]- 1b , -[2,3-c:4,5-c‘]- 1c and -[3,2-c:4,5-c’]dipyridine 1d were derived to the N-oxides 2a-d , N‘-oxides 2′b , 2′c or N,N’-dioxide 3b-d by N-oxidation with m-chloroperbenzoic acid. Chlorination of these N-oxides, N′-oxide and N,N′-dioxides with phosphorus oxychloride afforded compounds chlorinated at the α-position(s) to the ring nitrogen 4a-d , 4′c , 14b-d and 14′b . Acetoxylation of N-oxides 2a-d and 2′c with acetic anhydride gave the corresponding pyridone compounds 6a-d and 6′c in good yields, while the acetoxylation of N,N′-dioxides gave a complex mixture from which no compound could be isolated. Cyanation of 2a-d, 2′c and 3b-d with trimethylsilyl cyanide yielded the cyano compounds 7a-d , 7′c , cyano-N-oxides 15b-d and dicyano compounds 15′c and 15′d . Monocyano compounds 7a-d and 7′c were converted to the imino esters 8a-d and 8′c by treatment with sodium ethoxide. Imino esters were derived to the carboxylic esters 9a-d and 9′c , from which the corresponding alde hydes 10a-d and 10′c were obtained by reduction with diisobutylaluminum hydride. Dicyanide 15′c was converted to dialdehyde 19 by the treatment with sodium ethoxide, and the subsequent hydrolysis of the imino ester and reduction of the carboxylic ester with diisobutylaluminum hydride. 相似文献
154.
In-situ fatigue test on pre-fatigued aluminum single crystals and also in-situ tensile test of pre-fatigued copper-2 at.% aluminum alloy single crystals were carried out in an HVEM. In the Al crystals, forward and backward motion of dislocations, change of cell structures, formation of voids and crack propagation were directly observed in-situ by an HVEM under alternating stress. In the Cu-Al crystals, it was observed that slip occurred only in the part of the persistent slip bands during in-situ tensile deformation in an HVEM. 相似文献
155.
Rhodium complexes such as [RhCl(cod)]2, [Rh(cod)2]BF4, and [Rh(cod)(CH3CN)2]BF4 function as catalysts for carbonyl allylations by allylic alcohols with 1 equimolar amount of tin(II) chloride to each allylic alcohol and aldehyde in THF at 50 °C to produce the corresponding homoallylic alcohols. 相似文献
156.
A highly sensitive and accurate determination method for trace quantities of enantiomers of glufosinate (D,L-GLUF), a phosphorus-containing amino acid-type herbicide, has been studied. The present method is based on the change in the mole ratio of the enantiomeric isomers after spiking of a known amount of an isomer (L-GLUF). The chiral separation and detection were made by gamma-cyclodextrin modified capillary zone electrophoresis (gamma-CD-CZE) with fluorescence detection. Solid-phase extraction of D,L-GLUF with titania was investigated as the pre-separation method to eliminate coexisting materials such as inorganic salts and organic compounds in river water. A separated D,L-GLUF was labeled with dansyl chloride and subjected to the on-capillary concentration using large-volume sample stacking (LVSS) before gamma-CD-CZE. The detection limit of the present method was as low as 2.0 x 10(-9) M. The present method was successfully applied to a model sample containing 2.0 x 10(-7) M D,L-GLUF in river water. It was confirmed that trace quantities of D-and L-GLUF in environmental samples can be accurately determined without any calibration curves and comparison standards. 相似文献
157.
158.
Seiji Yamaguchi Yosbihiko Sugioka Miwa Ishida Hajime Yokoyama Yoshiro Hirai 《Journal of heterocyclic chemistry》1997,34(4):1329-1334
Diethyl 5-isopropenyl-4,5-dihydrofuran-2,3-dicarboxylate 1a and methyl 5-isopropenyl-3-methoxy-carbonyl-4,5-dihydrofuran-2-acetate 2a were prepared by cylization of diethyl 2-oxosuccinate or dimethyl 3-oxoglutarate with (E)-1,4-dibromo-2-methyl-2-butene. Their chemical properties were studied. 相似文献
159.
Harries JR Sullivan JP Sternberg JB Obara S Suzuki T Hammond P Bozek J Berrah N Halka M Azuma Y 《Physical review letters》2003,90(13):133002
We report the first experimental measurements of the effect of an applied field on the photoexcitation and autoionization of doubly excited states of helium. Ground-state photoionization spectra have been measured in the region below the He+(N=2) threshold with static electric fields of up to 84.4 kV/cm across the interaction region. The results are compared to the theoretical calculations of Chung et al. [J. Phys. B 34, 165 (2001)]], which are the only calculations available in this regime. Transitions to several states in the N=2, n=6 manifold are assigned, and a wealth of new structure is observed. Our data show that many more series are mixed in by the field than those predicted by theory. 相似文献
160.
Naraso N Nishida J Ando S Yamaguchi J Itaka K Koinuma H Tada H Tokito S Yamashita Y 《Journal of the American Chemical Society》2005,127(29):10142-10143
Aromatic ring-condensed TTF derivatives exhibited excellent p-type FET performances in thin films. Introduction of fused benzene and pyrazine rings to the TTF skeleton was effective to enhance the intermolecular interactions and stability to oxygen. Ordered molecular alignment was confirmed by XRD studies. A pi-stacking structure was observed in the single crystal of diquinoxalinoTTF. 相似文献