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61.
K. Nakanishi T. Masukawa T. Nadai K. Yoshii S. Okada K. Miyajima 《Journal of inclusion phenomena and macrocyclic chemistry》1996,25(1-3):181-184
Triacetyl--cyclodextrin (TA--CyD), a hydrophobic cyclodextrin derivative, that is insoluble in water, was used to form a complex with flufenamic acid (FA). FA-TA--CyD complex formation was demonstrated by differential scanning calorimetry and powder X-ray diffractometry. The release rate of FA from the FA-TA--CyD complexes in phosphate buffer pH 6.8 was significantly retarded compared to that of FA from the FA and glucose mixture. When the FA-TA--CyD complexes were administered directly into the intraduodenal lumen, the plasma concentration of FA remained at a plateau level (10-18 g/ml) for 6–8 h. An increased mean residence time of FA following FA-TA--CyD complexes administration was observed. These results indicate that TA--CyD may serve as a hydrophobic carrier in prolonged-release preparations of FA. 相似文献
62.
63.
Soichi Okada 《Journal of Algebraic Combinatorics》1993,2(2):155-176
An alternating sign matrix is a square matrix whose entries are 1, 0, or –1, and which satisfies certain conditions. Permutation matrices are alternating sign matrices. In this paper, we use the (generalized) Littlewood's formulas to expand the products
and
2 as sums indexed by sets of alternating sign matrices invariant under a 180° rotation. If we put t = 1, these expansion formulas reduce to the Weyl's denominator formulas for the root systems of type B
n and C
n. A similar deformation of the denominator formula for type D
n is also given. 相似文献
64.
Hisahiro Hagiwara Fumihide TakeuchiTakashi Hoshi Toshio SuzukiToshihiro Hashimoto Yoshinori Asakawa 《Tetrahedron letters》2003,44(11):2305-2306
1,9-Dideoxyforskolin 2 has been synthesized starting from ptychantin A 3. 相似文献
65.
The three-component aminoallylation reaction of the activated olefins 2 with the phthalimide 1a and allyl chloride proceeded very smoothly in the presence of Pd(2)dba(3).CHCl(3) (5 mol %)/P(4-FC(6)H(4))(3) (40 mol %) and Cs(2)CO(3) (3 equiv against 2) in dichloromethane at room temperature to give the corresponding aminoallylated products, N-pent-4-enylphthalimides 3, in 58-99% yields. The reaction of oxazolidinone 1b also proceeded very smoothly to give N-(2,2-dicyano-1-phenylpent-4-enyl)oxazolidinone in a quantitative yield; however, the Tsuji-Trost-type allylation products 4 were obtained in the case of dibenzylamine, N-tosylaniline, and pyrrolidin-2-one. Further, 2 underwent cycloaddition with N-tosylvinylaziridine 9a in the presence of Pd(2)dba(3).CHCl(3) (5 mol %)/P(4-FC(6)H(4))(3) (40 mol %) in THF at room temperature, giving the corresponding pyrrolidines 11 in 69-99% yields. 相似文献
66.
The delta form of crystalline syndiotactic polystyrene is a clathrate molecular compound in which various aromatic molecules are encaged. We have investigated the size, shape, and connectivity of the molecular cavity in the crystal using a molecular dynamics simulation. The effects of the guest species on the cavity structure were investigated in detail. In order to systematically vary the guest structure, various aromatic guests, e.g., benzene, toluene, p-xylene, m-xylene, o and mesitylene were examined. The interstitial spaces between the guests and the polymer chains were analyzed by cluster analysis of the free volumes. The individual cavity volumes into which the guests are clathrated were also evaluated. It was found that the guest molecules can greatly affect not only the cavity size and shape but also the connectivity of the cavities. The transport of small molecules in the crystal is discussed in connection with the cavity structure. 相似文献
67.
Neil C. Concibido Tetsuji Okuda Wataru Nishijima Mitsumasa Okada 《Reaction Kinetics and Catalysis Letters》2006,89(2):369-376
Summary The hydrodechlorination of tetrachloroethylene in methanol (MeOH) over palladium catalysts on activated carbon (Pd/C) at 20°C
and atmospheric pressure was rendered safer by using ethanol (EtOH), isopropanol (IPA) or water-alcohol mixtures as solvents.
Adding water to MeOH was better than using EtOH or IPA since it resulted in a faster reaction and better stability of Pd/C,
which could also be completely reactivated. 相似文献
68.
69.
70.
Takuma Shinya Nakashima Noriyuki Tantirungkij Manee Kinoshita Shinichi Okada Hirosuke Sew TatsÜji Yoshida Toshiomi 《Applied biochemistry and biotechnology》1991,28(1):327-340
Applied Biochemistry and Biotechnology - A NADPH/NADH-dependent xylose reductase gene was isolated from the xylose-assimilating yeast,Pichia stipitis. DNA sequence analysis showed that the gene... 相似文献