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The insistent two mode type behavior of the A1 and high frequency F2 bands in the tin contained glasses is reproduced by our vibrational calculations based on the outrigger-raft with some modifications. High pressure Raman spectra suggest an instability of the tin tetrahedral bonding. Comparative study of glassy and crystalline Ge(Se, or S)2 by high pressure Raman scattering gives important informations about the strain field and the topological order in the glasses. 相似文献
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Yoshimi Sueishi 《高等学校化学研究》2000,16(2):141-145
IntroductionThe photo-and thermo-chromisms of organometallic compounds have been intensivelystudied during thelast1 0 years.Meriwetheretal.[1 ,2 ] examined the chromic behaviorofmet-al-dithizone(phenyldiazenecarbothionic acid2 -phenylhydrazide) complexesin detail.From thekinetic and infrared studies,they showed thatthe central metal of a dithizonate complex de-termined the photochemical stability,the rate of the thermal return reaction,and the colorofthe dithizonate complex.As reported by Mer… 相似文献
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Neumann laplacians on domains and operators on associated trees 总被引:1,自引:0,他引:1
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Yasuyuki Endo Kiminori Ohta Tomohiro Yoshimi Kentaro Yamaguchi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4-5):799-802
The inorganic cage compounds, dicarba-closo-dodecaboranes (carboranes), are chemical building blocks of remarkable thermal and chemical stability, with spherical geometry and exceptional hydrophobic character. We have focused on medicinal drug design using carboranes as a hydrophobic pharmacophore and have developed a potent estrogen agonist, BE120. We also have applied carboranes for structural chemistry, utilizing their specific three-dimensional character to obtain multilayer aromatic structures. 相似文献
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Yukari Tajika Yumi Yasuoka Hiroyuki Nagahama Toshiyuki Suzuki Yoshimi Homma Tetsuo Ishikawa Shinji Tokonami Takahiro Mukai Miroslaw Janik Atsuyuki Sorimachi Masahiro Hosoda 《Journal of Radioanalytical and Nuclear Chemistry》2013,295(3):1709-1714
Gas-flow ionization chambers for radioisotope (RI) monitoring systems at RI institutes throughout Japan are commonly used to measure RIs which leak from the RI institutes. Before the Japan’s 2011 Tohoku earthquake [11 March 2011, moment magnitude (M w) 9.0], ionization current data measured with a gas-flow ionization chamber at the RI institute of Fukushima Medical University were found to change. The question we must raise is whether the variation ionization current can be considered to the variation of outdoor radon concentration. The conversion factors (from ionization current to radon concentration in air) of the gas-flow ionization chamber can be obtained by measuring four levels of radon concentration (outdoor air, indoor air, high level and radon-free gas) with an AlphaGUARD monitor and the chamber itself. The two gas-flow ionization chambers consist of the air intake and terminal exhaust duct of the RI institute. It was found that the radon concentration in the exhaust air was the same as that in the air intake. This study provided evidence that variations of outdoor radon concentration could be determined using gas-flow ionization chambers for RI monitoring systems. 相似文献