全文获取类型
收费全文 | 414篇 |
免费 | 8篇 |
专业分类
化学 | 351篇 |
晶体学 | 4篇 |
力学 | 1篇 |
数学 | 12篇 |
物理学 | 54篇 |
出版年
2021年 | 3篇 |
2020年 | 5篇 |
2019年 | 3篇 |
2018年 | 4篇 |
2017年 | 5篇 |
2016年 | 6篇 |
2015年 | 7篇 |
2013年 | 10篇 |
2012年 | 21篇 |
2011年 | 17篇 |
2010年 | 9篇 |
2009年 | 8篇 |
2008年 | 13篇 |
2007年 | 17篇 |
2006年 | 21篇 |
2005年 | 24篇 |
2004年 | 15篇 |
2003年 | 18篇 |
2002年 | 14篇 |
2001年 | 6篇 |
2000年 | 3篇 |
1999年 | 5篇 |
1998年 | 7篇 |
1997年 | 5篇 |
1996年 | 3篇 |
1995年 | 5篇 |
1994年 | 3篇 |
1993年 | 6篇 |
1991年 | 5篇 |
1990年 | 5篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 5篇 |
1986年 | 2篇 |
1985年 | 10篇 |
1984年 | 14篇 |
1982年 | 10篇 |
1981年 | 14篇 |
1980年 | 8篇 |
1979年 | 9篇 |
1978年 | 7篇 |
1977年 | 4篇 |
1976年 | 7篇 |
1975年 | 6篇 |
1974年 | 12篇 |
1973年 | 14篇 |
1972年 | 4篇 |
1971年 | 2篇 |
1965年 | 2篇 |
1963年 | 2篇 |
排序方式: 共有422条查询结果,搜索用时 281 毫秒
21.
We present the finding that photoluminescence intensity in ZnSe crystal is enhanced after exposure to a femtosecond laser beam. After the crystal was illuminated with laser light of 1.04 MW/cm(2) during 300 s, photoluminescence intensity was increased approximately 20%. The region in which photoluminescence intensity was enhanced was localized in the optical axis, because this phenomenon occurred in the two-photon excitation process. It is possible to achieve three-dimensional control of photoluminescence intensity by illumination with laser light. 相似文献
22.
Dr. Takaaki Mitsuhashi Dr. Lena Barra Zachary Powers Volga Kojasoy Andrea Cheng Feng Yang Dr. Yoshimasa Taniguchi Dr. Takashi Kikuchi Prof. Dr. Makoto Fujita Prof. Dr. Dean J. Tantillo Prof. Dr. John A. Porco Jr Prof. Dr. Ikuro Abe 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(52):23980-23989
Fungal meroterpenoids are a diverse group of hybrid natural products with impressive structural complexity and high potential as drug candidates. In this work, we evaluate the promiscuity of the early structure diversity-generating step in fungal meroterpenoid biosynthetic pathways: the multibond-forming polyene cyclizations catalyzed by the yet poorly understood family of fungal meroterpenoid cyclases. In total, 12 unnatural meroterpenoids were accessed chemoenzymatically using synthetic substrates. Their complex structures were determined by 2D NMR studies as well as crystalline-sponge-based X-ray diffraction analyses. The results obtained revealed a high degree of enzyme promiscuity and experimental results which together with quantum chemical calculations provided a deeper insight into the catalytic activity of this new family of non-canonical, terpene cyclases. The knowledge obtained paves the way to design and engineer artificial pathways towards second generation meroterpenoids with valuable bioactivities based on combinatorial biosynthetic strategies. 相似文献
23.
24.
Haino T Araki H Fujiwara Y Tanimoto Y Fukazawa Y 《Chemical communications (Cambridge, England)》2002,(18):2148-2149
A new class of fullerene sensors based on calix[5]arenes has produced the highly sensitive detection of C60 and C70. 相似文献
25.
Haino T Yamanaka Y Araki H Fukazawa Y 《Chemical communications (Cambridge, England)》2002,(5):402-403
The metal-induced regulation of fullerene complexation with double-calix[5]arene is described. The receptor shows strong binding to C70 only in the presence of Cu+. 相似文献
26.
Masatake Niwa Guo-Quan Liu Hiroshi Tatematsu Yoshimasa Hirata 《Tetrahedron letters》1984,25(34):3735-3738
A novel biflavonoid, chamaechromone was isolated from L. (Thymelaeaceae) and its structure elucidated by spectroscopic and chemical methods. 相似文献
27.
The title phanes were synthesized. Examination of their physical properties including X-ray crystallography disclosed that 1) the p-tropoquinone ring is still bent in both compounds though to a lesser extent than in the corresponding [2.2]phanes, 2) the metacyclo compound prefers syn conformation in solution, and 3) the intramolecular CT interaction is very similar in two compounds. 相似文献
28.
Toshie Tahara Yoshitsugu Sakuda Mitsuaki Kodama Yoshimasa Fukazawa Shô Itô Kazuyoshi Kawazu Shuhei Nakajima 《Tetrahedron letters》1980,21(19):1861-1862
The structures of xantholides A and B were deduced on the basis of IR and NMR spectra, and confirmed by X-ray analysis. Xantholide A inhibited the larval growth of Drosophila melanogaster. 相似文献
29.
A Mössbauer study was performed to find the fraction of non-bridging oxygens in potassium borate glasses containing a small amount of iron. The borate glasses with alkali contents of 15, 20, 25, 30 and 40 mol% were irradiated with 60Co-γ rays at room temperature in a nitrogen atmosphere. The Mössbauer absorption area for the irradiation-induced Fe2+ increased with the total γ-ray dose in the range of 1 × 106 ?2 × 108 R, and became constant after irradiation ranging from 2 × 108 R ? 1 × 109 R. The absorption area for the Fe2+ at the saturated region was correlated with the difference in the glass structure, i.e., the fraction of the non-bridging oxygens was estimated from the increased absorption area for the Fe2+ as a function of the alkali content of the glasses. The fraction of the non-bridging oxygen increased with the alkali content of the glasses in the alkali region above 20 mol%, and about 14% of the fraction was obtained for an alkali content of 40 mol%. 相似文献
30.