Estimation of 4s covalent bonding of Fe2+ and Fe3+ ions in NiO

The charge densities of the 4s electrons in Fe²⁺ and Fe³⁺ ions in the ionic compound, NiO, were measured from an internal conversion experiment and compared with some predicted values on the basis of different theoretical methods.     

The control of very low oxygen partial pressures with stabilized zirconia cell

Control of very low oxygen partial pressures was performed in the range of 10⁻²¹-10⁻²⁴ Pa at 750°C by pumping oxygen into the purified hydrogen stream with a stabilized zirconia cell. The oxygen partial pressures were monitored by a stabilized zirconia sensor. The stabilized zirconia oxygen sensor was calibrated by H₂-CO₂ gas buffer mixture in the range of oxygen pressure from 10⁻¹⁷ to 10⁻²¹ Pa, and oxygen partial pressures below 10⁻²¹ Pa were measured by extrapolating the calibration line to very low oxygen partial pressures. The lowest oxygen partial pressure controlled was 10⁻²⁴ Pa at 750°C, which was limited by gas leaks in the system and also by the reduction of the ionic transference number in solid electrolyte used as the oxygen pump.     

The local time of self-intersections of Brownian motions as generalized Brownian functionals

In this Letter, we show that the local time of self-intersections ofd-dimensional Brownian motions is a generalized Brownian functional in the sense of Hida.     

Thermally quenched and generated paramagnetism in Ge42S58 glass

Two kinds of paramagnetic defects whose density increases and decreases with temperature have been observed in Ge₄₂S₅₈ glass using ESR technique. The increasing and decreasing defects are interpreted as resulting from Ge dangling bonds with negative and positive effective electron correlation energies, respectively. Unlike usual amorphous semiconductors, Ge₄₂S₅₈ glass contains defects with the effective electron correlation energy whose value ranges from positive to negative depending on environment around the defect. The densities of the defects with the positive and negative values are about 4 × 10¹⁵ and 3 × 10¹⁷ cm^?3 respectively.     

Density results for uniform families

A familyF of subsets is calledk-dense if there exists ak-element setA such that all 2 ^k of its subsets can be obtained in the formAF for someFF. Best possible bounds are obtained for the maximum number of sets in notk-densek-partite families. This is a consequence of a new rank formula for inclusion matrices.     

A simple monitoring system for single subpicosecond laser pulses using an SH spatial autocorrelation method and a CCD image sensor

A simple noncollinear SHG autocorrelator for monitoring the time behavior of single subpicosecond laser pulses is described. A new CCD image-line sensor with high sensitivity in the UV range is used to measure the second-harmonic (SH) spatial distribution which gives information on the duration of the fundamental light pulses. An input energy of only 10 μJ is enough to obtain the SH spatial beam patterns in this highly sensitive autocorrelation system.     

Echo-intensity compensation in echolocating bats (Pipistrellus abramus) during flight measured by a telemetry microphone

An onboard microphone (Telemike) was developed to examine changes in the basic characteristics of echolocation sounds of small frequency-modulated echolocating bats, Pipistrellus abramus. Using a dual high-speed video camera system, spatiotemporal observations of echolocation characteristics were conducted on bats during a landing flight task in the laboratory. The Telemike allowed us to observe emitted pulses and returning echoes to which the flying bats listened during flight, and the acoustic parameters could be precisely measured without traditional problems such as the directional properties of the recording microphone and the emitted pulse, or traveling loss of the sound in the air. Pulse intensity in bats intending to land exhibited a marked decrease by 30 dB within 2 m of the target wall, and the reduction rate was approximately 6.5 dB per halving of distance. The intensity of echoes returning from the target wall indicated a nearly constant intensity (-42.6 +/- 5.5 dB weaker than the pulse emitted in search phase) within a target distance of 2 m. These findings provide direct evidence that bats adjust pulse intensity to compensate for changes in echo intensity to maintain a constant intensity of the echo returned from the approaching target at an optimal range.