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121.
The origin of the singular diamagnetic susceptibility at the Dirac point is probed through the study of effects of band-gap opening and spatially varying magnetic field. In the presence of a band gap, the susceptibility is nonzero only inside the band gap and exhibits a discrete jump at the band edges down to zero in the conduction and valence bands. The jump height is understood in terms of the pseudo-spin paramagnetism arising from valley degree of freedom. In spatially varying magnetic field with wave vector q, the susceptibility becomes nonzero only in a finite energy region containing the Dirac point, determined by q. This behavior is understood in terms of electronic states numerically calculated in periodic magnetic field. 相似文献
122.
We study the effects of noise intensity fluctuations on the stationary and dynamical properties of an overdamped Langevin model with a bistable potential and external periodical driving force. We calculated the stationary distributions, mean-first passage time (MFPT) and the spectral amplification factor using a complete set expansion (CSE) technique. We found resonant activation (RA) and stochastic resonance (SR) phenomena in the system under investigation. Moreover, the strength of RA and SR phenomena exhibit non-monotonic behavior and their trade-off relation as a function of the squared variation coefficient of the noise intensity process. The reliability of CSE is verified with Monte Carlo simulations. 相似文献
123.
Kitajima K Yoshikawa T Seo Y Ohno Y Yano Y Miki A Kanda T Kanata N Azuma T Sugimura K 《Magnetic resonance imaging》2011,29(4):579-583
Budd-Chiari syndrome (BCS) is a rare disorder caused by the obstruction of hepatic venous outflow, leading to sinusoidal congestion, ischemic injury to liver cells and portal hypertension. Long-term survival largely depends on whether hepatocellular carcinoma occurs. A recently available liver-specific contrast medium, gadolinium-ethoxybenzyl-diethylenetriamine penta-acetic acid (Gd-EOB-DTPA), reportedly has high diagnostic capability for detection of malignant liver tumors. However, there has been no report of the sue of Gd-EOB-DTPA-enhanced magnetic resonance imaging (MRI) for BCS. We present a case of chronic BCS who underwent both gadopentetate dimeglumine (Gd-DTPA) and Gd-EOB-DTPA-enhanced MRI. Hepatic congestion and edema were seen as slightly hypointense areas on Gd-EOB-DTPA-enhanced hepatobiliary-phase images, although these areas were observed as slightly hyperintense on previously obtained Gd-DTPA-enhanced delayed-phase image. Reduced uptake of Gd-EOB-DTPA by hepatocytes in the region of congestion or edema may account for this difference, which should be recognized in image interpretations. 相似文献
124.
Suginome M Ohmura T Miyake Y Mitani S Ito Y Murakami M 《Journal of the American Chemical Society》2003,125(37):11174-11175
Enantioenriched beta-borylallylsilanes were synthesized by palladium-catalyzed enantioface-selective addition of the silicon-boron bond to terminal allenes using a palladium catalyst possessing a chiral monodentate phosphine ligand. Use of a silylborane bearing a chiral auxiliary on the boron atom was beneficial to gain enantioface selectivities as high as 96% de. 相似文献
125.
Yukihiro Shintani Keiji Hirako Masanori Motokawa Yoshihiko Takano Masahiro Furuno Hiroyoshi Minakuchi Mitsuyoshi Ueda 《Analytical sciences》2004,20(12):1721-1723
An interconnecting technique, the "PDMS connection method", for quartz microchips in a high-pressure system is presented. The connection between quartz microchips is an essential technology for modular microfluidic devices, such as microchip-HPLC. PDMS was applied to the seal material, being spread on the seal side of the chips, and set into the metal housing. The characteristics of the PDMS connection method concerning pressure resistance and the extension of the peak were examined. The experimental results showed a good seal at 5 MPa, which seem to be sufficient for realizing microchip-HPLC utilizing a monolithic silica capillary column as a separation medium. The influence of the extra column effect on chromatographic separation was almost the same as in the case using a commercial union fitting. In addition, the PDMS connection enabled the detachability of chip-based modules with user-friendliness. Our experimental findings suggest that the novel PDMS connection method can possibly be applied as a generic technology in high-pressure microTAS. 相似文献
126.
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128.
Sato K Yamazoe S Yamamoto R Ohata S Tarui A Omote M Kumadaki I Ando A 《Organic letters》2008,10(12):2405-2408
1,3-Diketones were synthesized from alpha,beta-unsaturated ketones by treatment with acid chlorides and Et(2)Zn in the presence of RhCl(PPh(3))3. This is a very simple and extremely chemoselective reaction to give the adduct at the alpha-position of alpha,beta-unsaturated ketones. 相似文献
129.
N Murakami T Tanase S Nagai Y Sato T Ueda J Sakakibara H Ando Y Hotta K Takeya 《Chemical & pharmaceutical bulletin》1991,39(8):1962-1966
The Diels-Alder reactions of a cardiac glycoside, proscillaridin (1), with some dienophiles were investigated. The reaction of 1 with alkenes such as methyl vinyl ketone and methyl acrylate afforded 3-oxo-2-oxabicyclo[2.2.2]oct-7-enes (2-5) and para-substituted benzene derivatives (6 and 7), while 1 reacted with alkynes (3-butyn-2-one, methyl propiolate) to yield para- or meta-substituted benzene derivatives (6-9). The biological activities of the resulting derivatives were evaluated by the use of isolated guinea-pig papillary muscle preparations and Na+,K(+)-adenosine triphosphatase (ATPase) preparation from dog kidney. Among the proscillaridin derivatives, compounds 4 and 7 moderately inhibited Na+,K(+)-ATPase activity. Furthermore, the concentration range of 7 over which its positive inotropic effect on guinea-pig papillary muscle preparations, increased from 5% to 95% of maximum was broader than that of 1, i.e., concentration dependency was maintained over a greater range of concentration. 相似文献
130.
Kenshu Fujiwara Ryosuke Motousu Daisuke Sato Yoshihiko Kondo Uichi Akiba Takanori Suzuki Tetsuo Tokiwano 《Tetrahedron letters》2019,60(18):1299-1301
The total synthesis of a dibenzofuran rhamnoside, kehokorin A, and its aglycone, kehokorin B, was achieved via a route including Suzuki-Miyaura cross-coupling followed by Ullmann ether synthesis to form a dibenzofuran, stepwise bromination at C7 of the dibenzofuran, a second Suzuki-Miyaura cross-coupling to install a 4-methoxyphenyl group at C7, and rhamnosylation. 相似文献