全文获取类型
收费全文 | 1146篇 |
免费 | 30篇 |
国内免费 | 7篇 |
专业分类
化学 | 819篇 |
晶体学 | 12篇 |
力学 | 21篇 |
数学 | 92篇 |
物理学 | 239篇 |
出版年
2023年 | 8篇 |
2022年 | 11篇 |
2021年 | 10篇 |
2020年 | 9篇 |
2019年 | 14篇 |
2018年 | 11篇 |
2017年 | 12篇 |
2016年 | 18篇 |
2015年 | 22篇 |
2014年 | 22篇 |
2013年 | 70篇 |
2012年 | 60篇 |
2011年 | 66篇 |
2010年 | 40篇 |
2009年 | 32篇 |
2008年 | 66篇 |
2007年 | 91篇 |
2006年 | 69篇 |
2005年 | 75篇 |
2004年 | 52篇 |
2003年 | 60篇 |
2002年 | 57篇 |
2001年 | 17篇 |
2000年 | 20篇 |
1999年 | 22篇 |
1998年 | 14篇 |
1997年 | 14篇 |
1996年 | 17篇 |
1995年 | 10篇 |
1994年 | 7篇 |
1993年 | 8篇 |
1992年 | 5篇 |
1991年 | 9篇 |
1989年 | 8篇 |
1988年 | 5篇 |
1986年 | 9篇 |
1985年 | 10篇 |
1984年 | 24篇 |
1983年 | 8篇 |
1982年 | 12篇 |
1981年 | 17篇 |
1980年 | 12篇 |
1979年 | 11篇 |
1978年 | 4篇 |
1977年 | 6篇 |
1976年 | 4篇 |
1975年 | 6篇 |
1974年 | 4篇 |
1973年 | 6篇 |
1972年 | 5篇 |
排序方式: 共有1183条查询结果,搜索用时 390 毫秒
71.
We present a sophisticated optical design method for reducing the number of photodetectors for a specific sensing task. The chosen design parameter is the point spread function, and the selected task is object recognition. The point spread function is optimized iteratively with a genetic algorithm for object recognition based on a neural network. In the experimental demonstration, binary classification of face and non-face datasets was performed with a single measurement using two photodetectors. A spatial light modulator operating in the amplitude modulation mode was provided in the imaging optics and was used to modulate the point spread function. In each generation of the genetic algorithm, the classification accuracy with a pattern displayed on the spatial light modulator was fed-back to the next generation to find better patterns. The proposed method increased the accuracy by about 30 % compared with a conventional imaging system in which the point spread function was the delta function. This approach is practically useful for compressing the cost, size, and observation time of optical sensors in specific applications, and robust for imperfections in optical elements. 相似文献
72.
Visible‐Light‐Mediated Addition of α‐Aminoalkyl Radicals to [60]Fullerene by Using Photoredox Catalysts 下载免费PDF全文
Dr. Yoshihiro Miyake Yuya Ashida Dr. Kazunari Nakajima Prof. Dr. Yoshiaki Nishibayashi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(20):6120-6125
The functionalization of fullerene has been extensively studied and various fullerene derivatives have been synthesized. We have succeeded in the functionalization of [60]fullerene by using α‐aminoalkyl radicals generated by visible‐light‐mediated single‐electron oxidation of α‐silylamines as synthetic intermediates. In these reactions, the introduction of diarylamino groups, which are useful electron donors, has been easily achieved. 相似文献
73.
Ryota Kudo Masahiro Sonobe Yoshiaki Chino Yu Kitazawa Mutsumi Kimura 《Molecules (Basel, Switzerland)》2020,25(23)
The synthesis and characterization of two phthalocyanine (Pc) structural isomers, 1 and 2, in which four 2,6-di(hexyloxy)phenyl units were attached directly to the 1,8,15,22- or 1,4,15,18-positions of the Pc rings, are described. Both Pcs 1 and 2 exhibited low melting points, i.e., 120 and 130 °C respectively, due to the reduction in intermolecular π-π interaction among the Pc rings caused by the steric hindrance of 2,6-dihexyloxybenzene units. The thermal behaviors were investigated with temperature-controlled polarizing optical microscopy, differential scanning calorimetry, powder X-ray diffraction, and absorption spectral analyses. Pc 1, having C4h molecular symmetry, organized into a lamellar structure containing lateral assemblies of Pc rings. In contrast, the other Pc 2 revealed the formation of metastable crystalline phases, including disordered stacks of Pcs due to rapid cooling from a melted liquid. 相似文献
74.
In our previous paper Ohkuwa et al. (2016) corrigendum was found in Eqs. (3.4) and (3.6). However, conclusions of our previous paper are not changed. 相似文献
75.
76.
77.
Porphyrin accumulation onto a self-assembled monolayer (SAM) of imidazole-substituted porphyrins by a supramolecular method to form a chain structure leads to significant increase of light absorption in the visible light region and therefore photocurrents. 相似文献
78.
Akikawa H Ajimura S Chrien RE Eugenio PM Franklin GB Franz J Gang L Imai K Khaustov P May M Pile PH Quinn B Rusek A Sasao J Sawafta RI Schmitt H Tamura H Tang L Tanida K Yuan L Zhou SH Zhu LH Zhu XF 《Physical review letters》2002,88(8):082501
With a germanium detector array (Hyperball), we observed two gamma-ray peaks corresponding to the two transitions (5/2(+)-->1/2(+) and 3/2(+)-->1/2(+)) in the (9)(Lambda)Be hypernucleus which was produced by the 9Be(K-,pi(-)) reaction. The energies of the gamma rays are 3029 +/- 2 +/- 1 keV and 3060 +/- 2 +/- 1 keV. The energy difference was measured to be 31.4(+2.5)(-3.6) keV, which indicates a very small Lambda-spin-dependent spin-orbit force between a Lambda and a nucleon. This is the smallest level splitting by far ever measured in a hypernucleus. 相似文献
79.
Electronic states of P donors in Si nanocrystals (nc-Si) embedded in insulating glass matrices have been studied by electron spin resonance. Doping of P donors into nc-Si was demonstrated by the observation of optical absorption in the infrared region due to intraconduction band transitions. P hyperfine structure (hfs) was successfully observed at low temperatures. The observed splitting of the hfs was found to be much larger than that of the bulk Si:P and depended strongly on the size of nc-Si. The observed strong size dependence indicates that the enhancement of the hyperfine splitting is caused by the quantum confinement of P donors in nc-Si. 相似文献
80.