全文获取类型
收费全文 | 1298篇 |
免费 | 41篇 |
国内免费 | 3篇 |
专业分类
化学 | 933篇 |
晶体学 | 5篇 |
力学 | 53篇 |
数学 | 55篇 |
物理学 | 296篇 |
出版年
2024年 | 1篇 |
2023年 | 9篇 |
2022年 | 23篇 |
2021年 | 41篇 |
2020年 | 32篇 |
2019年 | 30篇 |
2018年 | 19篇 |
2017年 | 15篇 |
2016年 | 35篇 |
2015年 | 37篇 |
2014年 | 56篇 |
2013年 | 96篇 |
2012年 | 94篇 |
2011年 | 105篇 |
2010年 | 67篇 |
2009年 | 59篇 |
2008年 | 81篇 |
2007年 | 83篇 |
2006年 | 74篇 |
2005年 | 67篇 |
2004年 | 57篇 |
2003年 | 44篇 |
2002年 | 50篇 |
2001年 | 34篇 |
2000年 | 28篇 |
1999年 | 16篇 |
1998年 | 9篇 |
1997年 | 6篇 |
1996年 | 11篇 |
1995年 | 11篇 |
1994年 | 7篇 |
1993年 | 8篇 |
1992年 | 7篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 5篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有1342条查询结果,搜索用时 15 毫秒
71.
The first examples of metallodendritic spiranes have been obtained via incorporation of single terpyridine units within each dendritic quadrant. 相似文献
72.
Summary This paper is a further contribution to our work on the Weissenberg effect. One goal of our work is to show how the free-surface deformations on a viscoelastic fluid which is sheared between two concentric rotating cylinders can be used to determine rheological data about the fluid. In this paper we report the results of an experimental program in which free surface shapes have been measured on three viscoelastic fluids undergoing shearing in an apparatus consisting of a stationary outer cylinder and four interchangeable rotating inner cylinders. Experimentally-measured profiles are compared with profiles predicted from second-order theory, and found to be in excellent agreement for STP and TLA-227 in the range of applicability of the second-order theory, but there is some disagreement in the results for a 2% solution of polyacrylamide in 49% water –49% glycerin.
With 12 figures and 1 table 相似文献
Zusammenfassung Diese Arbeit stellt einen weiteren Beitrag zu unseren Untersuchungen über den Weissenberg-Effekt dar. Ein Ziel dieser Untersuchungen ist es zu zeigen, wie die Deformation der freien Oberfläche einer zwischen zwei konzentrischen Zylindern gescherten viskoelastischen Flüssigkeit dazu verwendet werden kann, rheologische Kenngrößen der Flüssigkeit zu gewinnen. In dieser Arbeit wird über die Ergebnisse einer experimentellen Untersuchung berichtet, in der die Gestalt der freien Oberfläche bei drei viskoelastischen Flüssigkeiten gemessen wurde, die in einem Apparat geschert wurden, der aus einem stationären Außenzylinder und vier auswechselbaren rotierenden Innenzylindern bestand. Die experimentell bestimmten Profile werden mit solchen verglichen, die aufgrund einer Theorie zweiter Ordnung vorausgesagt worden sind. Man findet im Bereich der Anwendbarkeit dieser Theorie für STP und TLA-227 eine ausgezeichnete Übereinstimmung, wohingegen die Ergebnisse bei einer 2%igen Polyacrylamid-Lösung in einer 1:1-Wasser-Glycerin-Mischung gewisse Diskrepanzen aufweisen.
With 12 figures and 1 table 相似文献
73.
Lim SC Kim KS Lee IB Jeong SY Cho S Yoo JE Lee YH 《Micron (Oxford, England : 1993)》2005,36(5):471-476
We have installed two nanomanipulators, which can travel about 20mm with a minimum increment of 1 nm, for manipulation of nanostructured materials inside field-emission scanning electron microscope (FE-SEM). Both manipulators render motions in x, y, and z directions, providing various manipulation freedoms such as moving, bending, cutting, and biasing. In addition, we have conducted in situ characterization of the electrical breakdown of multi-walled carbon nanotubes (MWCNTs). Our results demonstrate the possibility that MWCNTs can be used as a gas sensor. 相似文献
74.
Choi WJ Moon HR Kim HO Yoo BN Lee JA Shin DH Jeong LS 《The Journal of organic chemistry》2004,69(7):2634-2636
The preparative and stereoselective synthesis (45-50% overall yields) of the target compound 17 has been accomplished from D-ribose. The bulky protecting groups such as TBDPS and Trityl enforced the facial selectivity during Grignard reaction to give the tertiary beta-allylic alcohol 16 as the sole product, which was oxidatively rearranged to the key molecule 17 in excellent yield. 相似文献
75.
We report the full spectrum of the evolution of the wrinkle pattern formation in a thin bilayer film of an elastic metal on a viscoelastic polymer. Although the origin is different, the transition of an initial islandlike pattern to a labyrinthine structure without any change in the wavelength (q approximately t(0)) and the overall evolutionary process is strikingly similar to that in the spinodal system but the process is robust and takes place on a long time scale (about 10 days). The change into a mountainous topography in the late stages is accompanied by an increase in the length scale from an initial wavelength to another. This change, due to the relaxation of the confined polymer that results in a transition from elastic- to viscouslike behavior, induces wave coarsening (q approximately t(-1.04+/-0.08)) and macroscopic roughening. 相似文献
76.
The polymers containing ribose rings: poly(5'-acrylamido-5'-deoxy-1',2'-O-isopropylidene-alpha-D-ribose) (11), poly(5'-acrylamido-5'-deoxy-alpha-D-ribose) (12) and poly(5'-acrylamido-5'-deoxy-1'-O-methyl-D-ribose) (13) were prepared as enzyme mimics. Polymers 12 and 13 with free vic-cis-diol groups catalyzed the hydrolysis of phosphodiester (ethyl p-nitrophenyl phosphate and N-methylpyridinium 4-tert-butylcatechol cyclic phosphate) and phosphomonoester substrates with a rate acceleration of 10 approximately equal to 10(3) compared with the uncatalyzed reaction. They also catalyzed the reverse reactions, i.e., the esterification of phosphomonoester to phosphodiester and the phosphorylation of alcohols with phosphate ions. The catalytic activity was attributable to the vic-cis-diols of riboses on polymer chains, which formed hydrogen bonds with two phosphoryl oxygen atoms of phosphates so as to activate the phosphorus atoms to be attacked by nucleophiles. The catalytic activity was negligible for polymer 11 where vic-cis-diol groups were blocked with isopropylidene groups. The catalytic activity was attributable to the vic-cis-diols of riboses on polymer chains, which formed hydrogen bonds with two phosphoryl oxygen atoms of phosphates so as to activate the phosphorus atoms to be attacked by nucleophiles. 相似文献
77.
Analysis of vasopressin using capillary electrophoresis with laser-induced fluorescence detector based on competitive immunoassay 总被引:1,自引:0,他引:1
A competitive immunoassay based on CE-LIF has been developed for the determination of vasopressin in biological mixtures. Vasopressin participates in the hormonal control of water metabolism and the constriction of arterioles in humans. Thus, detection of vasopressin is important in diagnosing pathological conditions and physiological water metabolism. The peptides were fluorescently tagged with FITC and purified by HPLC. The purified product was then mixed with the cerebrospinal fluid sample followed with the addition of anti-vasopressin antibody. It was possible to separate antibody-bound and free FITC-tagged vasopressin within 10 min by CE-LIF analysis using uncoated fused-silica capillary with high reproducibility. 相似文献
78.
Cynn H Yoo CS Baer B Iota-Herbei V McMahan AK Nicol M Carlson S 《Physical review letters》2001,86(20):4552-4555
Angle-resolved x-ray diffraction patterns of Xe to 127 GPa indicate that the fcc-to-hcp transition occurs martensitically between 3 and 70 GPa in diamond-anvil cells without an intermediate phase. These data also reveal that the transition occurs by the introduction of stacking disorder in the fcc lattice at low pressure, which grows into hcp domains with increasing pressure. The small energy difference between the hcp and the fcc structures may allow the two phases to coexist over a wide pressure range. Evidence of similar stacking disorder and incipient growth of an hcp phase are also observed in solid Kr. 相似文献
79.
Chanho Kwon Yong-Hoon Choi Namjoon Kim Jong Shin Yoo Chul-Hak Yang Hyun-Won Kim Seunho Jung 《Journal of inclusion phenomena and macrocyclic chemistry》2000,36(1):55-64
Neutral cyclosophoraoses (unbranched cyclic -1,2-d-glucans) produced by the Rhizo-bium meliloti 2011 were prepared by size exclusion and anion-exchange chromatographic techniques. The degree of polymerization (DP) of isolated cyclosophoraoses was determined by matrix associated laser desorption/ionization mass spectrometry (MALDI/MS) techniques. A family of purified neutral cyclosophoraoses (DP 17–27) was used as a host for the inclusion complexation with hardly soluble ergosterol. High performance liquid chromatographic (HPLC) analysis showed that it induced much enhanced solubility of ergosterol compared to -cyclodextrin. In order to understand the molecular basis of the complex forming ability of cyclosophoraoses, a Monte Carlo (MC) docking-minimization method was used for host-guest complex formation of cyclosophoraoses or -cyclodextrin with ergosterol. From the MC simulation we propose the `hand-shake' mechanism for complexation of cyclosophoraoses with ergosterol. 相似文献
80.
Jaya Ram Simkhada Seung Sik Cho Seong Ju Park Poonam Mander Yun Hee Choi Hyo Jeong Lee Jin Cheol Yoo 《Applied biochemistry and biotechnology》2010,162(5):1457-1470
Organic solvent- and detergent-resistant proteases are important from an industrial viewpoint. However, they have been less
frequently reported and only few of them are from actinomycetes. A metalloprotease from Streptomyces olivochromogenes (SOMP) was purified by ion exchange with Poros HQ and gel filtration with Sepharose CL-6B. Apparent molecular mass of the
enzyme was estimated to be 51 kDa by sodium dodecyl sulfate–polyacrylamide gel electrophoresis and gelatin zymography. The
activity was optimum at pH 7.5 and 50 °C and stable between pH 7.0 and 10.0. SOMP was stable below 45 °C and Ca2+ increased its thermostability. Ca2+ enhanced while Co2+, Cu2+, Zn2+, Mn2+, and Fe2+ inhibited the activity. Ethylenediaminetetraacetic acid and ethylene glycol-bis (β-aminoethyl ether)-N,N,N′,N′-tetraacetic acid, but not phenylmethylsulfonyl fluoride, aprotinin, and pefabloc SC, significantly suppressed the activity,
suggesting that it might be a metalloprotease. Importantly, it is highly resistant against various detergents, organic solvents,
and oxidizing agents, and the activity is enhanced by H2O2. The enzyme could be a novel protease based on its origin and peculiar biochemical properties. It may be useful in biotechnological
applications especially for organic solvent-based enzymatic synthesis. 相似文献