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101.
102.
A nitrogen-phosphorus detection-gas chromatographic method, which provides improved sensitivity and selectivity for diphenhydramine, is reported. A 25 m X 0.31 mm cross-linked, 5% phenylmethyl silicone-coated fused-silica capillary column (film thickness 0.52 micron) was used for all analyses. The splitless capillary injection mode was employed with a 2-microliter sample being introduced by an automatic liquid sampler. Standard curves, using orphenadrine as an internal standard, were linear in the range 2-320 ng of diphenhydramine per 0.5 ml of sheep plasma. This represents an amount of diphenhydramine from ca. 40 pg to 6.4 ng at the detector. Chromatographic separation of diphenhydramine and orphenadrine was excellent, with no interference from endogenous plasma constituents. Applicability of the method was demonstrated by a placental transfer study in a chronically instrumented pregnant sheep following a 100 mg intravenous injection of diphenhydramine to the ewe. 相似文献
103.
Kwang Hee Yoo Alexander K. Voice André L. Boehman 《Proceedings of the Combustion Institute》2021,38(4):5529-5538
This study investigates the effects of intermediate temperature heat release (ITHR) on autoignition reactivity of full boiling range gasolines with different octane sensitivity through intake temperature and simulated exhaust gas recirculation (EGR) sweeps in a homogenous charge compression ignition (HCCI) engine. To isolate the ITHR effects, low temperature reactivity was suppressed through the use of high intake temperature and low intake oxygen mole fraction. For quantification of ITHR, a new method was applied to the engine data by examining the maximum value of the second derivative of heat release rate. Combustion phasing comparisons of fuels with octane sensitivity showed that fuel with less octane sensitivity became more reactive as intake temperature and simulated EGR ratio decreased, while fuel with higher octane sensitivity had a reverse trend. For all of the fuels that were tested, the amount of ITHR increased as the intake temperature and oxygen mole fraction increased. These ITHR trends, depending on octane sensitivity, were almost identical with the trends of combustion phasing, showing that ITHR significantly affects fuel autoignition reactivity and determines octane sensitivity. 相似文献
104.
We study two types of dynamical extensions of Lucas sequences and give elliptic solutions for them. The first type concerns a level-dependent (or discrete time-dependent) version involving commuting variables. We show that a nice solution for this system is given by elliptic numbers. The second type involves a non-commutative version of Lucas sequences which defines the non-commutative (or abstract) Fibonacci polynomials introduced by Johann Cigler. If the non-commuting variables are specialized to be elliptic-commuting variables the abstract Fibonacci polynomials become non-commutative elliptic Fibonacci polynomials. Some properties we derive for these include their explicit expansion in terms of normalized monomials and a non-commutative elliptic Euler–Cassini identity. 相似文献
105.
Young Hee Lee Mayavan Viji Eunhwa Lee Hyeju Jo Kyung Yoo Jaeuk Sim Sunhwan Lee Kiho Lee Heesoon Lee Jae-Kyung Jung 《Tetrahedron letters》2017,58(26):2614-2617
During the process development for multistep synthesis of Rosuvastatin calcium several impurities were obtained along with the final Rosuvastatin calcium. Out of this; synthesis of impurity A (acetone adduct) a minor impurity of Rosuvastatin calcium (3R,5S,6E)-7-[4-(4-fluorophenyl)-2-[[(2-hydroxy-2-methylpropyl)sulfonyl(methyl)amino]-6-(1-methylethyl)-pyrimidin-5-yl]-3,5-dihydroxyheptenoicacid hemicalcium salt, is described. The synthesis of impurity A has been accomplished in 6 steps; starting from formation of β-hydroxy sulfonamide as the key intermediate and followed by using convenient routes with overall yield of 13.5%. The target compound can be used as the reference substance of impurity of the Rosuvastatin calcium. 相似文献
106.
In spite of its simplicity and a well-defined theoretical basis, the Flory–Guggenheim approach is conventionally regarded as inapplicable to off-lattice system since the insertion probability of the approach does not account for the excluded region, existing in the off-lattice system. In this work, we propose the insertion probability accounting for the excluded region of off-lattice fluids and derive a new version of equation of state (EOS) for hard-sphere chains basing on the Flory–Guggenheim approach. To investigate the behavior of the excluded regions, a Monte Carlo sampling was performed for hard disks and the various excluded regions were found to have different density dependence. On the basis of the simulation result, we formulated the insertion probability for hard-sphere and that of hard-sphere chain which accounts for the effect of chain-connectivity on the monomer insertion. The proposed insertion probability was found to correctly predict the simulation data for monomer and correctly correlate the simulation data for chain fluids. The resulting EOS was found to meet closed-packed limit and predict the simulation data of compressibility factor for monomer and chains with a reasonable degree of accuracy. When compared with other off-lattice based EOS, it shows a comparable or better result. For second virial coefficient of chain molecules, the model was found to reasonably predict the simulation data. 相似文献
107.
Gjergji Shore Woo‐Jin Yoo Dr. Chao‐Jun Li Prof. Michael G. Organ Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(1):126-133
An effective multi‐component reaction (MCR) protocol has been developed for the construction of propargyl amines from aldehydes, amines and terminal alkynes by using microwave‐assisted continuous‐flow organic synthesis (MACOS). The process is catalysed by thin films of either copper or gold that achieve temperatures in excess of 900 °C when irradiated with low levels of microwave power. The process works equally well for premixed solutions of the three starting materials, or as three separate streams, which improves the combinatorial efficiency of the method. The process tolerates a wide variety of functional groups and heterocycles, and conversion over these diverse substrates ranges from 70–90 %. 相似文献
108.
109.
It is well known that the open-cell voltage (U) of a galvanic cell involving a binary compound, or a multinary compound with a single kind of mobile ionic species, is a state property under a gradient of chemical potential of the mobile component. It is not so transparent, however, whether U is still a state property when involving a ternary or multinary compound with two or more kinds of mobile ions under multiple chemical potential gradients of those mobile components. We clarify this issue with a multinary oxide that conducts oxide ions, protons and electron holes and is exposed to the chemical potential gradients of both water and oxygen. We show that U is path- and history-dependent, and manifests itself along the diffusion paths of the two mobile components H and O under given boundary conditions. 相似文献
110.
An analytical method of CE-MS and CE with an online preconcentration technique induced by a dynamic pH junction, addition of organic solvent and large volume injection was developed for sensitive determination of peptides in biological samples. Leucine enkephalin, methionine enkephalin, dynorphin A, β-endorphin and angiotensin II were used as model peptides. The optimal online preconcentration conditions were obtained at a sample matrix consisting of 100?mM borate buffer (pH 10.0) with 50% v/v acetonitrile and a BGE containing 1?M formic acid at pH 2.0, along with a 25-cm injection length. Under the optimized conditions, a 4.0×10(3)-1.1×10(4)-fold increase in peak intensity was achieved without degrading the peak shape. This online preconcentration method was applied to analyze the intracellular angiotensin II within the peptides extracted from HL1 cells and approximately increase of 1×10(4)-fold sensitivity was achieved compared to normal condition. Thus, the developed method could be applied to the analysis of various peptides for peptidomics study in biological samples. 相似文献