Preparation of sulfur‐quinone polyurethanes and their use to inhibit the corrosion of iron particles

A sulfur‐quinone diol monomer, 2,5‐bis‐(2‐hydroxyethylthio)‐1,4‐benzoquinone (SQM‐2), was prepared by the reaction of 2‐mercaptoethanol with benzoquinone. SQM‐2 and polycaprolactone diol (number‐average molecular weight = 1250) were condensed with toluene diisocyanate to give sulfur‐quinone polyurethanes. Two compositions were prepared, SQPU‐1 containing 7 mol % SQM‐2 and SQPU‐2 containing 35 mol % SQM‐2. These thermoplastic polyurethanes were soluble in solvents used in magnetic tape coating processes. The polymers were used to prepare magnetic coatings containing state‐of‐the‐art commercial iron particles. The sulfur‐quinone polyurethanes protected the iron particles against corrosion from a pH 2.0 aqueous buffer. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 3278–3283, 2000     

凤眼莲对铜离子的生物吸附研究

为探讨滇池凤眼莲对水中重金属离子Cu2 的吸附特性,考察了pH、时间、吸附剂量、浓度等因素对吸附能力的影响,进行了实验室吸附试验,绘制出吸附等温线,并由Langmuir曲线求出相应参数.对凤眼莲进行了脱附-再生实验.分析了吸附机理.结果表明,在pH3.5～5.5范围内,凤眼莲对Cu"有吸附作用,饱和吸附量可达35.6mg/g,吸附等温式为Cf/q=0.027Cf 0.114.用0.5mol/LHCl和NaOH可使其脱附与再生.     

2,7,16,21-四氧[8.8]对环吩-1,8,15,22-四酮的~1H-NMR研究

2,7,16,21-四氧[8.8]对环吩-1,8,15,22-四酮是一个新的大环化合物。由于它的苯环不能自由转动,而苯环上的质子是化学位移不等价的。这给研究羰基的屏蔽和去屏蔽区域提供了一个很好的例证。     

Transmission and reflection navigated optical probe with depth-tuned surface corrugations

An optical probe with a single aperture flanked by depth-tuned surface corrugations is presented. It can generate enhanced optical transmission at the exit of a slit and lower reflection at the top side of the compound dielectric/metal structure. The probe is designed and discussed on the basis of enhanced surface plasmon resonance for the purpose of high-resolution inspection use. A multidielectric probe consisting of air/glass/C/Ag/air is put forward. The influence of the thickness of the carbon film on the reduction of reflection is analyzed in detail combined with the relevant funneling effect induced by waveguide mode propagation through a central slit. Our simulation results show that a carbon film with a thickness of 150 nm and a 200-nm Ag film with the designed parabolic corrugations can reach our design target of the enhanced optical transmission and minimum reflection. PACS 02.60.Cb; 02.70.Bf; 07.79.Fc; 42.25.Bs     

离子型膦配体及其离子型过渡金属配合物的合成和均相催化作用

与传统中性叔膦配体构建的过渡金属配合物相比,由离子型膦配体配位构建的过渡金属配合物具有典型的离子盐组成特点、独特的电子效应和几何构型。该类配合物中,不仅存在金属和配体间的配位作用,还存在正电荷的强吸电子效应和阴阳离子的静电作用,由此可以产生独特的催化性能。近年来,离子型过渡金属配合物的合成及其均相催化应用成为配位化学和均相催化研究中备受关注的领域。离子型过渡金属配合物的离子盐结构,使其在与室温离子液体溶剂结合使用时,离子型离子配体及其配合物能够严格被锁定在离子液体相,具有避免离子型离子配体及其配合物的流失、抑制其失活、并实现循环使用的优点,也成为均相催化固载化的绿色方法之一。本文综述了近十年发展的一类咪唑鎓基与膦配体中的磷原子毗邻的离子型膦配体的合成,及其相应Rh、Pd、Ru、Pt、Au、Ni、Cu等离子型配合物的构建,并介绍了它们在均相催化反应中的应用。     

控制断裂能量与爆破效果的分形分析

定向断裂爆破与普通光爆、预裂相比，爆破效果明显提高，爆破能量利用更为合理。文中根据爆破断裂的分形研究，阐述了控制断裂爆破改进周边成形质量，提高爆炸能量利用率的力学机制。     

河南宝泉抽水蓄能电站近场区断裂活动特征及对兴建电站的稳定性评价

本文通过野外调查和人工地震反射剖面法对河南宝泉抽水蓄能电站近场区内的断裂进行了详细的研究, 结果表明近场区内的断裂活动在晚更新世以来均已停止, 断裂活动将不会影响该电站的稳定性。     

Do Intrinsically Disordered Proteins Possess High Specificity in Protein–Protein Interactions?

Specific protein–protein interactions are critical to cellular function. Structural flexibility and disorder‐to‐order transitions upon binding enable intrinsically disordered proteins (IDPs) to overcome steric restrictions and form complementary binding interfaces, and thus, IDPs are widely considered to have high specificity and low affinity for molecular recognition. However, flexibility may also enable IDPs to form complementary binding interfaces with misbinding partners, resulting in a great number of nonspecific interactions. Consequently, it is questionable whether IDPs really possess high specificity. In this work, we investigated this question from a thermodynamic viewpoint. We collected mutant thermodynamic data for 35 ordered protein complexes and 43 disordered protein complexes. We found that the enthalpy–entropy compensation for disordered protein complexes was more complete than that for ordered protein complexes. We further simulated the binding processes of ordered and disordered protein complexes under mutations. Simulation data confirmed the observation of experimental data analyses and further revealed that disordered protein complexes possessed smaller changes in binding free energy than ordered protein complexes under the same mutation perturbations. Therefore, interactions of IDPs are more malleable than those of ordered proteins due to their structural flexibility in the complex. Our results provide new clues for exploring the relationship between protein flexibility, adaptability, and specificity.     

Direct measurement of microscopic strain distribution near a crack tip

A dot map method was used for direct measurement of the microscopic strain field near a crack tip in a rubber-toughened epoxy. Results indicate that very large viscoelastic strains (37 percent) are present at the crack tip, though elongation in a tensile test is only 5.1 percent. Most of the strain is recovered immediately on unloading, and all of the remaining strain is recovered after annealing above the glass transition temperature.     

GPS RTK技术用于滑坡动态实时变形监测的研究

为了研究GPS RTK技术用于滑坡动态变形监测的精度和可靠性,本文结合某类滑坡的大型物理模型试验,在滑坡体上布设了若干监测点,并用GPS RTK技术、全站仪三维测量技术和GPS单历元定位技术实时跟踪监测了该滑坡在自然状态下从稳定到产生破坏的全部过程。通过对监测数据的处理和分析,获得了RTK技术用于滑坡变形监测的可靠性和精度等技术参数,即在基准站和流动站同步观测到的卫星数在7颗以上且RTK系统的数据链能够正常工作的情况下,RTK测量的平面和高程精度就能分别控制在15mm和20mm以内。研究结果表明,RTK技术在一定条件下完全可用于滑坡灾害的动态实时变形监测。