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991.
采用经典分子动力学方法模拟一定直径[111]晶向的硅纳米线填充不同扶手椅型单壁碳纳米管复合结构的加热过程, 通过可视化和能量分析的方法判断复合结构中硅纳米线和碳纳米管的热稳定性. 通过讨论碳纳米管的空间限制作用和分子间相互作用力的关系, 对碳纳米管和硅纳米线的热稳定性变化进行初步解释. 研究发现碳纳米管中硅纳米线的热稳定性和碳纳米管的直径关系密切: 当管径较小时, 硅纳米线的热稳定性有所提高, 当管径增大到一定大小时, 硅纳米线的热稳定性会突然显著地下降, 直到硅纳米线与管壁不存在分子间相互作用力, 硅纳米线的热稳定性才会恢复. 而硅纳米线填充到碳纳米管中对碳纳米管的热稳定性有着明显的降低作用. 相似文献
992.
本文提出一种新型函数光子晶体, 其折射率是空间位置函数. 由费马原理, 我们给出光在一维、 二维和三维函数光子晶体中的运动方程, 以及一维函数光子晶体的色散关系、 带隙结构和透射率, 再利用传输矩阵理论研究函数光子晶体周期数、 入射角和介质层的厚度等对透射率和禁带结构的影响, 计算发现通过选择不同的折射率空间分布函数, 可以得到比传统光子晶体更宽或更窄的禁带结构. 这样为我们设计不同带隙结构的光子晶体提供理论依据. 相似文献
993.
Ce3+ and Tb3+ co-doped Sr2B5O9Cl phosphors with intense green emission were prepared by the conventional high-temperature solid-state reaction technique. A broad band centered at about 315 nm was found in phosphor Sr2B5O9Cl: Ce3+, Tb3+ excitation spectrum, which was attributed to the 4f-5d transition of Ce3+. The typical sharp line emissions ranging from 450 to 650 nm were originated from the 5D4 → 7FJ (J = 6, 5, 4, 3) transitions of Tb3+ ions. The photoluminescence (PL) intensity of green emission from Tb3+ was enhanced remarkably by co-doping Ce3+ in the Tb3+ solely doped Sr2B5O9Cl phosphor because of the dipole-dipole mechanism resonant energy transfer from Ce3+ to Tb3+ ions. The energy transfer process was investigated in detail. In light of the energy transfer principles, the optimal composition of phosphor with the maximum green light output was established to be Sr1.64Ce0.08Tb0.1Li0.18B5O9Cl by the appropriate adjustment of dopant concentrations. The PL intensity of Tb3+ in the phosphor was enhanced about 40 times than that of the Tb3+ single doped phosphor under the excitation of their optimal excitation wavelengths. 相似文献
994.
Residual microstructures associated with hypervelocity impact craters in 55 vol.% TiB(2)/2024Al composite were investigated by transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM). TiB(2)-Al interface, TiB(2) particles and Al matrix before and after hypervelocity impact were compared to discuss the effect of hypervelocity impact. A new Al(x)O(1-x) phase with the fcc structure and the crystal parameter of 0.69 nm was formed at TiB(2)-Al interface. Stacking fault with width of 10-20 nm was formed along the (001) plane of TiB(2) particle. Formation of nanograins (≈ 100 nm) was observed within Al matrix, moreover, lamellar S' phase was transformed into lenticular or spherical S phase after hypervelocity impact. 相似文献
995.
5种丹参主要成分及微结构的检测及综合表征 总被引:1,自引:0,他引:1
利用X射线荧光(XRF)、粉末X射线衍射(PXRD)和傅里叶变换红外光谱(FTIR)分析技术,对安国栽培的5个不同种质丹参主要成分及微结构检测,对各样品中多种元素种类及含量、晶体及非晶体成分以一套综合特征图的方式对其表征;该谱将同种属不同种质丹参中的共有成分和细微差异之处给与直观地描述。3种技术共有制样简单,测定速度快,再现性和客观性好的特点;可用于药材优良品种的选育、中药材GAP种植条件的指导、药材产地特征、主要成分及微结构的检测及表征、质量稳定性的控制及真伪鉴别。 相似文献
996.
First-principle calculations based on density function theory (DFT) are used to clarify the roles of γ-Fe2O3 in fly ash for removing mercury from coal-fired flue gases. In this study, the structure of key surface of γ-Fe2O3 is modeled and spin-polarized periodic boundary conditions with the partial relaxation of atom positions are employed. Binding energies of Hg on γ-Fe2O3 (0 0 1) perfect and defective surfaces are calculated for different adsorption sites and the potential adsorption sites are predicted. Additionally, electronic structure is examined to better understand the binding mechanism. It is found that mercury is preferably adsorbed on the bridge site of γ-Fe2O3 (0 0 1) perfect surface, with binding energy of −54.3 kJ/mol. The much stronger binding occurs at oxygen vacancy surface with binding energy of −134.6 kJ/mol. The calculations also show that the formation of hybridized orbital between Hg and Fe atom of γ-Fe2O3 (0 0 1) is responsible for the relatively strong interaction of mercury with the solid surface, which suggests that the presently described processes are all noncatalytic in nature. However, this is a reflection more of mercury's amalgamation ability. 相似文献
997.
Time evolution of information entropy for a stochastic system with double singularities driven by quasimonochromatic noise 下载免费PDF全文
<正>This paper deals with the time evolution of information entropy for a stochastic system with double singularities driven by quasimonochromatic noise.The dimension of the Fokker-Planck equation is reduced by the linear transformation. The exact expression of the time dependence of information entropy is obtained based on the definition of Shannon’s information entropy.The relationships between the properties of dissipative parameters,system singularity strength parameter,quasimonochromatic noise,and their effects on information entropy are discussed. 相似文献
998.
Analysis on electrical characteristics of high-voltage GaN-based light-emitting diodes 总被引:1,自引:0,他引:1 下载免费PDF全文
<正>In order to investigate their electrical characteristics,high-voltage light-emitting-diodes(HV-LEDs) each containing four cells in series are fabricated.The electrical parameters including varying voltage and parasitic effect are studied. It is shown that the ideality factors(IFs) of the HV-LEDs with different numbers of cells are 1.6,3.4,4.7,and 6.4.IF increases linearly with the number of cells increasing.Moreover,the performance of the HV-LED with failure cells is examined.The analysis indicates that the failure cell has a parallel resistance which induces the leakage of the failure cell.The series resistance of the failure cell is 76.8Ω,while that of the normal cell is 21.3Ω.The scanning electron microscope(SEM) image indicates that different metal layers do not contact well.It is hard to deposit the metal layers in the deep isolation trenches.The fabrication process of HV-LEDs needs to be optimized. 相似文献
999.
We investigate the temperature dependence of radiation-induced attenuation (RIA) at 1 310 nm for a Ge/P co-doped fiber after a steady-state γ-ray irradiation.A γ irradiation facility 60Co source is used to irradiate the fiber at a dose rate of 0.5 Gy/min,satisfying a total dose of 100 Gy.The test temperature ranges from-40 to 60℃ by 20℃,and the RIA of the fiber is obtained using a power measuring device.The experimental result demonstrates that RIA exhibits a steady,monotonic,and remarkable temperature dependence after approximately 48h of accelerated annealing at 70℃.The optical fiber irradiated with a high dose and annealed sufficiently can be used as a temperature sensor. 相似文献
1000.