Cobalt-doped mesoporous titania with a crystalline framework synthesized by surfactant templating method presented highly selective (99%) and reasonable conversion rate (49%) of catalytic oxidation of para-chlorotoluene to para-chlorobenzaldehyde in acetic acid using aqueous hydrogen peroxide as oxidant for the first time. Recycling of the catalyst indicates that the catalyst can be used a number of times without losing its activity to a greater extent. By contrast, cobalt-doped mesoporous titania without a crystalline structure and cobalt doped the commercial titania, Degussa P25 prepared by impregnation method with the similar concentration of cobalt were found inactive. The effects of catalyst concentration, reaction time, reaction temperature, and solvents on the performance of the catalyst were also investigated. 相似文献
A functional equation of nonlinear iterates is discussed on the circle S1 for its continuous solutions and differentiable solutions. By lifting to R, the existence, uniqueness and stability of those solutions are obtained. Techniques of continuation are used to guarantee the preservation of continuity and differentiability in lifting. 相似文献
Chitosan/magnetite nanocomposite was synthesized induced by magnetic field via in situ hybridization in ambient condition. Results of XRD patterns and TEM micrographs indicated that magnetite particles with 10–20 nm were dispersed in chitosan homogeneously. An interesting result is that magnetite nanoparticles were assembled to form chain-like structures under the influence of the external magnetic field, which mimics the magnetite chains inside of magnetotatic bacteria. The saturated magnetization (Ms) of nano-magnetite in chitosan was 50.54 emu/g, which is as high as 54% of bulk magnetite. The remanence (Mr) and coercivity (Hc) were 4 emu/g and14.8 Oe, respectively, which indicated that magnetite nanoparticles were superparamagnetic. The key of route is that a pre-precipitated chitosan hydrogel membrane, used as chemical reactor, which controlled the precipitation of chitosan precipitation and in situ transformation of magnetite from the precursor simultaneously in the magnetic field environment. 相似文献
We report on the status of the LPCTrap experiment, devoted to measure the β–ν angular correlation in the pure Gamow–Teller
decay of 6He. This measurement is motivated by the search for the presence of tensor type contributions to the weak interaction. The
6He ions are confined in a novel transparent Paul trap. The β particles and the recoil ions are detected in coincidence to
deduce the angular correlation parameter. The commissioning run performed in 2005 has given the proof of principle of this
experiment. Up to 105 coincidences were recorded during a second run in 2006. 相似文献
In this article the author works with the ordinary differential equation u" = |u|^p for some p 〉 0 and obtains some interesting phenomena concerning blow-up, blow-up rate, life-span, stability, instability, zeros and critical points of solutions to this equation. 相似文献
In the present paper, a Lotka–Volterra type mutualism system with several delays is studied. Some new and interesting sufficient conditions are obtained for the global existence of positive periodic solutions of the mutualism system. Our method is based on Mawhin’s coincidence degree and novel estimation techniques for the a priori bounds of unknown solutions. Our results are different from the existing ones such as those in of Yang et al. [F. Yang, D. Jiang, A. Ying, Existence of positive solution of multidelays facultative mutualism system, J. Eng. Math. 3 (2002) 64–68] and Chen et al. [F. Chen, J. Shi, X. Chen, Periodicity in a Lotka–Volterra facultative mutualism system with several delays, J. Eng. Math. 21 (3) (2004) 403–409]. 相似文献
Based on solving the couple mode equation numerically, the characterization of the signal power on the gate power was analyzed. And the relationship of the tolerance of the grating period and the bulk temperature on the interaction length was analyzed. 相似文献
The paper deals with the stress, displacement, pore and fissure pressures fields induced by the drilling and/or the pressurization of a vertical borehole in a formation of water-saturated porous media with double porosity. The solution includes the boundary condition of non-hydrostatic in situ state of stress. The solid skeleton is assumed to behave as a linearly poroelastic material with compressible constituents. The analytical solution is derived in Laplace’s space and transformed to the time domain using a numerical inversion technique. The histories of pore and fissure pressures are illustrated to show the influence of permeabilities of the pore and fissure systems. 相似文献
A model for parallel and distributed programs, the dynamic process graph (DPG), is investigated under graph-theoretic and complexity aspects. Such graphs embed constructors for parallel programs, synchronization mechanisms as well as conditional branches. They are capable of representing all possible executions of a parallel or distributed program in a very compact way. The size of this representation can be as small as logarithmic with respect to the size of any execution of the program.
In a preceding paper [A. Jakoby, et al., Scheduling dynamic graphs, in: Proc. 16th Symposium on Theoretical Aspects in Computer Science STACS'99, LNCS, vol. 1563, Springer, 1999, pp. 383–392] we have analysed the expressive power of the general model and various variants of it. We have considered the scheduling problem for DPGs given enough parallelism taking into account communication delays between processors when exchanging data. Given a DPG the question arises whether it can be executed (that means whether the corresponding parallel program has been specified correctly), and what is its minimum schedule length.
In this paper we study a subclass of dynamic process graphs called
-output DPGs, which are appropriate in many situations, and investigate their expressive power. In a previous paper we have shown that the problem to determine the minimum schedule length is still intractable for this subclass, namely this problem is
-complete as is the general case. Here we will investigate structural properties of the executions of such graphs. A natural graph-theoretic conjecture that executions must always split into components that are isomorphic to subgraphs turns out to be wrong. We are able to prove a weaker property. This implies a quadratic upper bound on the schedule length that may be necessary in the worst case, in contrast to the general case, where the optimal schedule length may be exponential with respect to the size of the representing DPG. Making this bound constructive, we obtain an approximation to a
-complete problem. Computing such a schedule and then executing the program can be done on a parallel machine in polynomial time in a highly distributive fashion. 相似文献