Two New Lignans from Phryma leptostachya L.

Haedoxancoside A ( 1 ), a new sesquilignan glycoside, and phrymarolin V ( 2 ), a new lignan, together with two known compounds, were isolated from Phryma leptostachya L. Their structures were determined on the basis of comprehensive spectroscopic analysis, mainly 1D‐ and 2D‐NMR spectroscopy as well as mass spectrometry. This is the first report of a sesquilignan glycoside isolated from a species of the Phrymaceae family.     

A pair of epimeric cassane-type diterpenoids and a new labdane-type derivative from Caesalpinia decapetala

Caesaldecins A and B (1a/1b), a pair of epimeric cassane-type diterpenoids containing an ether linkage between C-6 and C-20 and an α,β-butenolide ring in the northern hemisphere, were isolated from the leaves of the medicinal plant Caesalpinia decapetala (Roth) Alston, along with a new labdane-type diterpenoid, termed as 8(17),11(Z),13(E)-trien-15,18-dioic acid (2). Structures of 1 and 2 were established by extensive spectroscopic analyses, including HRESIMS, 1D and 2D NMR, and electronic circular dichroism (ECD) calculations. The in vitro antibacterial and inhibitory activities against a panel of bacteria and cancer cell lines were evaluated, respectively. Compound 2 displayed moderate antibacterial activity against the methicillin-resistant Staphylococcus aureus subsp. aureus (MRSA) with an MIC₅₀ value of 5.99?μg?mL^?1.     

Density-Dependence of Nuclear Symmetry Energy: Role of QCD Chiral Phase Transition

The density-dependence of symmetry energy is of particular importance to many problems in nuclear physics and astrophysics. By using the functional path integral method, we show explicitly the relation between nuclear symmetry energy and isospin susceptibility. The latter one is found to be a probe to the QCD chiral phase transition. We further found in the Nambu-Jona-Lasinio model calculations that, the nuclear symmetry energy has an abrupt change at the critical nuclear density where the chiral symmetry restores partially.     

Functional mesoporous poly (ionic liquid) derived from P123: From synthesis to catalysis and alkylation of styrene and o‐xylene

A novel strategy was proposed for the fabrication of high‐performance acidic mesoporous poly ionic liquids catalyst. In this work, mesoporous poly ionic liquids (MPILs) were synthesized with P123 (PEO₂₀PPO₇₀PEO₂₀) served as pore‐forming agent. Then, MPILs were treated with PW^3? anion exchange, thereby fabricating PW/MPIL‐S(x). MPIL and PW/MPIL‐S(x) were characterized by scanning electron microscope (SEM), transmission electron microscopy (TEM), Thermogravimetric analysis (TA), N₂ adsorption–desorption and Fourier transform infrared (FT‐IR) spectra and X‐ray photoelectron spectroscopy (XPS) spectra. The effect of solvent and concentration of P123 on the morphology and mesoporous structure of MPILs were investigated systematically. And the results show that MPILs were featured with mesoporous channel structure, high surface area (up to 737 m²/g) and large pore volumes (1.16 cm³/g), which benefit heterogeneous phase reaction (such as, alkylation of styrene with o‐xylene). In the alkylation reaction, under optimal reaction conditions, the catalyst PW/MPIL‐THF (4.0 g) shows high conversion of styrene (100%) and PXE yield (96.21%), demonstrating the excellent catalytic activities. Furthermore, PW/MPIL‐S(x) are easy to be separated from the catalytic system by filtration and show no obvious decrease in catalytic activity after 6 cycle runs. The obtained PW/MPIL‐S(x) catalyst exhibit high thermal and mechanical stability as well, indicating extensive application in high temperature acidic catalysis. This work might open up a new method for the synthesizing of porous polymer catalysts in the future.     

混合模型中方差分量估计的容许性及非负估计

对含有两个方差分量的线性混合模型, 本文构造了方差分量的一个线性估计类, 它包含许多常见的方差分量估计. 在这个类中我们建立了容许性的必要条件, 据此得到了两个新的改进估计. 最后我们讨论了方差分量的非负估计, 得到了优于方差分析估计和Tatsuya估计的正估计.     

应变率及节理倾角对岩石模拟材料动力特性的影响

采用相似材料模拟实验方法并借助SHPB(split Hopkinson pressure bar)实验系统,探究应变率及节理倾角对节理岩石动态力学性状的影响,包括应力应变曲线特征、破坏模式、能量传递及耗散规律。该实验结果表明：应变率升高,动态弹性模量增大,试件破碎块度变小,完整试件裂纹缺陷沿着平行于压应力方向扩展;节理角度越大,峰值强度越低,但当应变率升高到一定程度,节理角度对岩石破坏形态的影响不再明显;不同试件的入射能、反射能、透射能和耗散能均随应变率升高呈非线性增加,含倾斜角度节理试件的能量耗散率随应变率的变化幅度明显大于完整试件。

     

合肥光源40 kW高频固态发射机的研制进展

介绍了用于合肥光源800 MeV电子储存环高频系统的204 MHz,40 kW固态发射机的研制进展。该发射机为双塔结构,由130个330 W功放模块进行三级合成。其关键部件的样件包括10路功放和2.5 kW八合一,20 kW八合一以及40 kW二合一功率合成器各1件的制作和测试已完成。测得各合成器输出端驻波比不超过1.05,功放模块的增益达到26 dB,幅相偏差小于0.1 dB和5°,达到设计要求。     

一种动力响应混合快速分析方法及其在功能梯度材料板瞬态响应分析中的应用

提出了一种把减基法嵌套在Newmark法中快速求解动力问题的混合算法.这种算法把Newmark法作为动力问题的基本求解器.而在嵌套减基法时,把参数样本空间对应的解集做成一个训练空间,采用贪婪算法进行减基空间基向量的自适应选取,进而由减基空间得到减缩系统.通过求解减缩系统对应的Newmark增量式来达到快速求解动力问题的目的.最后采用了一个无限大的功能梯度材料板的瞬态响应分析来验证文中方法的高效性和精确性.     

基于三维各向异性分形理论的固定机械结合面法向接触刚度建模研究

将结合面接触点拓展为椭圆形,基于KE有限元模型,类比球形微凸体在弹塑性接触变形阶段法向载荷、接触面积以及变形量之间的关系,采用代入法得到了表征椭圆抛物面形微凸体弹塑性接触变形机制的对应关系式.假设结合面接触点离心率分布与接触点面积分布相互独立,根据概率论以及接触点的面积大小分布函数,获得了关于结合面接触点面积与离心率的二维联合分布密度函数,进而依据三维各向异性分形几何理论建立了包含微凸体完全弹性、弹塑性以及完全塑性三种变形机制的结合面法向接触刚度分形模型.所建模型理论刚度与实验数据的对比结果,表明了模型的正确性及有效性,能较好的预测在轻载状态下的固定结合面法向接触刚度.     

Highly Ordered Mesoporous Tungsten Oxides with a Large Pore Size and Crystalline Framework for H2S Sensing

An ordered mesoporous WO₃ material with a highly crystalline framework was synthesized by using amphiphilic poly(ethylene oxide)‐b‐polystyrene (PEO‐b‐PS) diblock copolymers as a structure‐directing agent through a solvent‐evaporation‐induced self‐assembly method combined with a simple template‐carbonization strategy. The obtained mesoporous WO₃ materials have a large uniform mesopore size (ca. 10.9 nm) and a high surface area (ca. 121 m² g^?1). The mesoporous WO₃‐based H₂S gas sensor shows an excellent performance for H₂S sensing at low concentration (0.25 ppm) with fast response (2 s) and recovery (38 s). The high mesoporosity and continuous crystalline framework are responsible for the excellent performance in H₂S sensing.