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91.
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93.
Guocheng Zhu Yongning Bian Andrew S. Hursthouse Peng Wan Katarzyna Szymanska Jiangya Ma Xiaofeng Wang Zilong Zhao 《Journal of fluorescence》2017,27(6):2069-2094
Natural organic matter (NOM) found in water sources is broadly defined as a mixture of polyfunctional organic molecules, characterized by its complex structure and paramount influence on water quality. Because the inevitable release of pollutants into aquatic environments due to an ineffective control of industrial and agricultural pollution, the evaluation of the interaction of NOM with heavy metals, nanoparticles, organic pollutants and other pollutants in the aquatic environment, has greatly increased. Three-dimensional (3-D) fluorescence has the potential to reveal the interaction mechanisms between NOM and pollutants as well as the source of NOM pollution. In water purification engineering system, the 3-D fluorescence can indicate the variations of NOM composition and gives an effective prediction of water quality as well as the underline water purification mechanisms. Inadequately treated NOM is a cause of precursors of disinfection byproducts (DBPs), posing a potential threat to human health. Effective control and measurement/evaluation of NOM have long been an important factors in the prevention of water pollution. Overall, 3-D fluorescence allows for a rapid identification of organic components thus indicating possible sources of water pollution, mechanisms of pollutant interactions, and possible DBPs formed during conventional treatment of this water. This article reviews the 3-D fluorescence characteristics of NOM in natural water and typical water purification systems. The 3-D fluorescence was effective for indicating the variabilities in NOM composition and chemistry thus providing a better understanding of NOM in natural water system and water engineering system. 相似文献
94.
Rui Han XiangQing Li WeiGuang Jiang ZhiHuan Li Hui Hua ShuangQuan Zhang CenXi Yuan DongXing Jiang YanLin Ye Jing Li ZongHao Li FuRong Xu QiBo Chen Jie Meng JianSong Wang Chuan Xu YeLei Sun ChunGuang Wang HongYi Wu ChenYang Niu ChenGuang Li Chao He Wei Jiang PengJie Li HongLiang Zang Jun Feng SiDong Chen Qiang Liu XiaoChi Chen HuShan Xu ZhengGuo Hu YanYun Yang Peng Ma JunBing Ma ShiLun Jin Zhen Bai MeiRong Huang YuanJie Zhou WeiHu Ma Yong Li XiaoHong Zhou YuHu Zhang GuoQing Xiao WenLong Zhan 《中国科学:物理学 力学 天文学(英文版)》2017,60(4):042021
95.
PGP模块是超光谱成像仪中重要分光器件。为了能够在制作前有效预测PGP整个系统的衍射效率分布及其衍射特性,提出了PGP整体化设计方法。从体位相全息光栅设计角度出发,结合棱镜与光栅各项参数的制约关系,编制了计算PGP整体衍射效率的分析软件,综合考察了棱镜与光栅各项参数对PGP模块衍射特性的影响,讨论了光栅布拉格波长的漂移特性,据此设计了一种用于成像光谱仪的宽波段高衍射效率PGP分光模块。模拟结果表明:棱镜1材料的色散系数越小,PGP的光谱带宽越窄;光栅布拉格波长的漂移增大了PGP模块和光栅的光谱带宽,带宽增大使光栅的角度选择性随之增大,拓宽了棱镜1材料的选择要求;棱镜1顶角、光栅的胶层厚度和相对介电常数调制度等参数是影响PGP衍射效率分布的重要因素,制作时需要精确控制。利用此方法设计的PGP分光模块在400~1 000 nm波段范围内衍射效率不低于50%,并给出具体设计参数,这对PGP制作具有一定的参考价值。 相似文献
96.
Metal/semiconductor hybrids consisting of self-assembled CdS nanoparticles on Cd nanowires 下载免费PDF全文
We report on the synthesis and the characterisation of
metal/semiconductor hybrids consisting of self-assembled CdS
nanoparticles on Cd nanowires, which are grown by thermal
evaporation of the mixture of CdS and Cr. The growth of the hybrids
is attributed to the decomposition of CdS at high temperature and
the strain relieving that arises mainly from the lattice mismatch
between Cd and CdS. Temperature dependence of zero-field resistance
of single nanohybrid indicates that the as-produced Cd/CdS
nanohybrid undergoes a metal--semiconductor transition as a natural
consequence of hybrid from metallic Cd and semiconducting CdS. The
metal/semiconductor hybrid property provides a promising basis for
the development of novel nanoelectronic devices. 相似文献
97.
Xiaofeng Peng 《Applied Surface Science》2009,255(8):4384-4388
A novel approach is presented for nanohole 3D-size tailoring. The process starts with a monolayer of polystyrene (PS) beads spun coat on silicon wafer as a template. The holes can be directly prepared through combustion of PS beads by oxygen plasma during metal or oxide thin film deposition. The incoming particles are prevented from adhering on PS beads by H2O and CO2 generated from the combustion of the PS beads. The hole depth generally depends on the film thickness. The hole diameter can be tailored by the PS bead size, film deposition rate, and also the combustion speed of the PS beads. In this work, a series of holes with depth of 4-24 nm and diameter of 10-36 nm has been successfully prepared. The hole wall materials can be selected from metals such as Au or Pt and oxides such as SiO2 or Al2O3. These templates could be suitable for the preparation and characterization of novel nanodevices based on single quantum dots or single molecules, and could be extended to the studies of a wide range of coating materials and substrates with controlled hole depth and diameters. 相似文献
98.
Weifeng Yang Dong-Liang Peng Huolin Huang Zhengyun Wu 《Applied Surface Science》2009,255(11):5669-5673
Transparent conductive Al-doped zinc oxide (AZO) films with highly (0 0 2)-preferred orientation were deposited on quartz substrates at room temperature by RF magnetron sputtering. Optimization of deposition parameters was based on RF power, Ar pressure in the vacuum chamber, and distance between the target and substrate. The structural, electrical, and optical properties of the AZO thin films were investigated by X-ray diffraction, Hall measurement, and optical transmission spectroscopy. The 250 nm thickness AZO films with an electrical resistivity as low as 4.62 × 10−4 Ω cm and an average optical transmission of 93.7% in the visible range were obtained at RF power of 300 W, Ar flow rate of 30 sccm, and target distance of 7 cm. The optical bandgap depends on the deposition condition, and was in the range of 3.75-3.86 eV. These results make the possibility for light emitting diodes (LEDs) and solar cells with AZO films as transparent electrodes, especially using lift-off process to achieve the transparent electrode pattern transfer. 相似文献
99.
提出了一种简单直观的方法研究光致变色材料二芳基乙烯/PMMA膜的抗疲劳特性.通过测量样品在漂白和呈色过程中探测光的透过率,分析该样品光致变色过程的最佳曝光量,在此基础上测量样品的抗疲劳特性.结果显示:在漂白和呈色过程中,激发红光和紫光的最佳曝光量为分别为1 900 J/cm2和600 mJ/cm2,表明该材料对红光不敏感,对紫光比较敏感.定义漂白-呈色过程中,探测光透过率稳定值差下降为第一次循环的50%时样品已经疲劳.通过交替的漂白-呈色循环,测得这种二芳基乙烯材料的擦写次数为27次. 相似文献
100.
In this paper, a generalized Kolmogorov-Sinai-like entropy ( entropy) in the sense of Tsallis is proposed with a nonextensive parameter q under Markov shifts, which contains the classical Kolmogorov-Sinai (KS) entropy and the Rényi entropy as well as Bernoulli shifts as special cases. To verify the formula of this entropy, a one-dimensional iterative system is chosen as an example of Markov shifts, and its entropy is evaluated by a new refinement method of symbolic dynamics called symbolic refinement which differs from the conventional numerical method. The numerical results show that this entropy is monotonically decreasing as q increases. 相似文献