上海光源同步辐射空间干涉仪研制

 研制了上海光源同步辐射空间干涉仪,用于储存环束团横向截面尺寸及发射度的精确测量。对干涉仪工艺设计中的光路参数、关键设备选型、数据处理方法及数据采集处理软件结构进行了分析讨论。结合束流实验完成了系统调试及运行参数优化,结果表明,CCD增益系数与曝光时间设置对测量精度有显著影响,增益系数设为0 dB,曝光时间设为200 ms时,随机测量误差可控制在μm量级。对上海光源储存环横向束斑尺寸进行了精确测量,结果表明:空间相干度曲线近似为高斯分布,可以采用单一空间频率的相干度测量值进行快速束斑尺寸计算;水平束斑尺寸实测值为52.4 μm,与理论值预期值53.0 μm相比,差异小于2%;系统测量误差约为5.5%,主要误差来源为相干度随机测量误差。     

MONTE CARLO SIMULATION OF THE SURFACE REDOX MECHANISM OF WATER GAS SHIFT REACTION I. CONVERSION OF ADSORBED OH TO OXYGEN ADATOM

The surface redox mechanism of water gas shift reaction was explored by Monte Carlo simulation. The surface modeling with the consideration of experimental results reveals that the conversion of OH* to O* takes place primarily via an elementary step of the dissociation of OH* into O* and H*.     

分部优化正则化在近场声全息技术中的应用

在基于等效源法近场声全息技术的基础上,对稳定重建过程不适定性的正则化技术进行深入研究。为改善正则化效果,综合考虑Tikhonov正则化和截断奇异值法,提出一种新的分部优化正则化技术。该技术兼取了两种方法的优点,比Tikhonov正则化稳定,避免了过滤波等正则化失效的情况;比截断奇异值法精度高,包含了更多的细节信息。通过对简支板的数值仿真,分别和Tikhonov正则化和截断奇异值法进行了比较,说明了本文所提方法稳定性较好和精度较高的优点。最后通过实验研究进一步证明了本文方法的有效性和正确性。     

一种用鼻音声母识别讲话者的方法

本文提出一种新的讲话者识别方法,该方法仅对带鼻辅音音节的鼻声母段及声韵过渡段用极零模型来表示其语音特征,并采用该模型参数的加权组合距离进行判决,实验表明,这个新方法降低了运算量,同时首选正识率达到了86%以上。     

A Simplified Model for Calculating Hydrodynamic Lubrication Film Thickness in Elastoplastic Line Contacts

The present paper proposes a simplified model for calculating hydrodynamic lubrication film thickness in elastoplastic line contacts. According to the Saint-Venant’s principle, the pressure in the contact is taken as uniformly distributed, this gives the contact surface elastic deformations in the inlet zone far away from the contact center close to real ones while gives those close to the contact center greater than real ones. This treatment is validated for hydrodynamic lubricated elastic contacts for relatively light loads and high rolling speeds. It gives the film thickness at the contact center a little higher than that calculated based on the real elastic model. The treatment is extended to a hydrodynamic lubricated elastoplastic line contact. The contact surfaces in the inlet zone are assumed as elastic and their deformations are calculated based on the uniform pressure distribution in the elastoplastic contact area. An inlet zone analysis is taken for obtaining the calculating equation of the hydrodynamic film thickness at the contact center. The equation overestimates the central film thickness but gives a satisfactory film thickness prediction for the heavy load which gives significant plastic deformations in the elastoplastic contact. It is found that when the load is lighter than 0.6 w _pc , the contact can be taken as elastic when calculating the central film thickness, while when the load is heavier than 0.6 w _pc , the contact can be taken as fully plastic; Here w _pc is the critical load for the contact fully plastic deformation. The plastic deformation in an elastoplastic line contact is found to reduce the hydrodynamic lubrication film thickness in the contact. This reduction is greater for higher rolling speeds and heavier loads. However, it is significantly dropped with increasing surface hardness.     

二维半线性扩散反应方程的高精度全隐格式及其多重网格方法

针对二维非定常半线性扩散反应方程，空间导数项采用四阶紧致差分公式离散，时间导数项采用四阶向后Euler公式进行离散，提出一种无条件稳定的高精度五层全隐格式.格式截断误差为O（τ⁴+τ²h²+h⁴），即时间和空间均具有四阶精度.对于第一、二、三时间层采用Crank-Nicolson方法进行离散，并采用Richardson外推公式将启动层时间精度外推到四阶.建立适用于该格式的多重网格方法，加快在每个时间层上迭代求解代数方程组的收敛速度，提高计算效率.最后通过数值实验验证格式的精确性和稳定性以及多重网格方法的高效性.     

Catalyst-free,direct electrochemical trifluoromethylation/cyclization of N-arylacrylamides using TfNHNHBoc as a CF3 source

A new electrochemical strategy for trifluoromethylation/cyclization using TfNHNHBoc as a CF₃ source was established. This approach was realized by the direct electrolysis of Tf NHNHBoc under external oxidantfree and catalyst-free conditions, and afforded various trifluoromethylated oxindoles with good functional group compatibility and broad substrate scope. Preliminary mechanistic studies show that the reaction proceeds by a radical process.     

Preparation and characters of hyperbranched polyester‐based organic‐inorganic hybrid material compared with linear polyester

To compare the properties of hyperbranched polymers with linear oligomers for preparing organic‐inorganic hybrids, hyperbranched aliphatic polyester (Boltorn^TM H20) and linear polyester hexa‐acrylate (EB830) were selected as organic components for preparing UV‐curable transparent hybrid materials using 3‐(trimethoxysilyl) propylmethacrylate as a coupling agent via a sol‐gel process. The prehydrolyzed product of tetraethoxysilane was used as an inorganic component. The effects of inorganic content on the morphologies, thermal behaviors, photopolymerizaiton kinetics and mechanical properties of the hybrids were investigated. The results show that for hyperbranched polyester‐based hybrids, the organic phase shows much better compatibility with inorganic phase even at high inorganic component content due to its special spheral shape and plenty of functional end groups, compared with linear EB830‐based hybrids. Copyright © 2004 John Wiley & Sons, Ltd.