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891.
892.
Xiaoyan Zhao Zhiyi Wei Fangling Du Junqing Zhu 《Applied biochemistry and biotechnology》2010,162(7):2087-2097
Suitability of reverse micelles of anionic surfactant sodium bis(2-ethyl hexyl) sulfosuccinate (AOT) and sodium dodecyl sulfate
(SDS), cationic surfactant hexadecyl trimethyl ammonium bromide (CTAB) and nonionic surfactant polyoxyethylene p-t-octylphenol (TritonX-100) in organic solvent isooctane for extraction of soy isoflavone-enriching proteins was investigated.
The results showed that the order of combined isoflavone contents was SDS>CTAB>Triton X-100>AOT, while the order of protein
recovery was SDS>AOT>TritonX-100>CTAB. As compared with ACN-HCl extraction, the total amount of isoflavones was lower than
reverse micellar extraction. Ion strength was one of the important conditions to control extraction of isoflavone-enriching
proteins with AOT reversed micelles. For the six salt systems, KNO3, KCl, MgCl2, CaCl2, NaCl, and Na2SO4, extracted fraction of isoflavone-enriching proteins was measured. Salt solutions greatly influenced the extraction efficiency
of isoflavones in an order of KNO3>MgCl2>CaCl2>KCl>NaCl>Na2SO4, while protein in an order of MgCl2>CaCl2>NaCl>KNO3>Na2SO4>KCl. 相似文献
893.
894.
Wei Hu Bin Xie Ying Wang Jia‐qing Xie Xiang‐guang Meng Juan Du 《Journal of Dispersion Science and Technology》2013,34(6):860-868
Two transitional metal ion macrocyclic Schiff base complexes, NiL and CuL were synthesized and characterized, and the metallomicelles made up of the nickel(II) and copper(II) complexes and surfactants(LSS, Brij35, CTAB), as mimic hydrolytic metalloenzyme, were used in catalytic hydrolysis of carboxylic ester (PNPP). The analysis of specific absorption spectrums of the hydrolytic reaction systems indicates that key intermediates, made up of PNPP and Ni(II) or Cu(II) complexes, have formed in the reaction processes of the PNPP catalytic hydrolysis. In this, based on the analytic result of specific absorption spectrum, the mechanism of PNPP catalytic hydrolysis has been proposed; a kinetic mathematical model, applied to the calculation of the kinetic parameter of PNPP catalytic hydrolysis has been established on the foundation of the mechanism proposed; the acid effect of reaction system, structure effect of the complexes, effect of temperature and effects of micelle on the rate of PNPP hydrolysis catalyzed by the complexes also have been discussed. 相似文献
895.
896.
Marija Mirković Drina Janković Sanja Vranješ‐Đurić Magdalena Radović Dragana Stanković Dušan Mijin Nadežda Nikolić 《应用有机金属化学》2012,26(7):347-355
Two novel diamine dioxime ligands, 4,7‐diaza‐3,8‐diethyldecane‐2,9‐dione bis oxime (3) and 4,9‐diaza‐3,10‐diethyldodecane‐2,11‐dione bis oxime (5), were synthesized in order to develop new brain perfusion imaging agents, based on 99mTc(V)‐complexes. The synthesis involved condensation of 2‐hydroxyimino‐3‐pentanone with appropriate diamine in protic solvent which afforded the bis imine adducts. Subsequent reduction of imine functional groups yielded a diastereoisomeric mixture of 3 and 5. UV–visible, IR, 1H NMR, 13C NMR and elemental analysis were used to characterize the structures of the synthesized compounds. 99mTc‐complexes of both diamine dioximes were prepared and radiolabeling conditions optimized to give the maximum yield. Physicochemical parameters of the labeled complexes as well as and their biodistribution in rats were investigated. Both compounds (3 and 5) formed 99mTc‐complexes with a net charge of zero, determined by electrophoresis. The resultant lipophilic 99mTc‐complexes of 3 and 5 were readily formed at pH ~9.0 within 10 min at room temperature with yields of 90% and 95%, respectively. The 99mTc‐3 complex was found to be stable within 1 h, while 99mTc‐5 was stable for a few hours. A significant brain uptake of 99mTc‐3 (2.1% injected dose) and 99mTc‐5 (1.8% injected dose) complexes, 2 min after injection, is in accordance with their lipophilicity. The present study suggests that both ligands are promising candidates as new 99mTc‐based brain‐imaging agents. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
897.
Dušan Repovš Witold Rosicki Žiga Virk Andreas Zastrow 《Topology and its Applications》2012,159(10-11):2609-2620
This paper shows that a construction, which was introduced by Piotr Minc in connection with a problem that came from Helly type theorems and that allows to replace three PL-arcs with a “sheltered middle path”, can in the case of general (non-PL) paths result in the topologist?s sine curve. 相似文献
898.
Du‐Qiang Luo Wen‐Liang Zhu Xiao‐Long Yang Shu‐Juan Liang Zhi‐Ran Cao 《Helvetica chimica acta》2010,93(6):1209-1215
Two new daphniphyllum alkaloids named 2‐hydroxyyunnandaphnine D ( 1 ) and methyl 7‐hydroxyhomodaphniphyllate ( 2 ), together with eight known alkaloids, daphnioldhanin D, calyciphylline F, calyciphylline B, deoxycalyciphylline B, daphnicyclidin H, macropodumine C, 9,10‐epoxycalycine A, and yunnandaphnine A, were isolated from the stems and leaves of Daphniphyllum calycinum. Their structures and relative configurations were established on the basis of spectral evidence (including 2D‐NMR) and subsequently confirmed by a single‐crystal X‐ray crystallographic diffraction analysis. 相似文献
899.
ABSTRACT Convenient regio- and stereoselective syntheses of rhamnose-containing oligosaccharides via sugar-sugar orthoester formation and rearrangement are described. 1→3 Linked rhamno di- and trisaccharides were synthesized effectively using unprotected rhamnose residue as the glycosyl acceptor by this methodology. 相似文献
900.
Wei Shyy Young-Chang Cho Amit Gupta Chien-Chou Tseng Ann Marie Sastry 《Acta Mechanica Sinica》2011,27(6):845-865
Successful modeling and/or design of engineering systems often requires one to address the impact of multiple "design variables" on the prescribed outcome.There are often multiple,competing objectives based on which we assess the outcome of optimization.Since accurate,high fidelity models are typically time consuming and computationally expensive,comprehensive evaluations can be conducted only if an efficient framework is available.Furthermore,informed decisions of the model/hardware’s overall performance rely on an adequate understanding of the global,not local,sensitivity of the individual design variables on the objectives.The surrogate-based approach,which involves approximating the objectives as continuous functions of design variables from limited data,offers a rational framework to reduce the number of important input variables,i.e.,the dimension of a design or modeling space.In this paper,we review the fundamental issues that arise in surrogate-based analysis and optimization,highlighting concepts,methods,techniques,as well as modeling implications for mechanics problems.To aid the discussions of the issues involved,we summarize recent efforts in investigating cryogenic cavitating flows,active flow control based on dielectric barrier discharge concepts,and lithium(Li)-ion batteries.It is also stressed that many multi-scale mechanics problems can naturally benefit from the surrogate approach for "scale bridging." 相似文献