Phase transition behavior and piezoelectric properties of low-Li and high-Sb modified KNN based piezoceramics

(Na_0.5K_0.5)_0.975Li_0.025Nb_0.82−xSb_xTa_0.18O₃ lead-free piezoceramics were prepared by the conventional solid-state sintering method. All samples possess a pure perovskite phase, and no secondary phase could be certified. The crystal structure changes from tetragonal to pseudo-cubic with increasing amount of Sb. The ferroelectric Curie temperature (T_c) shifts to lower temperature while the tetragonal to orthorhombic phase transition temperature (T_o-t) shows no obvious change with increasing Sb⁵⁺. Enhanced piezoelectric and electromechanical properties are obtained with x=0.06: d₃₃=352 pC/N, k_p=47% and k_t=38%, showing that they could be promising candidates as lead-free piezoelectric materials.     

A 200 W diode-side-pumped CW 2 μm Tm:YAG laser with water cooling at 8°C

A water-cooled 785 nm diode-side-pumped high-power CW Tm:YAG laser system at 2 μm is reported. 200 W output power is achieved with cooling water running at 8°C. As far as we know, this is the highest output power for a diode-pumped all solid-state 2 μm Tm:YAG laser. The output corresponds to optical-to-optical conversion efficiency of 11.2%, with a slope efficiency of about 22.8%. To make the system structure simple, only deionized water is used as the coolant instead of alcohol- or glycol-water mixture or the liquid nitrogen in the reported high-power Tm rod laser experiments, which were performed at low temperature near the freezing point of water, or even below.     

Magnetic surface plasmon-induced tunable photonic bandgaps in two-dimensional magnetic photonic crystals

We experimentally studied magnetically controllable photonic band gaps (PBGs) in two-dimensional magnetic photonic crystals consisting of ferrite rods. Besides the conventional PBG that relates to Bragg scattering, two other types of PBG, resulting from magnetic surface plasmon (MSP) resonance and spin-wave resonance, respectively, are observed. The PBG due to MSP resonance is particularly interesting because of its analogy to surface plasmon in metal; furthermore, it is shown to be completely tunable by an external static magnetic field from both an experimental and a theoretical point of view.     

Three-dimension direct writing TiO<Subscript>2</Subscript> crystalline patterns in Bi-free glass using femtosecond laser

Crystalline TiO₂ was induced three dimensionally inside Bi-free glass sample by an 800 nm, 250-kHz femtosecond laser irradiation. Micro-Raman spectra analysis indicated that the laser-induced crystals in the focal point of the laser beam were monophase TiO₂ rutile. Continuous crystalline lines were written through moving the focal point of the laser beam inside the glass. The results demonstrate that this technique is a convenient method to engrave three-dimensional patterns of crystals for fabricating integrated optical devices in transparent materials.     

辐射传输介质散射相函数的蒙特卡洛算法

复分散系相函数在辐射介质传热中是关键参数,蒙特卡洛法兼具数值算法与试验测量的优点.利用该方法计算复分散系的多重散射相函数克服了以往算法的缺点,可以体现多重散射的影响,并且可以计算任意形状控制体的相函数.大量的数学实验发现当介质系密度增大时,散射能量在4π空间内分布趋于均匀.     

采用FTIR和电子能谱EDS指纹图谱直观比对鉴定右归丸济生肾气丸

结合FTIR和电子能谱EDS指纹图谱,鉴别了两种组成相近的中药复方右归丸和济生肾气丸.测定右归丸和济生肾气丸样品氯仿提取物的红外指纹图谱,依据W检验理论判别方法精细建立两种中药复方红外指纹图谱的特征吸收峰组,确定了各个特征吸收峰相对应的特征分子基团和药物成分组成.同时测量两种中药复方原药粉末样品的EDS指纹图谱.根据两...     

基于正交投影散度的高光谱遥感波段选择算法

由于高光谱数据的海量高维特征,对其进行降维处理成为高光谱遥感研究的一个重要问题.波段选择算法由于能够有效地保留原始数据的信息,在高光谱数据降维及后续的遥感识别与分类等方面具有明显的优越性.文章提出了一种基于正交投影散度(OPD)的波段选择方法,该方法继承了正交子空间投影(OSP)算法的特点,通过把原始数据投影到特征空间...     

发红色荧光铽配合物的合成及荧光性能的研究

以二苯甲酰甲烷(HDBM)为第一配体,邻菲罗啉(phen)和二吡啶并[3,2-a:2',3'-c]哇喔啉(dpq)为第二配体合成两种三元铽配合物,并进行元素分析、稀土络合滴定、摩尔电导率、红外光谱、紫外光谱、荧光激发和发射光谱的测定,推测化合物的组成分别为:Tb(DBM)3phen,Tb(DBM)3dpq.DBM通过氧...     

考虑意外事件对交通流影响的元胞自动机交通流模型

在NaSh模型的基础上,考虑交通事故和养护路段等意外事件对高速公路交通流的影响,建立了有意外事件影响的在车道管制下的高速公路交通流元胞自动机模型,并进行数值模拟. 研究发现:意外事件对高速公路交通流有明显影响,并且意外事件对交通流的影响在某一密度值范围内尤其明显,且意外事件堵塞点在第一车道比在第二车道对交通流的影响小;同时,在该密度值范围内,意外事件堵塞时间和堵塞路段长度越长,对交通流的影响就越大. 关键词： 元胞自动机 交通流 意外事件     

NaLa(MoO4)2∶Eu3+的水热调控合成与发光特性研究

采用水热法合成了不同粒径的NaLa(MoO₄)₂∶Eu³⁺微晶.通过调节乙二醇浓度和反应时间,研究了NaLa(MoO₄)₂∶Eu³⁺微晶的形貌演变过程,在水热条件下180 ℃反应16 h获得了均一梭子形NaLa(MoO₄)₂∶Eu³⁺微晶,其晶粒长度约为2.0 μm.荧光光谱分析表明,Eu³⁺取代了NaLa(MoO₄)₂中La³⁺的格位, Eu³⁺在613 nm处红光发射(⁵D₀–⁷F₂跃迁)的浓度猝灭机理是电偶极-电四极相互作用,并发生了Eu³⁺( ⁵D₁ ) + Eu³⁺(⁷F₀ )→ Eu³⁺( ⁵D₀ ) + Eu³⁺(⁷F₃) 交叉弛豫,由此导致浓度猝灭. 关键词： 钼酸盐 水热法 稀土离子 发光