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51.
High-level computations at G3, CBS-Q, and G3B3 levels were conducted, and good-quality C-H and N-H bond dissociation energies (BDEs) were obtained for a variety of saturated and unsaturated strained hydrocarbons and amines for the first time. From detailed NBO analyses, we found that the C-H BDEs of hydrocarbons are determined mainly by the hybridization of the parent compound, the hybridization of the radical, and the extent of spin delocalization of the radical. The ring strain has a significant effect on the C-H BDE because it forces the parent compound and radical to adopt certain undesirable hybridization. A structure-activity relationship equation (i.e., BDE (C-H) = 61.1-227.8 (p(parent)% - 0.75)(2) + 152.9 (p(radical)% - 1.00)(2) + 40.4 spin) was established, and it can predict the C-H BDEs of a variety of saturated and unsaturated strained hydrocarbons fairly well. For the C-H BDEs associated with the bridgehead carbons of the highly rigid strained compounds, we found that the strength of the C-H bond can also be predicted from the H-C-C bond angles of the bridgehead carbon. Finally, we found that N-H BDEs show less dependence on the ring strain than C-H BDEs. 相似文献
52.
Part I of the present work outlined the rigorous application of information theory to a quantum mechanical system in a thermodynamic equilibrium state. The general formula developed there for the best-guess density operator \(\hat \rho\) was indeterminate because it involved in an essential way an unspecified prior probability distribution over the continuumD H of strong equilibrium density operators. In Part II mathematical evaluation of \(\hat \rho\) is completed after an epistemological analysis which leads first to the discretization ofD H and then to the adoption of a suitable indifference axiom to delimit the set of admissible prior distributions. Finally, quantal formulas for information-theoretic and thermodynamic entropies are contrasted, and the entire work is summarized. 相似文献
53.
54.
Seo K Kim C Choi YS Park KA Lee YH Kim B 《Journal of the American Chemical Society》2003,125(46):13946-13947
CO2 molecule chemisorbs selectively on the zigzag tube edge without an activation barrier, whereas it physisorbs on the armchair edge of nanotubes. In addition, carbon nanotubes can be etched by an adsorbed oxygen atom of CO2 molecule. From our results, we suggest a selective etching mechanism for tuning the chirality of the mass-produced carbon nanotubes. 相似文献
55.
Rhodium(II)-catalyzed reactions of cyclic diazodicarbonyl compounds with a variety of halides have been examined. With acid halides, β-acyloxy α-haloenones are produced in good yields. With benzyl halides, β-benzyloxy α-haloenones are obtained in good yields. Reactions with methylene halides yield β-halomethoxy α-haloenones in good yields, whereas reactions with ethyl halides and ethylene dihalides result in β-hydroxy α-haloenones in high yields. These reactions provide a useful and rapid entry to β-substituted α-haloenones. The mechanistic pathway for the formation of these products has been also described in terms of halonium ylides. 相似文献
56.
Reaction of copper(II) salts with n-alkylsulfonate anions yields light blue lamellar Cu(C(n)H(2n + 1)SO3)2 x zH2O displaying distinct (mono/bi-layer) chain packing with increasing alkyl chain lengths. This may be attributed to the amphiphilic nature of the surfactants, i.e., the hydrophilic sulfonate head groups, mediating the coordination, and H-bonding interactions, and the hydrophobic alkyl chains. 相似文献
57.
Titanium porphyrin hydrazido complexes (TTP)Ti = NNR2 (TTP = meso-tetra-p-tolylporphyrinato dianion; R = Me (1), Ph (2)) were synthesized by treatment of (TTP)TiCl2 with 1,1-disubstituted hydrazines H2NNR2 (R = Me, Ph) in the presence of piperdine. The nucleophilic character of the hydrazido moiety was demonstrated in the reactions of complexes 1 and 2 with p-chlorobenzaldehyde, which yielded the titanium oxo complex (TTP)-Ti = O and the respective hydrazones. Protonation of complexes 1 and 2 with phenol or water produced the 1,1-disubstituted hydrazine along with (TTP)Ti(OPh)2 or (TTP)Ti = O, respectively. Similar reactivity of p-chlorobenzaldehyde and phenol with (TTP)Ti = NiPr, 3, was observed. The reaction of complex 3 with nitrosobenzene cleanly formed the azo compound iPrN = NPh and the terminal oxo product (TTP)Ti = O. 相似文献
58.
William Doherty Peter Halley Les Edye David Rogers Francisco Cardona Yoosup Park Tim Woo 《先进技术聚合物》2007,18(8):673-678
Sugarcane fiber (i.e. bagasse) lignin has a larger fraction of aromatics unsubstitution in the ortho position than hardwood or softwood lignin and hence has the greater ability to be derivatized. Furthermore, organosolv lignin has a higher purity than sulfonated and kraft lignins. This work examines the purification of organosolv lignin derived from bagasse and the physico‐chemical properties of the lignin and lignin‐phenol formaldehyde (PF) resin coatings, and composites. The wetability tests have shown that lignin and lignin‐PF resin films are effective water barrier coatings, though the contact angles of lignin‐PF resin films were considerably less than the wax films. The overall mechanical properties (i.e. peak stress, peak strain and modulus) of the bagasse fiber composites were lower than the values obtained with the composites without the inclusion of bagasse fiber. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
59.
Lashuel HA Labrenz SR Woo L Serpell LC Kelly JW 《Journal of the American Chemical Society》2000,122(22):5262-5277
Deciphering the mechanism(s) of β-sheet mediated self-assembly is essential for understanding amyloid fibril formation and for the fabrication of polypeptide materials. Herein, we report a simple peptidomimetic that self-assembles into polymorphic β-sheet quaternary structures including protofilaments, filaments, fibrils, and ribbons that are reminiscent of the highly ordered structures displayed by the amyloidogenic peptides Aβ, calcitonin, and amylin. The distribution of quaternary structures can be controlled by and in some cases specified by manipulating the pH, buffer composition, and the ionic strength. The ability to control β-sheet-mediated assembly takes advantage of quaternary structure dependent pK(a) perturbations. Biophysical methods including analytical ultracentrifugation studies as well as far-UV circular dichroism and FT-IR spectroscopy demonstrate that linked secondary and quaternary structural changes mediate peptidomimetic self-assembly. Electron and atomic force microscopy reveal that peptidomimetic assembly involves numerous quaternary structural intermediates that appear to self-assemble in a convergent fashion affording quaternary structures of increasing complexity. The ability to control the assembly pathway(s) and the final quaternary structure(s) afforded should prove to be particularly useful in deciphering the quaternary structural requirements for amyloid fibril formation and for the construction of noncovalent macromolecular structures. 相似文献
60.
N. B. Kim D. K. Kim H. W. Choi Y. S. Kim H. J. Woo K. S. Park 《Journal of Radioanalytical and Nuclear Chemistry》1995,192(1):147-154
A quantitative analysis of an ancient Buddha statue was performed by external beam Proton Induced X-ray Emission for the purpose of identifying its originality. It is shown how the PIXE method can be applied for archeological study. The elemental composition of the statue is compared with that of several samples with definite ages. The experiment was performed by extracting 2.4 MeV proton beam through a 2 mm diameter collimator and 7.6 m kapton foil to the He atmosphere. X-rays were measured by a Si(Li) detector. The analysed elements were Fe, Cu, Ag, Au and Hg for gold coating and Fe, Ni, Cu, Zn, As, Ag, Sn, Au, Pb and Bi for bronze body. 相似文献