The mechanism of the allylic oxidation of 2-methyl-2-butene with selenium dioxide has been investigated by ab initio quantum mechanics. Transition states for two major steps (an ene reaction and a [2,3]-sigmatropic rearrangement) of this reaction have been optimized by the B3LYP/6-311+G(d,p) method. A comparison of the energies of the transition states shows that the anti-endo and syn-endo approaches are the efficient routes in the ene reaction and the methyl (C4) group is sited in a pseudo-equatorial environment in cyclic transition states during the [2,3]-rearrangement. Calculations also show the kind of the terminal alkyl (C4) substituents may control (E)-selectivity in the formation of the allylic alcohols. 相似文献
Czechoslovak Mathematical Journal - During the last decade, several research groups have published results on sufficient conditions for the hamiltonicity of graphs by using some topological... 相似文献
As an important research direction, operational research (OR) has always attracted scholars worldwide. We study the structure, trend and prospect in the OR field by conducting a bibliometric analysis of publications in the period of 1952–2020, which are included in the Web of Science (WoS) database. Using three effective bibliometric tools, namely, VOS viewer, CiteSpace, and Bibliometrix, a total of 5,353 publications were retrieved to show clear visual results using a series of scientific analyses. First, a performance analysis revealed the basic characteristics of publications considering the type distribution, annual trend, quantity and quality. Then, a cooperation analysis presented the influential countries/regions and showed the relationships among countries/regions, institutions and authors during different periods based on bibliometric indicators and co-authorship networks. Moreover, a keyword analysis was conducted to investigate the hot topics and development of the OR field, using co-occurrence analysis, timeline view analysis and evolution analysis. Finally, we discussed the implications and limitations, and summarized the main findings. This study hopes to provide important and valuable references for future research on the OR field.
G. Grätzer, H. Lakser, and E. T. Schmidt proved that every distributive lattice with n join-irreducible elements can be represented as the congruence lattice of a small lattice L, that is, a lattice L with O(n2) elements. G. Grätzer, I. Rival, and N. Zaguia proved that, for any <2, O(n2) can not be improved to O(n). In this note we show that the theorem about small representation can be improved further to get a more delicate result. 相似文献
The properties of a toric variety have strong connection with the combinatorial structure of the corresponding fan and the relations among the generators. Using this fact, we have described explicitly the Chow ring for aQ-factorial toric variety as the Stanley-Reisner ring for the corresponding fan modulo the linear equivalence relation. In this paper, we calculate the Chow ring for 3-dimensionalQ-factorial toric varieties having one bad isolated singularity. 相似文献
Summary The essential oils have been isolated from tobacco leaves using a simple gas co-distillation apparatus. The method involves co-distillation with water under the continuous stream of an inert gas with subsequent single solvent extraction of the distillate. The extract is analysed on GC and GC/MS in splitless injection mode without further concentration. The method was evaluated for reproducibility using n-octadecane as an internal standard. The distillation-extraction procedure was reporducible with an average deviation of ±3% for the major constituents. The present method was applied to the analyses of the essential oils of other agricultural products.Dedicated to Dr. L. S. Ettre on the occasion of his 60th birthday. 相似文献
Gallium(III) triflate catalyzed the rearrangement of 2-substituted vinylepoxides into beta,gamma-unsaturated carbonyl compounds with high regio- and chemoselectivity (>97/3) in low catalyst loading (1-5 mol %). The alkyl-substituted trimethylsilylvinyl epoxides gave beta,gamma-unsaturated ketone, but aryl-substituted vinylepoxides gave the aldehydes instead. 相似文献