首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   24834篇
  免费   2718篇
  国内免费   2483篇
化学   17363篇
晶体学   319篇
力学   1201篇
综合类   235篇
数学   3043篇
物理学   7874篇
  2024年   24篇
  2023年   211篇
  2022年   433篇
  2021年   626篇
  2020年   633篇
  2019年   707篇
  2018年   683篇
  2017年   652篇
  2016年   1014篇
  2015年   979篇
  2014年   1301篇
  2013年   1766篇
  2012年   1974篇
  2011年   2229篇
  2010年   1613篇
  2009年   1568篇
  2008年   1899篇
  2007年   1747篇
  2006年   1607篇
  2005年   1422篇
  2004年   1175篇
  2003年   931篇
  2002年   1058篇
  2001年   736篇
  2000年   631篇
  1999年   439篇
  1998年   279篇
  1997年   226篇
  1996年   223篇
  1995年   171篇
  1994年   154篇
  1993年   119篇
  1992年   115篇
  1991年   98篇
  1990年   90篇
  1989年   74篇
  1988年   60篇
  1987年   32篇
  1986年   25篇
  1985年   43篇
  1984年   27篇
  1983年   24篇
  1982年   22篇
  1981年   18篇
  1980年   19篇
  1979年   17篇
  1978年   29篇
  1977年   14篇
  1976年   18篇
  1975年   12篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
The emergence of drug-resistant hepatitis B virus (HBV) has been reported in patients with prolonged administration of lamivudine, which is a potent drug for the prevention of HBV infection. Lamivudine-resistant HBV has several types of mutations at the YMDD motif of its DNA polymerase. We successfully demonstrated that monitoring the hybridization behavior in nanostructured reverse micelles enables us to detect single nucleotide polymorphisms (SNPs). With the aid of reverse micelles, a model 40-mer oligonucleotide containing a single-base substitution was clearly distinguished from the normal, complementary oligonucleotide. In addition, we extended this technique to a high-throughput analysis. The results obtained with a 96-well micro-plate reader indicated the possibility of SNPs detection toward multiple samples of patients.  相似文献   
62.
Electrospinning of cellulose acetate (CA) in a new solvent system and the deacetylation of the resulting ultrafine CA fibers were investigated. Ultrafine CA fibers (∼2.3 μm) were successfully prepared via electrospinning of CA in a mixed solvent of acetone/water at water contents of 10–15 wt %, and more ultrafine CA fibers (0.46 μm) were produced under basic pH conditions. Ultrafine cellulose fibers were regenerated from the homogeneous deacetylation of ultrafine CA fibers in KOH/ethanol. It was very rapid and completed within 20 min. The crystal structure, thermal properties, and morphology of ultrafine CA fibers were changed according to the degree of deacetylation, finally to those of pure cellulose, but the nonwoven fibrous mat structure was maintained. The activation energy for the deacetylation of ultrafine CA fibers was 10.3 kcal/mol. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 5–11, 2004  相似文献   
63.
Zn(BTZ)2白色有机电致发光材料的合成及其器件制备   总被引:10,自引:1,他引:9       下载免费PDF全文
以PCl3为脱水剂,将邻氨基硫酚与水杨酸脱水环化合成出2-(2-羟基苯基)苯并噻唑,并进一步将所得产物与乙酸锌反应合成出2-(2-羟基苯基)苯并噻唑螯合锌(Zn(BTZ)2)材料。以该配合物作为发光层制备出结构为ITO/PVK:TPD/Zn(BTZ)2/Al近白色电致发光器件,其色坐标位于白场之内(x=0.242,y=0.359),在驱动电压为16V时,亮度达3200cdm2,对应的量子效率为0.32%。进一步在Zn(BTZ)2中掺入橙红色染料Rubrene,制成ITO/PVK:TPD/Zn(BTZ)2:Rubrene/Al结构器件,实现了纯白色发光(色坐标值:x=0.324,y=0.343),非常接近于白色等能点,且量子效率达0.47%。最后对上述器件的发光和电学性能进行了深入的研究和探讨。  相似文献   
64.
双阳极磁控注入枪束流特性的研究   总被引:1,自引:1,他引:0       下载免费PDF全文
 介绍了用于34GHz基波回旋速调管的双阳极磁控注入枪的结构特点,为了准确分析磁控注入枪的束流特性,建立了阴极表面理论模型,用新编制的程序模拟了电子轨迹。模拟和测量结果显示磁场对磁控注入枪的束流有影响,磁控注入枪的束流也与阴极温度和空间电荷效应有关系。  相似文献   
65.
The relation of the isoelectric point (IEP) and the point of zero net charge (PZNC) of the hydrotalcite-like compounds was discussed. It was found that the IEP does not equal to the PZNC and the IEP is higher than the PZNC. The structural positive charges existing in the HTlc,which cause the difference between the IEP and the PZNC. The effects of the structural positive charges of the HTlc on its IEP and PZNC are the same as the specific adsorption of metal cations.  相似文献   
66.
In this article we prove the existence of the solution to the mixed problem for Euler–Bernoulli beam equation with memory term. The existence is proved by means of the Faedo–Galerkin method and the exponential decay is obtained by making use of the multiplier technique combined with integral inequalities due to Komornik. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
67.
该文利用算子半群的方法给出了取值于具有左不变度量的完备可分群的齐次Levy过程是复合Poisson过程的弱极限这一结论.  相似文献   
68.
Modifying complex plane rotations, we derive a new Jacobi-type algorithm for the Hermitian eigendecomposition, which uses only real arithmetic. When the fast-scaled rotations are incorporated, the new algorithm brings a substantial reduction in computational costs. The new method has the same convergence properties and parallelism as the symmetric Jacobi algorithm. Computational test results show that it produces accurate eigenvalues and eigenvectors and achieves great reduction in computational time.The work of this author was supported in part by the National Science Foundation grant CCR-8813493 and by the University of Minnesota Army High Performance Computing Research Center contract DAAL 03-89-C-0038.The work of this author was supported in part by the University of Minnesota Army High Performance Computing Research Center contract DAAL 03-89-C-0038.  相似文献   
69.
The electrochemical behavior of the copper-tyrosine complex has been studied by linear-sweep adsorption voltammetry. In 0.02 mol/L Na2HPO4 buffer solution (pH=9.6), the complex can be adsorped on a hanging mercury drop electrode and reduced at a peak potential of about –0.42 V (vs. SCE). The secondary derivative peak height is linear proportional to the concentration of tyrosine in the range 1.0×10–7–5.0×10–5 mol/L. The detection limit is 5×10–8 mol/L.Project supported by the Provincial Science Foundation of Shandong Province  相似文献   
70.
A new type of partial-dielectric-loaded helical groove slow-wave structure (SWS) for millimetre wave travelling wave tube (TWT) is presented in this paper.The radio-frequency characteristics including the dispersion properties,the longitudinal electric field distribution and the beam-wave coupling impedance of this structure are analysed.The results show that the dispersion of the helical groove circuit is weakened,the phase velocity is reduced and the position of the maximum Ez is moved from the mouth to the inside of the groove after partially filling the dielectric materials in the helical groove SWS.Therefore,the dielectric-loaded helical groove SWS is suitable for a multi-beam TWT with broad band and high gain.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号