全文获取类型
收费全文 | 30674篇 |
免费 | 4958篇 |
国内免费 | 4511篇 |
专业分类
化学 | 22268篇 |
晶体学 | 423篇 |
力学 | 1861篇 |
综合类 | 388篇 |
数学 | 4031篇 |
物理学 | 11172篇 |
出版年
2024年 | 83篇 |
2023年 | 517篇 |
2022年 | 945篇 |
2021年 | 978篇 |
2020年 | 1103篇 |
2019年 | 1180篇 |
2018年 | 989篇 |
2017年 | 886篇 |
2016年 | 1434篇 |
2015年 | 1481篇 |
2014年 | 1842篇 |
2013年 | 2328篇 |
2012年 | 2562篇 |
2011年 | 2686篇 |
2010年 | 2064篇 |
2009年 | 1972篇 |
2008年 | 2197篇 |
2007年 | 2038篇 |
2006年 | 1903篇 |
2005年 | 1690篇 |
2004年 | 1302篇 |
2003年 | 1102篇 |
2002年 | 1242篇 |
2001年 | 978篇 |
2000年 | 769篇 |
1999年 | 609篇 |
1998年 | 486篇 |
1997年 | 395篇 |
1996年 | 396篇 |
1995年 | 310篇 |
1994年 | 285篇 |
1993年 | 241篇 |
1992年 | 194篇 |
1991年 | 184篇 |
1990年 | 135篇 |
1989年 | 146篇 |
1988年 | 105篇 |
1987年 | 64篇 |
1986年 | 53篇 |
1985年 | 67篇 |
1984年 | 52篇 |
1983年 | 31篇 |
1982年 | 25篇 |
1981年 | 17篇 |
1980年 | 21篇 |
1979年 | 8篇 |
1978年 | 17篇 |
1977年 | 7篇 |
1976年 | 6篇 |
1957年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
Yong Joon Park Min Gyu KimYoung-Sik Hong Xianglan WuKwang Sun Ryu Soon Ho Chang 《Solid State Communications》2003,127(7):509-514
Li[NixLi(1/3−2x/3)Mn(2/3−x/3)]O2 (X=0.17, 0.25, 0.33, 0.5) compounds are prepared by a simple combustion method. The Rietvelt analysis shows that these compounds could be classified as having the α-NaFeO2 structure. The initial charge-discharge and irreversible capacity increases with the decrease of x in Li[NixLi(1/3−2x/3)Mn(2/3−x/3)]O2. Indeed, Li[Ni0.50Mn0.50]O2 compound shows relatively low initial discharge capacity of 200 mAh/g and large capacity loss during cycling, with Li[Ni0.17Li0.22Mn0.61]O2 and Li[Ni0.25Li0.17Mn0.58]O2 compounds exhibit high initial discharge capacity over 245 mAh/g and stable cycle performance in the voltage range of 4.8 -2.0 V. On the other hand, XANES analysis shows that the oxidation state of Ni ion reversibly changes between Ni2+ and about Ni3+, while the oxidation state of Mn ion sustains Mn4+ during charge-discharge process. This result does not agree with the previously reported ‘electrochemistry model’ of Li[NixLi(1/3−2x/3)Mn(2/3−x/3)]O2, in which Ni ion changes between Ni2+ and NI4+. Based on these results, we modified oxidation-state change of Mn and Ni ion during charge-discharge process. 相似文献
82.
Qing Shi Dong Yang Yanlei Su Jian Li Zhongyi Jiang Yanjun Jiang Weikang Yuan 《Journal of nanoparticle research》2007,9(6):1205-1210
Lipase from Candida rugosa was covalently anchored onto acid-treated multi-walled carbon nanotubes (MWNTs) through a self-catalytic mechanism. A variety
of characterization techniques including FTIR, Raman spectroscopy, and XPS were employed to demonstrate the formation of the
ester linkage between lipase and MWNTs. The MWNTs-lipase biocomposites showed significantly increased solubility in some common-used
organic solvents, such as THF, DMF and chloroform. This study may offer a novel and facile route for covalent modification
of carbon nanotubes, and expand the potential utilization of both lipases and MWNTs in the fields of biocatalyst and biosensor. 相似文献
83.
The main aim of this paper is to provide convergence analysis of Quasi-Wilson nonconforming finite element to Maxwell's equations under arbitrary quadrilateral meshes.The error estimates are derived,which are the same as those for conforming elements under conventional regular meshes. 相似文献
84.
Hua Jin Zhuangqi Hu Qingmin Liu Yunlong Ge Changxu Shi 《Applied Physics A: Materials Science & Processing》1992,54(5):399-403
A crystallization study has been carried out for rapidly solidified Bi2Pb0.5Sr2Ca4Cu5Ox glass. Glass transition temperature T
g, crystallized superconducting phases and microstructural changes were measured and analysed by differential thermal analysis (DTA), X-ray diffraction (XRD), and scanning electron microscopy (SEM). The crystallization mechanism of the three superconducting phases — (2201) 20 K phase, (2212) 80 K phase, and (2223) 110 K phase — has been discussed, and a time-temperature-transformation diagram for the glass has been constructed. 相似文献
85.
在随机删失下研究了乘积限过程和累积失效率过程的振动模的局部性质 .给出了这两个过程的振动模的重对数律 ,并应用这些结果得到了几种核密度估计和Bahadur-Kiefer过程的精确收敛速度 相似文献
86.
C Z Shi Z Y Zhang L Z Zhuang 《Science in China. Series B, Chemistry, life sciences & earth sciences》1991,34(9):1098-1104
The effect of hormones on progesterone secretion by 6-8 week human trophoblast tissue cultured in serum-free medium has been investigated. GnRH at low concentration (10(-10)-10(-8) mol/L) stimulated progesterone secretion, while high dose (10(-6)-10(-5) mol/L) produced inhibitory effect. The progesterone secretion could be significantly decreased by addition of anti-hCG antiserum or monoclonal anti-hCG IgG in a dose- and time-dependent manner. Various concentrations of TRH, PGE2, PGF2 alpha, testosterone and estradiol were found to be ineffective. These data indicate clearly that progesterone production by human trophoblast tissue at early gestation stage is under the modulation of GnRH and hCG. 相似文献
87.
88.
Brandau C. Bartsch T. Böhm S. Böhme C. Hoffknecht A. Kieslich S. Knopp H. Schippers S. Shi W. Müller A. Grün N. Scheid W. Steih T. Bosch F. Franzke B. Kozhuharov C. Krämer A. Mokler P. H. Nolden F. Steck M. Stöhlker T. Stachura Z. 《Hyperfine Interactions》2003,146(1-4):41-45
Hyperfine Interactions - An overview of measurements of dielectronic recombination (DR) with the heaviest lithiumlike ions is presented. The experiments have been carried out at the heavy ion... 相似文献
89.
Transfer matrix approach of vibration isolation analysis of periodic composite structure 总被引:1,自引:0,他引:1
Wang Yong Huang Qibai Zhou Minggang Xu Zhisheng 《Archive of Applied Mechanics (Ingenieur Archiv)》2007,77(7):461-471
The transmission properties of elastic waves propagating in a three-dimensional composite structure embedded periodically
with spherical inclusions are analyzed by the transfer matrix method in this paper. Firstly, the periodic composite structures
are divided into many layers, the transfer matrix of monolayer structure is deduced by the wave equations, and the transfer
matrix of the entire structure is obtained in the case of boundary conditions of displacement and stress continuity between
layers. Then, the effective impedance of the structure is analyzed to calculate its reflectivity and transmissivity of vibration
isolation. Finally, numerical simulation is carried out; the experiment results validate the accuracy and feasibility of the
method adopted in the paper and some useful conclusions are obtained.
Project (No. 50075029) supported by the National Natural Science Foundation of China. 相似文献
90.
Xun Fu Danmei Wu Xiaodong Zhou Huaqiang Shi Zhengshui Hu 《Journal of nanoparticle research》2007,9(4):675-681
Hollow spherical molybdenum disulfide has been successfully synthesized via a solvothermal method using Cyanex 301 as sulfur
source and modification agent. The hollow spheres are characterized by transmission electron microscopy, scanning electron
microscopy, X-ray diffraction and Energy-Dispersive X-ray analysis. The influences of reaction conditions are also discussed
while a mechanism is proposed to explain the formation of the peculiar morphology. 相似文献