Absolute Orientation of Molecules with Competing Hydrophilic Head Groups at the Air/Water Interface Probed with Sum Frequency Generation Vibrational Spectroscopy

和频振动光谱(SFG-VS)研究中由基团在界面上取向所引起的光谱增强或相消的干涉现象为研究分子在界面上的绝对取向提供了一种直接的测量方法. 这一方法比SFG实验中复杂的相位测量方法更为直接和简单可行. 以在空气/水界面取向已知的对羟基苯腈(PCP)分子的氰基(-CN)基团为相位参考来获得3,5-二甲基对羟基苯腈(35DMHBN)和2,6-二甲基对羟基苯腈(26DMHBN)分子在空气/水界面的取向信息. 通过对这三种分子的水溶液和它们两两混合溶液界面上-CN基团和频振动光谱强度的比较,发现在空气/水界面的3     

Quantitative Surface Chirality Detection with Sum Frequency Generation Vibrational Spectroscopy: Twin Polarization Angle Approach

介绍了一种新的表面和频振动光谱方法: 定量手性检测中的双偏振角方法. 一般来讲表面光谱信号中非手性项贡献最强,而纯界面手性信号要比非手性信号弱两到三个数量级. 因此在和频振动光定量测量和分析界面手性的贡献问题上存在困难. 在和频振动光谱的双偏振角方法中,通过固定入射红外光偏振方向,并同时改变入射可见光和初涉和频信号光的偏振角进行测量. 这样所得到的偏振依赖的和频振动光谱信号能够直接给出界面手性贡献的特征,并 且能够用于准确测量界面的手性和非手性贡献. 对双偏振角方法进行了描述,并且通过S和R手性的柠檬烯空     

Multi-wavelength fiber ring laser based on a chirped moire fiber grating and a semiconductor optical amplifier

A simple and cost-effective multi-wavelength fiber ring laser based on a chirped Moire fiber grating （CMFG） and a semiconductor optical amplifier （SOA） is proposed. Stable triple-wavelength lasing oscillations at room temperature are experimentally demonstrated. The measured optical signal-to-noise ratio （SNR） reaches the highest value of 50 dB and the power fluctuation of each wavelength is less than 0.2 dB within a 1-h period. To serve as a wavelength selective element, the CMFG possesses excellent comb-like filtering characteristics including stable wavelength interval and ultra-narrow passband, and its fabrication method is easy and flexible. The lasing oscillation shows a narrower bandwidth than SOA-based multi-wavelength fiber lasers utilizing some other kinds of wavelength selective components. Methods to optimize the laser performance are also discussed.     

长余辉材料SrAl2O4:Eu,Dy中Eu的价态变化及对发光性能的影响

采用高温固相法,先在空气气氛下制备了SrAl2O4∶Eu,Dy,后对其进行还原→氧化→还原处理.X射线衍射结果表明,经过还原→氧化→还原处理后样品的晶体结构没有改变.样品的发射光谱测试表明,在高温空气气氛下有少量的Eu3+还原成Eu2+.Eu3+和Eu2+有不同的发光特性,Eu3+产生的是线状特征光谱,发射峰值在592,616 nm.Eu2+产生的是带状光谱,带的中心位置在513 nm.经过还原处理的样品和经过氧化处理的样品相比,Eu2+的浓度得到显著提高,而Eu3+的浓度则急剧下降.对Eu2+的氧化、Eu3+的还原的机理进行了细致地讨论.另外,样品的热释光谱测试表明,经过氧化气氛处理和经过还原气氛处理过的样品的热释光峰值有很大的变化,但陷阱能级深度基本不变,在0.65 eV左右.这表明,对长余辉材料SrAl2O4∶Eu,Dy进行还原→氧化→还原处理,Eu离子价态和发光强度会产生变化,并不影响其中Dy离子的陷阱能级.     

云环境下景区游客流量监控与推荐系统设计

设计了云环境下景区游客流量监控与推荐系统,包括CC3200流量监控与景点推荐两部分,流量监控由RFID电子门票统计游客数量,数据经Wi-Fi上行本地AP节点,由AP节点汇聚至云推荐服务器;当前游客流量、时间富裕度、游客满意度,经服务器解析计算得景点综合推荐指数,主动为游客推荐旅游景点,规划最佳游览路线。经测试,系统工作稳定、数据准确,适用于各类景区游客流量监控与推荐服务。     

太赫兹波段Smith-Purcell辐射的介质加载光栅高频特性

提出了一种用于Smith-Purcell效应器件的介质加载光栅慢波结构,通过研究该结构的注-波互作用过程,推导出带电子注的色散方程,并数值求解出波的线性增长率.利用色散方程,结合电磁场传播的边界条件,推导出Smith-Purcell效应振荡器工作所需的起振电流.详细研究了高频结构长度、电子注主要参数和介质相对介电常数对起振电流的影响,并与普通金属光栅结构进行了比较.结果表明:保持其他参数不变时,高频结构长度越短,起振电流越大;保持高频结构参数不变时,起振电流随电子注厚度和注-栅距离的增大而增大,随电子注电压的增大而减小;与金属光栅相比,介质的引入提高了注-波互作用的增长率,有效减小了振荡器的起振电流.理论计算结果与软件CHIPIC的模拟结果比较符合.     

Darboux Transformation and N-soliton Solution for Extended Form of Modified Kadomtsev-Petviashvili Equation with Variable-Coefficient

The extended form of modified Kadomtsev-Petviashvili equation with variable-coefficient is investigated in the framework of Painlevé analysis. The Lax pairs are obtained by analysing two Painlevé branches of this equation. Starting with the Lax pair, the N-times Darboux transformation is constructed and the N-soliton solution formula is given, which contains 2n free parameters and two arbitrary functions. Furthermore, with different combinations of the parameters, several types of soliton solutions are calculated from the first order to the third order. The regularity conditions are discussed in order to avoid the singularity of the solutions. Moreover, we construct the generalized Darboux transformation matrix by considering a special limiting process and find a rational-type solution for this equation.     

Sonochemical coating of magnetite nanoparticles with silica

Magnetite nanoparticles were coated with silica through the hydrolysis and condensation of tetraethyl orthosilicate (TEOS) under ultrasonic irradiation. The ultrasonic irradiation was used to prevent the agglomeration of the magnetite particles and accelerate the hydrolysis and condensation of TEOS. TEM, DLS, XRF, VSM, TG and sedimentation test were used to characterize the silica-coated magnetite particles. The dispersibility of silica-coated magnetite particles in aqueous solution was improved significantly and the agglomerate particle size was decreased to 110 nm. It was found that the agglomerate particle size of silica-coated magnetite particles was mainly decided by the coating temperature and the pH value in the silica-coating process. The weight ratio of silica in silica-coated magnetite particles was mainly decided by the pH value in the silica-coating process. The dispersibility of silica-coated magnetite particles was mainly decided by the agglomerate particle size of the suspension. The oxidation of magnetite particles in air was limited through the coated silica. The magnetism of silica-coated magnetite particles decreased slightly after silica-coating.     

第十五届全国原子与分子物理学术会议投稿论文:粒子在 Hénon-Heiles势中的逃逸动力学模拟

利用庞加莱截面和相空间轨迹方法对粒子在Hénon-Heiles势中的逃逸动力学进行了模拟。粒子的动力学性质敏感地依赖于粒子的能量。数值计算表明当能量很小时,粒子的运动是规则的;随着能量的增加,粒子的运动开始出现混沌。当能量增加到鞍点能 时,几乎所有的相空间轨迹都是混沌的。当粒子的能量 , 粒子可以越过势阱发生逃逸。对于给定的大于 的能量, 我们画出了粒子的逃逸－时间曲线和逃逸轨迹。我们的研究对于研究混沌传输和逃逸动力学具有一定的参考价值。     

掺Yb钒酸盐晶体激光振荡中的光学双稳态现象研究

研究了三种掺Yb钒酸盐晶体Yb:LuVO4,Yb:YVO4和Yb:GdVO4的激光振荡中所呈现的光学双稳态效应.以晶体所吸收的抽运功率表征的双稳区宽度ΔPabs可超过1W,在双稳区高功率一侧的边界,即激光振荡的上阈值点,出现激光输出功率的不连续变化或跃变,同时发生亚毫秒时间尺度上的大幅度强度涨落.谐振腔的输出耦合透过率、晶体长度、晶体中的热效应等对双稳态效应均具有重要影响.