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51.
We consider optimal control problems of systems governed by stationary, incompressible generalized Navier–Stokes equations with shear dependent viscosity in a two-dimensional or three-dimensional domain. We study a general class of viscosity functions with shear-thinning and shear-thickening behavior. We prove an existence result for such class of optimal control problems. 相似文献
52.
We study an integro-differential equation that describes the slow erosion of granular flow. The equation is a first order nonlinear conservation law where the flux function includes an integral term. We show that there exist unique traveling wave solutions that connect profiles with equilibrium slope at ±∞. Such traveling waves take very different forms from those in standard conservation laws. Furthermore, we prove that the traveling wave profiles are locally stable, i.e., solutions with monotone initial data approach the traveling waves asymptotically as t→+∞. 相似文献
53.
The formalism to describe electron scattering reactions on two-neutron halo nuclei is developed. The halo nucleus is described as a three-body system (core +n + n), and the wave function is obtained by solving the Faddeev equations in coordinate space. We discuss elastic and quasielastic scattering using the impulse approximation to describe the reaction mechanism. We apply the method to investigate the case of electron scattering on 6He. Spectral functions, response functions, and differential cross sections are calculated for both neutron knockout and knockout by the electron. 相似文献
54.
Since the first use of glass electrode to the detection of pH, many efforts have been made to develop new techniques and methods. In this study, the pH sensing properties of an extended gate field effect transistor (EGFET) based on the vanadium pentoxide xerogel thin film is investigated. The vanadium pentoxide was prepared by a sol–gel route. The X-ray diffractogram indicates the presence of a lamellar structure of the vanadium pentoxide xerogel films. The film was investigated as a sensor in the pH range of 2–12 and the corresponding EGFET has a sensitivity of 58.1 mV/pH. This value suggests that the material is a promising candidate for applications as disposable biosensor. 相似文献
55.
Rubén Marín-Barrios Francisco M. Guerra Ana Leticia García-Cabeza F. Javier Moreno-Dorado Guillermo M. Massanet 《Tetrahedron》2012,68(4):1105-1108
The multivariate optimization method known as simplex is applied to the Kharasch–Sosnovsky allylic oxidation of double bonds. By applying this method, the amounts of three variables (copper source, oxidant, and additive) are optimized at the same time. Under the conditions thus obtained the reaction takes place in a considerable shorter time, being the alkene the limiting reagent. These conditions are applied to some monoterpenes and sesquiterpenes leading regioselectively to the corresponding benzoate esters, opening a route to the employment of this reaction in the synthesis of more complex molecules. 相似文献
56.
Francisco A. Macías José O. Guerra Ana M. Simonet Andy J. Pérez Clara Nogueiras 《Magnetic resonance in chemistry : MRC》2010,48(5):350-355
A careful NMR analysis, especially by 1D TOCSY and 1D ROESY, of a refined saponin fraction allowed us to determine the structure of three saponins from a polar extract of Agave brittoniana Trel. spp. Brachypus leaves. The use of 1D DOSY for the suppression of the solvent signal was useful to obtain the chemical shifts of anomeric signals. A full assignment of the 1H and 13C spectral data for the new saponins, agabrittonosides E–F (1–2) and the well‐known Karatavioside C (3) and their methoxyl derivatives, is reported. The structures were established using a combination of 1D and 2D (1H, 1H‐COSY, TOCSY, ROESY, g‐HSQC, g‐HMBC and g‐HSQC‐TOCSY) NMR techniques and ESI–MS. In addition, the methoxylation of these furostane saponins in the presence of MeOH was studied. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
57.
58.
Pedro Jiménez Guerra Miguel Angel Melguizo María J. Mu?oz-Bouzo 《Set-Valued Analysis》2007,15(1):47-59
The paper deals with the properties of a conic set-valued function defined on the set of all ideal points of vector programming
problems. The results here about the continuity and derivability of this conic set-valued map, can be used to get information
about the sensitivity of the problem and the stability of the order associated to every ideal point. Furthermore, it is proved
that certain contingent cones are determined by the ideal conic set-valued map.
相似文献
59.
Celia Regaño Romina Marín Abdelilah Alla José I. Iribarren Antxon Martínez De Ilarduya Sebastián Muñoz‐Guerra 《Journal of Polymer Science.Polymer Physics》2007,45(1):116-125
The crystal structure and crystallization behavior of a series of poly(ester amide)s derived from L ‐tartaric acid, 1,6‐hexanediamine, and 6‐amino‐1‐hexanol were examined. The study included aregic polymers containing 5, 10, and 20% of ester groups in addition to the syndioregic polymer containing equal amounts of amide and ester groups. X‐ray diffraction data revealed that all the aregic poly(ester amide)s adopt the same crystal structure as the parent polyamide made of L ‐tartaric acid, and 1,6‐hexanediamine. In this structure, chains are slightly compressed and arranged as in the α‐form of nylon 66. Solid‐state nuclear magnetic resonance (NMR) revealed that ester groups are excluded from the crystal phase except for the case of the syndioregic polymer. Isothermal crystallization kinetics was analyzed according to the Avrami theory. Crystallization rates were found to decrease regularly with increasing contents in ester groups and with increasing crystallization temperature. Avrami exponent values close to 2 were found whereas spherulitic morphologies were observed by optical microscopy. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 116–125, 2007 相似文献
60.
Jairo Quijano Jorge David Claudia Snchez Elizabeth Rincon Doris Guerra Luis A. Len Rafael Notario Jos L. Abboud 《Journal of Molecular Structure》2002,580(1-3):201-205
Thermolysis studies of β-hydroxyolefins in gas phase were realized using ab initio MP2 and DFT methods at the 6-31G* levels to explore the possibility of determining a possible concerted process with a six-membered cyclic transition state (TS). Vibrational frequency calculations were carried out in order to confirm the stationary states, including TS structures. IRC calculations have been performed in all cases in order to verify that localized TS structures connect with the corresponding minimum stationary points associated with the reactant and products. With the aim of corroborating the postulated mechanism in the experimental study, we present a theoretical study in order to calculate the rate constants and the activation parameters. The results obtained are in accordance with the experimental conclusions. 相似文献