Electrostatic potential in a gravitational field

The electrostatic potential in a gravitational field is estimated up to the order ofe ² G ² in the framework of the conventional quantum field theory. It is shown that the electrostatic potential is different from the classical one. We find that this discrepancy is attributable to the process in which a particle emits three massless ones which are absorbed by three other particles.     

Effect of hydration on the induction of strand breaks and base lesions in plasmid DNA films by gamma-radiation

The yields of gamma-radiation-induced single- and double-strand breaks (ssb's and dsb's) as well as base lesions, which are converted into detectable ssb by the base excision repair enzymes endonuclease III (Nth) and formamidopyrimidine-DNA glycosylase (Fpg), at 278 K have been measured as a function of the level of hydration of closed-circular plasmid DNA (pUC18) films. The yields of ssb and dsb increase slightly on increasing the level of hydration (Gamma) from vacuum-dried DNA up to DNA containing 15 mol of water per mole of nucleotide. At higher levels of hydration (15 < Gamma < 35), the yields are constant, indicating that H2O*+ or diffusible hydroxyl radicals, if produced in the hydrated layer, do not contribute significantly to the induction of strand breaks. In contrast, the yields of base lesions, recognized by Nth and Fpg, increase with increasing hydration of the DNA over the range studied. The maximum ratios of the yields of base lesions to that of ssb are 1.7:1 and 1.4:1 for Nth- and Fpg-sensitive sites, respectively. The yields of additional dsb, revealed after enzymatic treatment, increase with increasing level of hydration of DNA. The maximum yield of these enzymatically induced dsb is almost the same as that for prompt, radiation-induced dsb's, indicating that certain types of enzymatically revealed, clustered DNA damage, e.g., two or more lesions closely located, one on each DNA strand, are induced in hydrated DNA by radiation. It is proposed that direct energy deposition in the hydration layer of DNA produces H2O*+ and an electron, which react with DNA to produce mainly base lesions but not ssb. The nucleobases are oxidized by H2O*+ in competition with its conversion to hydroxyl radicals, which if formed do not produce ssb's, presumably due to their scavenging by Tris present in the samples. This pathway plays an important role in the induction of base lesions and clustered DNA damage by direct energy deposition in hydrated DNA and is important in understanding the processes that lead to radiation degradation of DNA in cells or biological samples.     

Synthesis and absolute configuration of a new 3,4-dihydro-beta-carboline-type alkaloid, 3,4-dehydro-5(S)-5-carboxystrictosidine,isolated from Peruvian Uña de Gato (Uncaria tomentosa)

The structure including the absolute configuration of a new glucoalkaloid, 3,4-dehydro-5(S)-5-carboxystrictosidine, isolated from Peruvian U?a de Gato (Cat's Claw, original plant: Uncaria tomentosa), was confirmed by synthesis starting from secologanin and L-tryptophan.     

Photoemission spectroscopic evidence of gap anisotropy in an f-electron superconductor

We used low-temperature ultrahigh-resolution (360 microeV) photoemission spectroscopy with a laser as a photon source (Laser-PES) to study the superconducting (SC) gap of an f-electron superconductor CeRu2. The unique combination of the large escape depth expected from the known universal behavior and extremely high-energy resolution has enabled us to directly measure the bulk SC gap of an f-electron superconductor for the first time. The present study provides direct evidence for an anisotropic SC gap in CeRu2, and also demonstrates the potential of Laser-PES in investigating unconventional superconductivity realized in correlated d- and f-electron superconductors.     

Evidence for suppressed screening on the surface of high temperature La(2-x)SrxCuO4 and Nd2(2-x)CexCuO4 superconductors

Hard x-ray photoemission spectroscopy (PES) of Cu core electronic states, with a probing depth of approximately 60 A, is used to show that the Zhang-Rice singlet feature is present in La2CuO4 but is absent in Nd2CuO4. Hole and electron doping in La(2-x)SrxCuO4 (LSCO) and Nd(2-x)CexCuO4 (NCCO) result in new well-screened features which are missing in soft x-ray PES. Impurity Anderson model calculations establish screening from doped states as its origin, which is strongly suppressed within 15 A of the surface. Complemented with x-ray absorption spectroscopy, the small chemical-potential shift in core levels (approximately 0.2 eV) are shown to be consistent with modifications of valence and conduction band states spanning the band gap (approximately 1 eV) upon hole and electron doping in LSCO and NCCO.     

Interplay of superconductivity and rattling phenomena in beta-pyrochlore KOs2O6 studied by photoemission spectroscopy

The electronic structure near the Fermi level (EF) of the beta-pyrochlore superconductor KOs2O6 is studied using laser-excited ultrahigh-resolution photoemission spectroscopy. The superconducting gap clearly opens across the superconducting transition (Tc=9.6 K), with the strong electron-phonon coupling value of 2Delta(0)/k B Tc>or=4.56. A fitting analysis identifies clear anomalies at Tp=7.5 K in the temperature dependencies of the superconducting gap size and the quasiparticle relaxation lifetime. These anomalies and the fine spectral structures arising from phonons suggest that the existence of the rattling behavior of K ions significantly affects the superconductivity in KOs2O6.     

A reduction approach to the repeated assignment problem

We consider the repeated assignment problem (RAP), which is a K-fold repetition of the n × n linear assignment problem (LAP), with the additional requirement that no assignment can be repeated more than once. In actual applications K is typically much smaller than n. First, we derive upper and lower bounds respectively by a heuristic together with local search, and an efficient method solving the continuous relaxation. The latter also solves a Lagrangian relaxation, such that the related pegging test, to fix variables at zero or one, decomposes into K independent pegging tests to LAPs. These can be solved exactly by transforming them into all-pairs shortest path problems. Together with these procedures, we also employ a virtual pegging test and reduce RAP in size. Numerical experiments show that the reduced instances, with K ? n, can be solved exactly using standard MIP solvers.