Mössbauer spectra and electronic structure of nonequilibrium Fe-Cu alloys produced by vapor quenching

Mössbauer spectra have been observed for nonequilibrium bcc and fcc Fe–Cu alloys sputter-deposited at several Ar gas pressures,P _Ar. These alloys are ferromagnetic at low temperatures and show sextet spectra. The fcc alloys which are paramagnetic at 290 K show asymmetric doublet spectra, indicating no serious segregation. In the alloys deposited at highP _Ar, the weak intensity ratios of the second and fifth lines of the sextet indicate a tendency of perpendicular magnetic anisotropy, while a large magnetic hyperfine field component of about 40 MA/m (500 kOe) at 4.2 K and a large quadrupole splitting component of about 0.7 mm/s at 290 K imply CuFeO₂ formation. The nonequilibrium, bcc and fcc Fe–Cu, alloys are maintained below 500 K and the phase separation is detected above 550 K. X-ray photoemission spectroscopy studies of these alloys reveals individual Fe- and Cu-d bands. The concentration dependence of peak intensities and peak positions indicate that Fe and Cu electronically intermix.     

Isotope separation by laser-enhanced chemical reaction

Reactivity enhancement was studied using a reaction between a laser excited atomic beam and a molecular beam. This method was applied to lithium isotope separation, in which the excited Li isotopic atom reacts with CHCIF₂. It is found that the specified lithium isotope is enriched in the reaction product LiF, whereas LiCl has no selectivity.     

Recent developments in magnetism and magnetic materials

In the last decade we have obtained a deeper understanding of basic magnetism in alloys and a variety of new magnetic materials have been developed. In this review article two kinds of recent topics in these fields will be discussed. The first one is the magnetic properties of rare earth-3d transition intermetallics. After describing the magnetic properties of RMn₂ very briefly, we discuss the magnetic properties of YMn₂ in detail, particularly its magnetovolume effect which is closely related with the magnetic moment of Mn atoms below and above the magnetic transition temperature. Then, as an example of recent developments in soft magnetic materials, Fe-Ni-Cr alloys with very high permeability and low coercive force will be discussed including impurity effects on their magnetic properties.     

Unprecedented CO2-promoted aminochlorination of olefins with Chloramine-T

[STRUCTURE: SEE TEXT] A new synthetic procedure for the aminochlorination of olefins for the synthesis of vicinal chloroamine derivatives using a combination of Chloramine-T and carbon dioxide is described. The method can be applied to a variety of olefins, including an electron-sufficient olefin and a conjugated diene.     

Unprecedented 1,4-stannatropy: effective generation of azomethine ylides as nitrile ylide equivalents from N-(stannylmethyl)thioamides

Generation and cycloaddition of less- or non-stabilized azomethine ylides, or nitrile ylide equivalents, via unprecedented 1,4-stannatropy of N-(tributylstannylmethyl)thioamides were achieved. The reactions with dipolarophiles, such as electron-deficient alkenes and alkynes, afforded corresponding pyrrolidine and pyrrole derivatives effectively.     

The search for a hair-growth stimulant: new radicicol analogues as WNT-5A expression inhibitors from Pochonia chlamydosporia var. chlamydosporia

WNT-5A, a secretory glycoprotein, is related to the proliferation of dermal papilla cells. While searching for an inhibitor of WNT-5A expression, we identified an active compound, radicicol (1), and isolated four unique analogues, pochonins G-J (2-5), from a culture broth of the fungus Pochonia chlamydosporia TF-0480. Structural elucidation of 2-5 and their biological activities against WNT-5A are described.     

Subexponential instability in one-dimensional maps implies infinite invariant measure

We characterize dynamical instability of weak chaos as subexponential instability. We show that a one-dimensional, conservative, ergodic measure preserving map with subexponential instability has an infinite invariant measure, and then we present a generalized Lyapunov exponent to characterize subexponential instability.     

The Energetics of Large Deformations of a Single Polyimide Molecular Chain: DFT and MO Calculations

The large‐deformation energetics of a single molecular chain of the rod‐like polyimide PMDA‐PDA was investigated using DFT, ab initio MO and semi‐empirical MO methods. The force/displacement curves were calculated from tensile testing simulations along the axis of the molecular chain, allowing a discussion of the distribution and change of local strain of the molecular chain. The deformation behavior of a single PMDA‐PDA molecular chain under finite deformations as functions of bending angle and dihedral angle between PMDA and PDA groups are compared. It is found that the semi‐empirical MO calculations provide sufficient accuracy to express the energetics of large deformations except for compressive deformation.

     

Turbulence in diffusion replicator equation

Dynamical behaviors in the diffusion replicator equation of three species are numerically studied. We point out the significant role of the heteroclinic cycle in the equation, and analyze the details of the turbulent solution that appeared in this system. Firstly, the bifurcation diagram for a certain parameter setting is drawn. Then it is shown that the turbulence appears with the supercritical Hopf bifurcation of a stationary uniform solution and it disappears under a subcritical-type bifurcation. Secondly, the statistical property of the turbulence near the supercritical Hopf onset point is analyzed precisely. Further, the correlation lengths and correlation times obey some characteristic scaling laws.