The crystal structure of N‐[(1‐{2‐oxo‐2‐[2‐(pyrazin‐2‐ylcarbonyl)hydrazin‐1‐yl]ethyl}cyclohexyl)methyl]pyrazine‐2‐carboxamide monohydrate (Pyr‐Gpn‐NN‐NH‐Pyr·H2O), C19H23N7O3·H2O, reveals an unusual trans–gauche (tg−) conformation for the gabapentin (Gpn) residue around the Cγ—Cβ (θ1) and Cβ—Cα (θ2) bonds. The molecular conformation is stabilized by intramolecular N—H...N hydrogen bonds and weak C—H...O interactions. The packing of the molecules in the crystal lattice shows a network of strong N—H...O and O—H...O hydrogen bonds together with weak C—H...O and π–π inteactions. 相似文献
The unique mechanical performance of nacre, the pearly internal layer of shells, is highly dependent on its complex morphology. Inspired by the structure of nacre, the fabrication of well‐ordered layered inorganic–organic nanohybrids is presented herein. This biomimetic approach includes the use of a block copolymer template, consisting of hydrophobic poly(vinylidene fluoride) (PVDF) lamellae covered with hydrophilic poly(methacrylic acid) (PMAA), to direct silica (SiO2) mineralization. The resulting PVDF/PMAA/SiO2 nanohybrid material resembles biogenic nacre with respect to its well‐ordered and layered nanostructure, alternating organic–inorganic phases, macromolecular template, and mild processing conditions.
Journal of Radioanalytical and Nuclear Chemistry - Dissolved radon (222Rn) in drinking water has been measured using SMART RnDuo, a continuous radon monitor. Water samples have been collected from... 相似文献
Chromatographia - In this work, we present a new method for the determination and speciation of selenium in water with ion chromatography (IC) using a conductometric detector. Chromatographic... 相似文献
Chromatographia - Stability-indicating reverse-phase HPLC analytical method for the quantification of Paclitaxel (PTX) in the bulk and cationic liposomes was developed. The optimized method was... 相似文献