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排序方式: 共有236条查询结果,搜索用时 15 毫秒
51.
Abhaya K. Mishra Galit Parvari Irit Cohen Natalia Fridman Yoav Eichen 《Journal of Coordination Chemistry》2018,71(11-13):2082-2089
AbstractAmine-tetrachloromethane charge-transfer complexes have recently been shown to be useful intermediates in transition-metal free solar light-assisted organic synthetic chemistry. Of particular promise is the complex of 1,4-diazabicyclo[2.2.2]octane (DABCO) which may serve as a starting point for several potential reactions involving oxidation of organic compounds. Here we disclose the crystal structure of the [DABCO???CCl4] complex, and computational studies of two possible complex structures in their ground state, as well as in their first singlet and first triplet excited states. 相似文献
52.
An approach has been recently introduced for acquiring two-dimensional (2D) nuclear magnetic resonance images in a single scan, based on the spatial encoding of the spin interactions. This article explores the potential of integrating this spatial encoding together with conventional temporal encoding principles, to produce 2D single-shot images with moderate field of views. The resulting “hybrid” imaging scheme is shown to be superior to traditional schemes in non-homogeneous magnetic field environments. An enhancement of previously discussed pulse sequences is also proposed, whereby distortions affecting the image along the spatially encoded axis are eliminated. This new variant is also characterized by a refocusing of T2* effects, leading to a restoration of high-definition images for regions which would otherwise be highly dephased and thus not visible. These single-scan 2D images are characterized by improved signal-to-noise ratios and a genuine T2 contrast, albeit not free from inhomogeneity distortions. Simple postprocessing algorithms relying on inhomogeneity phase maps of the imaged object can successfully remove most of these residual distortions. Initial results suggest that this acquisition scheme has the potential to overcome strong field inhomogeneities acting over extended acquisition durations, exceeding 100 ms for a single-shot image. 相似文献
53.
Tal S Salman H Abraham Y Botoshansky M Eichen Y 《Chemistry (Weinheim an der Bergstrasse, Germany)》2006,12(18):4858-4864
Photoinduced-electron-transfer (PET)-based chemosensing is a very elegant way of reporting the presence of a guest species in solution. This method was successfully applied for the detection of different ionic species, such as cations, anions, and protons. Herein, we report on the application of the PET chemosensing concept for the efficient and selective detection of different alkylating agents. 2-(2-Dimethylaminoethyl)benzo[de]isoquinoline-1,3-dione (1) was found to be a highly selective and effective PET chemosensor that turns luminescent upon reacting with different alkylating agents. This PET-based system detected even rather weak alkylating agents, such as dichloromethane. A PET-based sensor that consists of 1 as the active component could detect rather low concentrations of alkylating agents in solution and in the gas phase. 相似文献
54.
55.
We consider an M / G / 1 queue in which the customers, while waiting in line, may renege from it. We show the Nash equilibrium profile among customers and show that it is defined by two sequences of thresholds. For each customer, the decision is based on the observed past (which determines from what sequence the threshold is taken) and the observed queue length (which determines the appropriate element in the chosen sequence). We construct a set of equations that has the Nash equilibrium as its solution and discuss the relationships between the properties of the service time distribution and the properties of the Nash equilibrium, such as uniqueness and finiteness. 相似文献
56.
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58.
Maria G. Corradini Veronique Stern Thongchai Suwonsichon Micha Peleg 《Rheologica Acta》2000,39(5):452-460
Samples of commercial tomato paste, low fat mayonnaise and mustard about 6–8 mm thick were squeezed to 0.8 mm at various
speeds between 5 mm min−1 and 25 mm min−1 between Teflon-coated parallel plates 127 mm in diameter using an Instron UTM Model 5542. All the log force vs log height
relationships had a clearly identified linear region. This indicated that a dominant squeezing flow regime was achieved at
about 3 mm height, and that the machine has the proper stiffness to perform the tests. The stress level at a pre-selected
height in this region is a measure of consistency, sensitive enough to distinguish between products of different brands. The
residual stress after relaxation for about 2 min was on order of 10–50% of the initial stress, an indication that all three
foods have a considerable structural integrity. In all three products there was a considerable discrepancy between the observed
rate effects and predictions based on a pseudoplastic (power law) model. It could be described by the empirical relation (Fv1 − FR)/(Fv2 − FR)=(V1/V2)m where Fv1 and Fv2 are the forces at the given displacement reached at speeds v1 and v2 respectively, FR is the residual force after relaxation (found to be practically rate independent), and m is a constant of the order of 0.15–0.33,
independent of the compression velocities ratio but characteristic of the food and brand. The calculated elongational viscosity
was not a unique function of biaxial strain rate. To a certain extent, this was probably due to imperfect lubrication. But
it was also a manifestation of these products considerable structural integrity which cannot be accounted for by models developed
for ideal liquids.
Received: 1 November 1999 Accepted: 2 May 2000 相似文献
59.
Carmit Hertzog‐Ronen Dr. Elena Borzin Yulia Gerchikov Nir Tessler Prof. Yoav Eichen Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(40):10380-10386
Alkylating agents are simple and reactive molecules that are commonly used in many and diverse fields such as organic synthesis, medicine, and agriculture. Some highly reactive alkylating species are also being used as blister chemical‐warfare agents. The detection and identification of alkylating agents is not a trivial issue because of their high reactivity and simple structure. Herein, we report on a new multispot luminescence‐based approach to the detection and identification of alkylating agents. In order to demonstrate the potential of the approach, seven π‐conjugated oligomers and polymers bearing nucleophilic pyridine groups, 1 – 7 , were adsorbed onto a solid support and exposed to vapors of alkylators 8 – 15 . The alkylation‐induced color‐shift patterns of the seven‐spot array allow clear discrimination of the different alkylators. The spots are sensitive to minute concentrations of alkylators and, because the detection is based on the formation of new covalent bonds, these spots saturate at about 50 ppb. 相似文献
60.
Avner Peleg 《Physics letters. A》2009,373(31):2734-2738
We study the dynamics of a probe soliton propagating in an optical fiber and exchanging energy in fast collisions with a random sequence of pump solitons. The energy exchange is induced by Raman scattering or by cubic nonlinear loss/gain. We show that the equation describing the dynamics of the probe soliton's amplitude has the same form as the equation for the local space average of energy dissipation in random cascade models in turbulence. We characterize the statistics of the probe soliton's amplitude by the τq exponents from multifractal theory and by the Cramér function S(x). We find that the nth moment of the two-time correlation function and the bit-error-rate contribution from amplitude decay exhibit power-law behavior as functions of propagation distance, where the exponents can be expressed in terms of τq or S(x). 相似文献