Unique geometric and electronic structure of CO adsorbed on Ge(100): A DFT study

CO adsorption on the Ge(100) surface has been investigated using a slab model with density functional theory implemented in SIESTA. CO was found to be exclusively adsorbed on the asymmetric dimer with C attaching on the lower Ge dimer atom. The adsorption process is barrierless. The calculated adsorption energy and vibration frequencies are comparable to previous experimental results. The crystal orbital Hamilton analysis showed that the bonding between Ge and CO is mainly attributable to the Ge 4p_z orbital overlapping with C 2 s, or with CO molecular orbitals 3σ and 4σ. The repulsive energy between adsorbed CO molecules is less than 1 kcal/mol. The diffusion barrier of CO on the Ge(100) surface is about 14 kcal/mol.     

Evaluation of an oral carrier system in rats: bioavailability and gastrointestinal absorption properties of curcumin encapsulated PBCA nanoparticles

A new oral delivery system, polybutylcyanoacrylate nanoparticles (PBCNs), was introduced to improve the oral bioavailability of curcumin (CUR), a poorly soluble drug. The formulation was optimized by orthogonal design and the optimal PBCNs loading CUR exhibited a spherical shape under transmission electron microscopy with a range of 40?C400?nm. Physicochemical state of CUR in PBCN was investigated by X-ray diffraction and the possible structure changes occurring in CUR after conjugating with polybutylcyanoacrylate were studied with FTIR. The results indicated that CUR in PBCN was in a non-crystalline state and CUR was encapsulated in PBCN without chemical reaction. The oral pharmacokinetic study was conducted in rats and the relative bioavailability of CUR encapsulated PBCNs to the crude CUR was more than 800%. The in situ absorption experiment in rat intestine indicated the absorption was first order with passive diffusion mechanism. The absorption results in various segments of intestine showed that the main absorption sites were ileum and colon. It can be concluded that PBCNs as an oral carrier can significantly improve the oral absorption of a poorly soluble drug.     

应用于ICF实验的软X射线平面镜反射率

在北京同步辐射装置上,通过对应用于惯性约束聚变（ICF）实验的平面镜反射率的进一步研究,提高了辐射温度的测量精度。进行了对软X射线平面镜反射率的测量、反射镜的清洗、反射率的模拟计算,证明影响反射率变化的主要因素是平面镜的安装角度和沾污。实验结果表明:平面镜的沾污主要来源于ICF实验中的油沾污,采用射频辉光放电清洗非常有效。     

CMOS电路总剂量效应最劣偏置甄别

采用电路分析和解析建模方法研究了CMOS电路中甄别总剂量效应最劣辐照与测试偏置的问题。通过引入小规模模拟电路和数字电路的例子进行具体分析,获取了不同电路的最劣偏置情况。对于数字电路,引入了敏感因子的概念用于定量计算不同辐照与测试偏置组合下电路的总剂量效应敏感程度。利用实测数据或电路仿真结果对甄别结果进行了一一验证,得到相一致的结论,证明了该研究思路的正确性。     

The formation of different structures in the interaction between a single femtosecond laser pulse and a thin Au film

The interactions between femtosecond (fs) laser pulses and a thin Au film deposited on a silica glass substrate were systematically investigated based on experimental data. Different structures, including microholes, nanoholes, and nanobumps, are obtained when pulses with different energies are incident on the surface of a gold film. The experimental results are discussed according to specific experimental parameters. Two physical models were constructed in order to explain the experimental results. The formation of nanoholes in a silica substrate is attributed to etching by higher order harmonic generations (HHG) when the femtosecond laser pulse interacts with the generated plasma layer, while the formation of nanobumps on the surface of an Au film is attributed to the elastic and plastic characteristics of the metal film under laser pulse irradiation.     

太阳能电池陷光结构辐射特性研究

本文分析了不同微结构、电池厚度对太阳能电池光损失的影响,提出了一种新的电池陷光结构。运用时域有限差分法(FDTD)仿真了该类太阳能电池陷光结构中光传输过程,获得了不同波源入射下陷光结构电池的储能特性和光捕获特性,优化设计了最佳陷光结构并分析了其光捕获性能。     

基于高频雷达多普勒谱预测风向的一种新方法

通过高频雷达一阶多普勒谱与海上风向的关系, 提出了一种基于神经网络和多波束采样法相结合预测海面风向的新方法. 在神经网络不同输入、输出参数情况下对扩展因子为奇数时的仿真数据进行了风向预测, 并在扩展因子为偶数时结合多波束采样法进行风向预测, 消除了风向的模糊性. 通过预测数据和仿真数据对比, 发现两者符合较好. 从神经网络和多波束采样法相结合的预测结果中可以看出, 风向的误差大约为4°—6°, 风向扩展因子的平均误差为0.26, 为预测海面风场的研究提供一种新的思路和方法.     

光纤受激调制不稳定性的谱理论

利用多重尺度微扰法,直接从包含非线性极化项的麦克斯韦方程组出发,得到了在频域描述光纤中的受激调制不稳定性的谐波耦合方程组,在此基础上,得出了受激调制不稳定性的谱分布的一些数字结果。