Effects of Air/H<Subscript>2</Subscript>O Discharge Plasma on Propane Combustion Enhancement Using Dielectric Barrier Discharges

Combustion provides about 80% energy for our daily life and industrial production. But thermal efficiency of traditional combustion technologies is low, which causes energy waste and serious environmental pollution. In order to improve the combustion efficiency, a combined method based on non-equilibrium plasma generated by dielectric barrier discharge and OH radicals coming from water-steam additive was proposed in this work, and plasma assisted propane combustion was examined and evaluated. The results indicated that when relative humidity (RH) was 20% and applied peak voltage was fixed at 8.75 kV, the relative intensity of OH radical and the flame temperature reached the maximum value at the flame root. At the same time, propane combustion was the most complete. In addition, we found that the erosion of the inner electrode was weakened by H₂O addition, and the symmetry of discharge current was changed from symmetry to asymmetry with the increase of RH. Compared with the pure air undischarged combustion, when the relative humidity was 20% and under the discharge conditions of 8.75 kV, the lean-burn extinction limit was extended to 0.4,which is far lower than the traditional lean-burn limit (0.51).     

双核钯配合物Pd2L2和Pd2L2X2(L=Me2PCH2PMe2;X=F,Cl,Br,I,H)的量子化学理论研究

采用 ab initio HF,MP2方法和密度泛函理论方法,对Pd(0),Pd(Ⅰ)双核配合物Pd2L2和Pd2L2X2(L=Me2PCH2PMe2;X=F,Cl,Br,I,H)的儿何结构和电子结构进行了研究.研究表明Pd2L2中Pd原子间的相互作用丰要来自电子相关效应,Pd2L2X2中Pd原子问的相互作用则主要来自d轨道的成键作用.MP2方法和局域泛函Xa方法能对两类配合物的几何结构给予准确的描述.在Pd2L2中,Pd原子的4d电了组成一一对应的成键、反键轨道,轨道作用相互抵消使Pd原子间仅存在微弱的相互作用.x原子与Pd2L2的作用使Pd-Pd反键轨道电子占据数减少,成键作用加强.两类配合物的Pd-Pd键长与NAO键级之间存在很好的线性关系.还对Pd2L2和Pd2L2X2的低占据电子激发态进行了含时密度泛函理论计算,分析不同配合物的电子跃迁特征,并就卤素配体对Pd2L2X2光谱性质的影响进行了讨论.     

快前沿直线脉冲变压器驱动源多间隙气体开关

进行了一种可用于快前沿直线脉冲变压器驱动源系统的多间隙气体开关的设计和实验,给出了开关的静态放电实验结果,获得了静态击穿电压平均值及标准偏差随气体压强的变化规律。开关充0.15 MPa干燥空气时,最高耐压可以达到200 kV。研究了开关在不同欠压比和不同触发脉冲幅值下的触发特性。开关工作电压150 kV、欠压比78.5%、触发电压70 kV时,开关的触发延迟时间34.4 ns,抖动1.6 ns。开关经过5 000余次放电,击穿点分布均匀,可以形成多通道放电。开关结构新颖,安装操作简便,装配精度大大提高,实用性强。     

Visible‐Light Photoredox‐Catalyzed C−H Difluoroalkylation of Hydrazones through an Aminyl Radical/Polar Mechanism

An unprecedented visible‐light‐induced direct C?H bond difluoroalkylation of aldehyde‐derived hydrazones was developed. This reaction represents a new way to synthesize substituted hydrazones. The salient features of this reaction include difluorinated hydrazone synthesis rather than classical amine synthesis, extremely mild reaction conditions, high efficiency, wide substrate scope, ease in further transformations of the products, and one‐pot syntheses. Mechanistic analyses and theoretical calculations indicate that this reaction is enabled by a novel aminyl radical/polar crossover mechanism, with the aminyl radical being oxidized into the corresponding aminyl cation through a single electron transfer (SET) process.     

Novel fluorescent sensor for Ag and Hg based on the BINOL-pyrene derivative via click reaction

A novel BINOL-pyrene derivative sensor 1 for Ag⁺ and Hg²⁺ incorporating the triazole moieties and pyrenes was synthesized via click reaction. Binding of Ag⁺ ion induces the formation of 1:1 Ag⁺-1 chelating complex, and occurs in a ratiometric manner through an enhanced monomer and declining excimer emission, which make it possible to ratiometrically detect Ag⁺. The competitive experiment shows 1 can be used as an Ag⁺ specific fluorescence sensor over a wide range of competing cations. In the meanwhile, the sensor 1 was found to be selectively quenched by only Hg²⁺ at both monomer and excimer emission. Furthermore, we obtained evidences for different fluorescence signaling behaviors with Ag⁺ and Hg²⁺ by ¹H NMR titration experiments.     

聚丁二酸丁二酯/纳米高岭土共混体系结晶及力学性能研究

用熔融共混法制备聚丁二酸丁二酯(PBS)/纳米高岭土(nano kaolin)复合降解材料,利用FTIR、DSC、万能拉力机和SEM对其微观结构、结晶、力学性能及分散性进行研究.FTIR光谱分析结果表明,改性剂与nano kaolin发生了化学键合作用;DSC结果表明,在PBS中加入nano kaolin,提高了结晶起...     

Exact explicit traveling wave solutions for two nonlinear Schrödinger type equations

The traveling wave solutions of the generalized nonlinear derivative Schrödinger equation and the high-order dispersive nonlinear Schrödinger equation are studied by using the approach of dynamical systems and the theory of bifurcations. With the aid of Maple, all bifurcations and phase portraits in the parametric space are obtained. All possible explicit parametric representations of the bounded traveling wave solutions (solitary wave solutions, kink and anti-kink wave solutions and periodic wave solutions) are given.     

石墨量热计测量相对论电子能谱的数值模拟

采用数值实验的方法对石墨量热计测量电子能谱的过程进行了模拟,并对解谱方法进行了研究。使用MCNP软件建立了实验模型,根据不同能量入射电子能量沉积分布情况确立了入射电子能量-沉积能量的传递函数,研究确定合适的函数求解方法,并采用添加人为扰动的方式对该函数求解方法的可靠性进行分析,最终得到了有效的解谱方法。