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971.
We give an explicit formula of the quasihyperbolic distance from a point to a line in the once punctured plane and prove the geodesic is orthogonal to the line. By this result, we give an affirmative answer to the open problem in the case of twice and thrice punctured planes raised by Klén and generalize their estimates. We also construct an example to show that the cosine inequality does not hold in twice or thrice punctured planes. 相似文献
972.
Ang Qian Yee Chan Florence Tan Pei Chin Low Siew Chun 《Journal of Sol-Gel Science and Technology》2018,86(1):226-238
Journal of Sol-Gel Science and Technology - Molecularly imprinted polymer (MIP) is of great attention in biomimetic recognition systems due to its selective molecular recognition towards any guest... 相似文献
973.
Yue‐Hu Wang Qian‐Yun Sun Fu‐Mei Yang Chun‐Lin Long Fu‐Wei Zhao Gui‐Hua Tang Hong‐Mei Niu Huan Wang Qiao‐Qin Huang Jin‐Jin Xu Li‐Juan Ma 《Helvetica chimica acta》2010,93(12):2467-2477
Ten new phenolic compounds including the six neolignans 1 – 3 and 6 – 8 and four caffeoyl derivatives, i.e., myo‐inositol 1‐caffeate ( 9 ), myo‐inositol 6‐caffeate ( 10 ), myo‐inositol 5‐caffeate ( 11 ), and paucine 3′‐β‐D ‐glucopyranoside ( 12 ) were isolated from the whole plants of Selaginella moellendorffii (caffeic acid=3‐(3,4‐dihydroxyphenyl)prop‐2‐enoic acid). Their structures were established by spectroscopic and chemical methods. 相似文献
974.
Jun‐Qing Wen Zhen‐Yi Jiang Jun‐Qian Li Li‐Ke Cao San‐Yan Chu 《International journal of quantum chemistry》2010,110(7):1368-1375
Density‐functional with generalized gradient approximation (GGA) for the exchange‐correlation potential has been used to calculate the energetically global‐minimum geometries and electronic states of NinAl (n = 2–8) neutral clusters. Our calculations predict the existence of a number of previously unknown isomers. All structures may be derived from a substitution of a Ni atom at marginal positions by an Al atom in the Nin+1 cluster. Aluminum atom remains on the surface of the geometrical configurations. Moreover, these species prefer to adopt three‐dimensional (3D) spacial forms at the smaller number of nickel atoms compared with the pure Nin+1 (n ≥ 3) configuration. Atomization energies per atom for NinAl (n = 2–8) have the same trend as the binding energies per atom for Nin (n = 3–9). The stabilization energies reveal that Ni5Al is the relatively most stable in this series. In comparison with the magnetic moment of pure metal nickel (0.6 μB), the average magnetic moment of Ni atom increases in Ni Al clusters except the Ni3Al. Moreover, except the case of Ni5Al, Ni average magnetic moment decreases when alloyed with Al atoms than that in pure Ni clusters, which originate the effective charge transferring from Al to Ni atoms. © 2009 Wiley Periodicals, Inc. Int J Quantum Chem, 2010 相似文献
975.
976.
977.
We report the controlled growth of Au25(SR)18 and Au38 (SR)24 (where R = CH2CH2Ph) nanoclusters of molecular purity via size-focusing from the same crude product that contains a distribution of nanoclusters. In this method, gold salt was first mixed with tetraoctylammonium bromide (TOAB), and then reacted with excess thiol to form Au(I)-SR polymers in THF (as opposed to toluene in previous work), followed by NaBH 4 reduction. The resultant crude product contains polydisperse nanoclusters and was then used as the common starting material for controlled growth of Au25(SR)18 and Au38(SR)24 , respectively. In Route I, Au25(SR)18 nanoclusters of molecular purify were produced from the crude product after 6 h aging at room temperature. In Route II, the crude product was isolated and further subjected to thermal thiol etching in a toluene solution containing excess thiol, and one obtained pure Au38(SR)24 nanoclusters, instead of Au25(SR)18 . This work not only provides a robust and simple method to prepare both Au25(SR)18 and Au38(SR)24 nanoclusters, but also reveals that these two nanoclusters require different environments for the size-focusing growth process. 相似文献
978.
Nickel hydroxide mesoporous structures are synthesized by a simple method in the presence of different additives (oxalic acid, aminoacetic acid, and sulfosalicylic acid). Structural characterizations reveal that the additives can affect the crystal structure, increase the specific surface area, and reduce the pore size of the products. The electrochemical properties of the synthesized Ni(OH)2 samples are dependent on their crystal phase, surface area, and pore size distribution. Mesoporous β-Ni(OH)2 with poor crystallinity shows high specific capacitances at different current densities and excellent cycling ability. A highest specific capacitance of 1,693 F?g?1 can be achieved at a scan rate of 5 mV?s?1. The results suggest its potential application in electrochemical supercapacitors. 相似文献
979.
Zuliang Luo Weijun Kong Feng Qiu Meihua Yang Qian Li Riwei Wei Xiaoli Yang Jieping Qin 《Journal of separation science》2013,36(4):699-705
A simple and sensitive HPLC coupled with photodiode array (HPLC–PDA) method was developed for simultaneous determination of seven lignans in Justicia procumbens using relative response factors (RRFs). The chromatographic separation was performed on a Shiseido Capcell Pak C18 column (250 × 4.6 mm id, 5 μm), a gradient elution of acetonitrile/water, and a photodiode array detector. The column temperature was maintained at 35°C and the detection wavelength was set at 256 nm. Chinensinaphthol methyl ether was selected as the reference compound for calculating the relative response factors of the lignans. It has shown that the RRFs for lignans are quite similar at 256 nm of detection under different analytical conditions (different columns and HPLC instruments). Using RRFs, not every lignan is needed as a reference standard, making the method ideal for rapid, routine analysis, especially for those laboratories where lignans standards are not readily available. An economic and practicable HPLC method using RRFs was established for the determination of seven lignans in J. procumbens. This method not only can determine multiple indexes in traditional Chinese medicines (TCMs) simultaneously, but also resolve the problem of lacking of chemical standards. It will be a good quality evaluation method and pattern for TCMs. 相似文献
980.