电沉积－退火工艺制备铜铟硒太阳能电池薄膜及表征

利用电沉积硒气氛下后续退火的工艺制备出了高结晶质量的铜铟硒薄膜．通过X射线衍射、扫描电子显微镜、拉曼光谱、紫外-可见-近红外光谱和阻抗谱技术对退火后的铜铟硒薄膜进行表征,结果表明530 oC硒化退火后的铜铟硒薄膜具有四方的黄铜矿晶体结构,晶粒尺寸达到微米量级,光学带隙为0.98 eV,经过KCN溶液去除表面高导电性的铜硒化合物后铜铟硒薄膜的载流子浓度在10¹⁶ cm^-3量级．利用硒化退火的铜铟硒薄膜作为光吸收层制备了结构为AZO/i-ZnO/CdS/CIS/Mo/glass的太阳能电池,在AM1.5光照条件下对其电流-电压特性测试后发现面积为0.2 cm²的电池可以达到0.96％的能量转换效率,并对限制电池效率的原因做出了初步的分析和讨论.     

胸腺嘧啶低能量VUV光解离路径的实验和理论研究

利用同步辐射真空紫外光电离质谱和理论计算研究了胸腺嘧啶的光解离反应路径, 通过改变光子能量得到不同的质谱信号, 光子能量在12.0 eV时主要的碎片有m/z=98 (C₄H₆N₂₄O⁺)、97 (C₄H₅N₂O⁺)、84 (C₃H₄N₂O⁺或C<     

Isospin splittings of doubly heavy baryons

The SELEX Collaboration has reported a very large isospin splitting of doubly charmed baryons. We show that this effect would imply that the doubly charmed baryons are very compact. One intriguing possibility is that such baryons have a linear geometry Q–q–Q$Q\text{–}q\text{–}Q$ where the light quark q oscillates between the two heavy quarks Q  , analogous to a linear molecule such as carbon dioxide. However, using conventional arguments, the size of a heavy-light hadron is expected to be around 0.5 fm, much larger than the size needed to explain the observed large isospin splitting. Assuming the distance between two heavy quarks is much smaller than that between the light quark and a heavy one, the doubly heavy baryons are related to the heavy mesons via heavy quark–diquark symmetry. Based on this symmetry, we predict the isospin splittings for doubly heavy baryons including Ξ_cc${\Xi }_{cc}$, Ξ_bb${\Xi }_{bb}$ and Ξ_bc${\Xi }_{bc}$. The prediction for the Ξ_cc${\Xi }_{cc}$ is much smaller than the SELEX value. On the other hand, the Ξ_bb${\Xi }_{bb}$ baryons are predicted to have an isospin splitting as large as (6.3±1.7) MeV$(6.3\pm 1.7)\text{MeV}$. An experimental study of doubly bottomed baryons is therefore very important to better understand the structure of baryons with heavy quarks.     

Laser-induced damage characteristic of porous alumina optical films

Pure aluminum films were deposited on B270 glass by electron beam evaporation technique. The aluminum films, which were used as anode, were placed in phosphoric acid to prepare porous alumina films using a two-step anodization method. They were subsequently annealed in high temperature to improve transmission. The microstructure, transmitted spectrum and laser damage characteristics of the alumina films were then tested. Their microstructure formed in phosphoric acid was retiform. The transmissivity can be increased efficiently if the annealing temperature is adequately high. The laser-damaged spots of the porous films were formed by innumerable small damaged pits with no mutual effect. In contrast, the laser-damaged spots of the compact films were formed by several larger damaged pits which acted together toward expansion. The damage process of the porous films comprised heat ablation and stress fracture.     

Reflection chromaticity of cholesteric liquid crystals with sandwiched periodical isotropic defect layers

We study one-dimensional photonic crystals made of cholesteric liquid crystals with sandwiched isotropic defect layers. Based on the Berreman Fast 4 × 4 matrix method, the dispersion relation of one-dimensional photonic crystals is calculated and the corresponding reflection chromaticity is obtained. It is found that the color shift could be controlled by adjusting the thickness and refractive index of the isotropic defect layers. Compared with conventional structures, the reflection chromaticity of this structure is insensitive to the incident angle, if the thickness ratio of the cholesteric liquid crystals to that of the isotropic defect layers and the refractive index of periodical isotropic defect layers are properly set. Furthermore, the common forbidden bands for both left and right circular polarizations can be obtained, and we also take the wavelength-dependent refractive indices into consideration and obtain the reflected light chromaticity with the incident angle increasing. The proposed device can be used as a reflective color filter in the display industry.     

一种破译混沌直接序列扩频保密通信的方法

提出了一种新型的混沌保密通信破译方法,并破译了混沌直接序列扩频保密通信(简称混沌直扩).针对混沌直扩信号中只有一个混沌吸引子的特点,基于混沌系统广义同步的思想,提出了混沌拟合方法;针对混沌直扩中混沌实值序列和数字信号相乘的特点,充分利用混沌直扩的基本原理和信息码是慢变信号的特性,提出了用无先导卡尔曼滤波混沌拟合的方法估计信息码的破译方法;进一步针对无先导卡尔曼滤波的过程噪声和混沌拟合的拟合误差共同导致的跟踪误差,提出了跟踪误差控制因子的方法,从而将跟踪误差转变成有利因素并加以利用,根据跟踪误差的值域范围破     

多源共蒸发制备高性能REBa2Cu3O7-x涂层导体的进展与展望

REBa2Cu3O7-x (RE：钇、钆等稀土元素,REBCO）高温超导体因其具备较高的不可逆场和上临界场等优越性能,一经发现就备受关注。但由于材料本身固有的陶瓷性及弱连接等属性,导致其实际应用起来难度较大。目前,人们已经发展了诸多制备工艺来克服这些困难,实现了REBCO超导体的实际应用。按照前驱膜沉积方法可将REBCO超导薄膜的制备分为物理法和化学法。本文综述了物理气相沉积（PVD-Physical Vapor Deposition）法中多源共蒸发法制备REBCO超导薄膜的技术起源及演变历程,并与金属有机沉积、金属有机化学气相沉积、脉冲激光沉积等不同方法生产的REBCO超导带材进行对比,突出多源共蒸发法制备的REBCO薄膜性能优异、在商业化生产效率上具有更大的优势。最后对多源共蒸发法制备REBCO超导薄膜进行总结及展望,解决多源共蒸发沉积制备REBCO薄膜的成相机理、提高薄膜的钉扎中心等问题对未来第二代高温超导带材的大规模应用具有重要意义。     

Revisiting the security of quantum dialogue and bidirectional quantum secure direct communication

From the perspective of information theory and cryptography, the security of two quantum dialogue protocols and a bidirectional quantum secure direct communication (QSDC) protocol was analyzed, and it was pointed out that the transmitted information would be partly leaked out in them. That is, any eavesdropper can elicit some information about the secrets from the public annunciations of the legal users. This phenomenon should have been strictly forbidden in a quantum secure communication. In fact, this problem exists in quite a few recent proposals and, therefore, it deserves more research attention in the following related study. Supported by the National High Technology Research and Development Program of China (Grant No. 2006AA01Z419), the National Natural Science Foundation of China (Grant Nos. 90604023 and 60373059), the National Research Foundation for the Doctoral Program of Higher Education of China (Grant No. 20040013007), the National Laboratory for Modern Communications Science Foundation of China (Grant No. 9140C1101010601), the Natural Science Foundation of Beijing (Grant No. 4072020) and the ISN Open Foundation