三氧化钨/氧化银复合材料的水热法合成及其光催化降解性能研究

染料污染是水污染中最严重的问题之一,吸引了很多科学家的关注.人们尝试了很多方法去解决该问题,如化学氧化法、物理吸附法、光催化降解法和生物降解法等.与其他几种方法相比,光催化法有着低能耗、环保以及高效等优势.三氧化钨是常见的半导体材料,具有独特的光学性能,近年来受到了广泛的研究.本文以钨酸钠和硫脲为前驱体,通过水热法制备了三氧化钨/氧化银(WO_3/Ag_2O)复合材料,并用光催化降解亚甲基蓝来分析其光催化性能.通过X射线光电子能谱、X射线衍射、透射电子显微镜、扫描电子显微镜、紫外可见吸收光谱等表征手段对样品的形貌、晶格结构和光催化的性能进行表征.氧化银的带宽为1.2 e V,对可见光很敏感,三氧化钨和氧化银的复合使材料在可见光下的光催化活性显著增强,在可见光下对亚甲基蓝染料的光降解率可以达到98%.实验结果表明,复合材料中的三氧化钨纳米棒为六方相,其平均直径约为200 nm,平均长度约为4μm.而复合材料中的氧化银纳米颗粒为六方相,附着在氧化钨纳米棒的表面,平均晶粒尺寸为20 nm.氧化银的存在为复合材料提供了更多的反应活性位点.相较于单一组分,复合材料在可见光下的光吸收度更高,这说明三氧化钨和氧化银的复合改变了材料的能带结构.研究发现,三氧化钨和氧化银之间形成的异质结构是其优良光催化性能的来源.此外,三氧化钨和氧化银复合材料还具有良好的催化稳定性和化学稳定性.本文结果表明,可以通过给宽带隙的半导体材料复合一些带隙合适的金属氧化物以提升其光催化活性.     

偶氮侧基聚合物光致异构动力学研究

本文对偶氮侧基聚合物相位共轭光时间特性进行了研究,得到了相位共扼光产生机制─光致异构过程的时间常数.在相位共轭光上升阶段,其时间常数在0.4～0.5s之间,在相让共轭光的衰减过程,衰减满足双指数关系,分段拟合得到较好的结果,且得到快过程的时间常数为0.27s,慢过程的时间常数为0.78s.     

On the far field in the Lorenz-Mie theory and T-matrix formulation

The far field within the context of the Lorenz-Mie theory and the T-matrix formulation is usually expressed on the basis of the asymptotic properties of vector spherical waves. The radiation condition is taken into account by employing proper vector spherical functions as the expansion basis of the scattered field. The asymptotic behavior of the Hankel function is obtained from differential equations. The asymptotic far field can also be obtained from the Kirchhoff surface integral equation, in which the radiation condition has been implemented when it is derived from the Maxwell equations. This note is to present an explicit establishment of the relationship between the asymptotic far field and the near field in the Lorenz-Mie theory and the T-matrix formulation through the Kirchhoff surface integral.     

Exergetic efficiency optimization for an irreversible heat pump working on reversed Brayton cycle

This paper deals with the performance analysis and optimization for irreversible heat pumps working on reversed Brayton cycle with constant-temperature heat reservoirs by taking exergetic efficiency as the optimization objective combining exergy concept with finite-time thermodynamics (FTT). Exergetic efficiency is defined as the ratio of rate of exergy output to rate of exergy input of the system. The irreversibilities considered in the system include heat resistance losses in the hot- and cold-side heat exchangers and non-isentropic losses in the compression and expansion processes. The analytical formulas of the heating load, coefficient of performance (COP) and exergetic efficiency for the heat pumps are derived. The results are compared with those obtained for the traditional heating load and coefficient of performance objectives. The influences of the pressure ratio of the compressor, the allocation of heat exchanger inventory, the temperature ratio of two reservoirs, the effectiveness of the hot- and cold-side heat exchangers and regenerator, the efficiencies of the compressor and expander, the ratio of hot-side heat reservoir temperature to ambient temperature, the total heat exchanger inventory, and the heat capacity rate of the working fluid on the exergetic efficiency of the heat pumps are analysed by numerical calculations. The results show that the exergetic efficiency optimization is an important and effective criterion for the evaluation of an irreversible heat pump working on reversed Brayton cycle.     

A tunable multi-wavelength Brillouin–erbium fiber laser with fourfold Brillouin frequency spacing

We have experimentally demonstrated a tunable multi-wavelength Brillouin–erbium fiber laser with over 40 GHz spacing utilizing two cascaded double Brillouin-frequency-spacing cavities. In this laser configuration, two segments of 25 km-long single-mode fibers are used as Brillouin gain medium in each ring cavity, and a segment of 8 m-long erbium-doped fiber with 980 nm pump is employed to amplify Brillouin pump (BP). At BP wavelength of 1550 nm, BP power of 8.3 dBm (6.8 mW) and the maximum 980 nm pump power of 27.78 dBm (600 mW), seven output channels with fourfold Brillouin-frequency spacing, and the tuning range of 15 nm from 1545 to 1560 nm are achieved. The proposed multi-wavelength Brillouin–erbium fiber laser has wide applications, such as in microwave signal generation and optical communications.     

Decay of metastable states in Nd II

The difficulty associated with an accurate determination of transition rates for forbidden lines in lowly ionized heavy elements is illustrated in the case of Nd II. We have investigated the radiative decay of the low-lying metastable levels in Nd⁺ including the two levels K_11/2 and I_13/2. In these two particular cases, using different theoretical approaches, we find that the decay is dominated by the M1 channels but that the E2 contributions are of the same order of magnitude. These levels have also been studied experimentally by lifetime measurements with the heavy ion storage ring CRYRING of Stockholm University. The difficulties encountered when performing such experiments are underlined and discussed.     

Experimental and theoretical lifetimes in Yb III

Lifetimes of three levels belonging to the configuration 4f ¹³5d with J = 1 in Yb III have been measured for the first time using the time-resolved laser-induced fluorescence method. Experimental transition probabilities have been deduced for the transitions between the levels studied and the ground state. The comparison of the experimental lifetimes with theoretical data, deduced within the relativistic Hartree-Fock (HFR) approach, underlines the dramatic importance of an adequate consideration of core-polarization effects in the theoretical model and the sensitivity of one of the lifetime values to small correlation effects. Received 2 April 2001     

锶460.7 nm法拉第色散光学滤波器的滤波特性分析

分析了处于夫琅禾费暗线的Sr 460.7nm法拉第色散光学滤波器线翼和线芯工作的滤光特性,研究了磁场,温度和池长对滤波特性的影响,讨论了在其最佳的工作条件下,线芯透射率为95％,线宽为1．47GHz。     

Gamma rays from dark matter annihilation in the Draco and observability at ARGO

The CACTUS experiment recently observed a gamma ray excess above 50 GeV from the direction of the Draco dwarf spheroidal galaxy. Considering that Draco is dark matter dominated, the gamma rays may be generated through dark matter annihilation in the Draco halo. In the framework of the minimal supersymmetric extension of the standard model we explore the parameter space to account for the gamma ray signals at CACTUS. We find that the neutralino mass is constrained to be approximately in the range between 100 GeV∼400 GeV and a sharp central cuspy of the dark halo profile in Draco is necessary to explain the CACTUS results. We then discuss further constraints on the supersymmetric parameter space by observations at the ground-based ARGO detector. It is found that the parameter space can be strongly constrained by ARGO if no excess from Draco is observed above 100 GeV.     

基于波叠加法的近场声全息空间分辨率增强方法

提出一种基于波叠加法的近场声全息空间分辨率增强方法. 该方法在波叠加法的基础上,利用全息面声压信号求得布置在全息面附近的虚源面上的简单源源强,再根据求得的简单源源强实现对全息面声压的插值,进而利用插值后的全息面声压数据进行重建. 该方法可以提高近场声全息重建图像的空间分辨率,减少测量工作量,简化测量过程. 通过仿真对影响插值结果的参数进行了分析,给出了合理的选取范围;通过仿真和实验研究验证了该方法的有效性. 关键词： 波叠加法 近场声全息 空间分辨率