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31.
研究了乙酸溶剂中无引发剂条件下,Co掺杂MCM-41催化过氧化氢(30%)氧化4-甲基吡啶的反应,催化剂表现出高底物转化率和产物吡啶甲酸选择性以及良好的再生性。 探讨了不同溶剂、反应时间、反应温度、催化剂用量等对H2O2氧化4-甲基吡啶反应的影响,确定较优反应条件为m(4-甲基吡啶)∶m(催化剂)=10∶1,V(4-甲基吡啶)∶V(冰醋酸)=1∶10,温度363 K,时间6 h。 该条件下4-甲基吡啶的转化率为96.5%,4-吡啶甲酸的选择性为91.4%。 探讨了可能的反应机理。 相似文献
32.
In this paper it is proved that every sufficiently large even integer N satisfying one of the congruence conditions N ≡ 10, 58, 130, or 178(mod 240) may be represented as the sum of one square and nine fourth powers of prime numbers. 相似文献
33.
Orthogonal frequency division multiplexing passive optical network (OFDM-PON) has been considered a promising access solution to meet the variable bandwidth demand. In this paper, a novel scheduling for dynamic bandwidth allocation (DBA) at medium access control (MAC) layer is proposed for uplink transmission of OFDM-PON. In order to utilize the bandwidth efficiently, scheduling in four dimensions is adopted in the proposed DBA algorithm. Four dimensions stand for frequency domains, time domains, modulation formats and power allocations. The algorithm is quite flexible. Simulation results and analysis show that the proposed algorithm can efficiently utilize the OFDM bandwidth and make the system highly energy-efficient. 相似文献
34.
Cai Yingchun 《数学学报(英文版)》1997,13(4):443-452
The asymptotic formulae for the third and fourth power moments of Fourier coefficients of cusp forms are proved in this paper. 相似文献
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Based on cyanine dye probe oxazole yellow (YO) and Cy3, a series of novel styryl cyanine dyes were designed and synthesized. Carbazole was inserted into the structures of YO and Cy3 to act as a bridge to link the benzoxazole and indole group. This modification resulted in a novel kind of benzoxazole indole styryl cyanine dye with a carbazole-bridged chain. The dyes were characterized by 1HNMR and MS. The spectra of the novel dyes were also performed and the results showed that the maximum emission wavelength of the carbazole styryl cyanine dye was shifted red, the Stokes shift increased and the fluorescence intensity enhanced compared with those of YO and Cy3. These results indicated that the novel dye could be used as an excellent fluorescent probe in biological labeling. 相似文献
39.
Light chirp is a major issue in optical fiber links. This letter deals with precise characterizations of the frequency chirp parameters of reflective semiconductor optical amplifiers (RSOAs). The RSOA chirp properties are represented by transient and adiabatic chirps, whose parameters are characterized utilizing a ratio between the phase and the amplitude modulation depths of the RSOA when modulated with sine waves. Utilizing a high-resolution optical spectrum analyzer, a RSOA linewidth enhancement factor a and an adiabatic factork are obtained experimentally, based on which the influence of chirp parameters on the transmission performance of non-return-to-zero (NRZ) signals can be analyzed. 相似文献
40.
The direct observation and rotational analysis of the (3, 6) band in the comet-tail (A2Πi-X2Σ+) system of CO+ are carried out for the first time employing optical heterodyne and magnetic rotation enhanced velocity modulation spectroscopy. That 193 lines are assigned to this band ranging from 12 100 to 12 370 cm−1 results in most accurate molecular constants by nonlinear least-squares fitting procedure employing the effective Hamiltonians. 相似文献