全文获取类型
收费全文 | 42820篇 |
免费 | 2299篇 |
国内免费 | 1600篇 |
专业分类
化学 | 20680篇 |
晶体学 | 436篇 |
力学 | 2187篇 |
综合类 | 79篇 |
数学 | 10663篇 |
物理学 | 12674篇 |
出版年
2023年 | 314篇 |
2022年 | 481篇 |
2021年 | 562篇 |
2020年 | 691篇 |
2019年 | 580篇 |
2018年 | 1680篇 |
2017年 | 1851篇 |
2016年 | 1379篇 |
2015年 | 1252篇 |
2014年 | 1188篇 |
2013年 | 1704篇 |
2012年 | 4319篇 |
2011年 | 3517篇 |
2010年 | 2605篇 |
2009年 | 2346篇 |
2008年 | 1492篇 |
2007年 | 1401篇 |
2006年 | 1307篇 |
2005年 | 5086篇 |
2004年 | 4391篇 |
2003年 | 2690篇 |
2002年 | 870篇 |
2001年 | 601篇 |
2000年 | 377篇 |
1999年 | 461篇 |
1998年 | 302篇 |
1997年 | 221篇 |
1996年 | 238篇 |
1995年 | 205篇 |
1994年 | 179篇 |
1993年 | 144篇 |
1992年 | 269篇 |
1991年 | 238篇 |
1990年 | 225篇 |
1989年 | 174篇 |
1988年 | 162篇 |
1987年 | 105篇 |
1986年 | 83篇 |
1985年 | 78篇 |
1984年 | 65篇 |
1983年 | 43篇 |
1981年 | 38篇 |
1976年 | 89篇 |
1975年 | 48篇 |
1974年 | 42篇 |
1973年 | 50篇 |
1972年 | 44篇 |
1970年 | 39篇 |
1969年 | 42篇 |
1966年 | 37篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
61.
Bahattin Gümgüm Nermin Biricik Feyyaz Durap Ismail Özdemir Nevin Gürbüz Wee Han Ang Paul J. Dyson 《应用有机金属化学》2007,21(8):711-715
Palladium(II) complexes with N,N‐bis(diphenylphosphino)aniline ligands catalyse the Heck reaction between styrene and aryl bromides, affording stilbenes in good yield. The structures of two of the complexes used as pre‐catalysts have been determined by single‐crystal X‐ray diffraction. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
62.
This paper establishes a link between a generalized matrix Matsumoto-Yor (MY) property and the Wishart distribution. This link highlights certain conditional independence properties within blocks of the Wishart and leads to a new characterization of the Wishart distribution similar to the one recently obtained by Geiger and Heckerman but involving independences for only three pairs of block partitionings of the random matrix.In the process, we obtain two other main results. The first one is an extension of the MY independence property to random matrices of different dimensions. The second result is its converse. It extends previous characterizations of the matrix generalized inverse Gaussian and Wishart seen as a couple of distributions.We present two proofs for the generalized MY property. The first proof relies on a new version of Herz's identity for Bessel functions of matrix arguments. The second proof uses a representation of the MY property through the structure of the Wishart. 相似文献
63.
Daniel Pa?ca 《Journal of Mathematical Analysis and Applications》2007,325(1):90-100
Some existence results are obtained for periodic solutions of nonautonomous second-order differential inclusions systems with p-Laplacian. 相似文献
64.
Goran Pavi? 《Applied Acoustics》2006,67(9):864-881
A method is formulated for the identification of an unknown physical parameter of a fluid-filled pipe using the measurement of sound speed in the pipe. The method uses a simple formula which provides the relationship between the sound speed and a few physical parameters of the pipe: thickness, diameter, wall material constants and fluid constants. Once the sound speed in the pipe is measured, the simple formula can be used to extract one of the unknown parameters providing the remaining ones are known.The sound speed in the pipe is measured using a 3-transducer array. In order to demonstrate the potential of the technique the results of several measurements obtained in a water-filled steel pipe are presented.The required accuracy of the measurement of sound speed and of the specification of known parameters is analysed. The accuracy depends on the unknown parameter which is to be identified. For example, if the pipe thickness is the unknown parameter, the other parameters have to be known within a very narrow margin of error. On the contrary, if the fluid properties have to be identified the needed accuracy of known parameters gets much lower. 相似文献
65.
Temperature effects on deposition rate of silicon nitride films were characterized by building a neural network prediction model. The silicon nitride films were deposited by using a plasma enhanced chemical vapor deposition system and process parameter effects were systematically characterized by 26−1 fractional factorial experiment. The process parameters involved include a radio frequency power, pressure, temperature, SiH4, N2, and NH3 flow rates. The prediction performance of generalized regression neural network was drastically improved by optimizing multi-valued training factors using a genetic algorithm. Several 3D plots were generated to investigate parameter effects at various temperatures. Predicted variations were experimentally validated. The temperature effect on the deposition rate was a complex function of parameters but N2 flow rate. Larger decreases in the deposition rate with the temperature were only noticed at lower SiH4 (or higher NH3) flow rates. Typical effects of SiH4 or NH3 flow rate were only observed at higher or lower temperatures. A comparison with the refractive index model facilitated a selective choice of either SiH4 or NH3 for process optimization. 相似文献
66.
A tree T is arbitrarily vertex decomposable if for any sequence τ of positive integers adding up to the order of T there is a sequence of vertex-disjoint subtrees of T whose orders are given by τ. An on-line version of the problem of characterizing arbitrarily vertex decomposable trees is completely solved here. 相似文献
67.
研制了一台五通道ROSS-FILTER-PIN软X射线能谱仪,能谱范围为0.28—1.56keV.它由5个连续能段组成,每个能段的起止边由罗斯滤片对(ROSS-FILTERS)的L或K吸收边确定.罗斯滤片对的厚度通过优化计算得到,为了使每个通道的灵敏区外响应(即所测能段外响应)与通道总响应之比最小,在滤片对的第二滤片上镀上了一定厚度的第一滤片材料;为了缩减滤片表面积以增强低能滤片的抗冲击能力及方便滤片加工,能谱仪采用了小探测面积的PIN探测器(1mm2).借助此能谱仪,测量得到了喷气式Z箍缩(Z-pinch)等离子体辐射软X射线能谱的分布,并研究了软X射线产额随箍缩状况的变化趋势.
关键词:
Z箍缩等离子体
罗斯滤片
软X射线能谱 相似文献
68.
Improved sample wettability was obtained by oxygen plasma functionalization of pyrolytic graphite. The samples were exposed to highly dissociated oxygen plasma with the density of 1 × 1016 m−3, the electron temperature of about 5.5 eV and the density of neutral oxygen atoms of 8 × 1021 m−3 for 20 s. The surface wettability was measured by a contact angle of water drop. The contact angle dropped from original 112° down to about 1°. The functional groups were detected by XPS analyses. The survey spectrum showed a substantial increase of oxygen concentration on the surface, while high-resolution analyses showed additional oxygen was bonded onto the graphite surface in the form of C-O polar functional group responsible for the increase of the surface energy. 相似文献
69.
Recently, molecular imaging has been rapidly developed to studyphysiological and pathological processes in vivo at the cellularand molecular levels. Among molecular imaging modalities, opticalimaging has attracted a major attention for its unique advantages.In this paper, we establish a mathematical framework for multispectralbioluminescence tomography (BLT) that allows simultaneous studiesof multiple optical reporters. We show solution existence, uniquenessand continuous dependence on data as well as the limiting behaviourswhen the regularization parameter approaches zero or when thepenalty parameter approaches infinity. Then, we propose twonumerical schemes for multispectral BLT and derive error estimatesfor the corresponding solutions. 相似文献
70.
Kj?rand Iversen Per Nilsson 《International Journal of Computers for Mathematical Learning》2007,12(2):113-133
This paper focuses on the different ways in which students in lower secondary school (14–16 year olds) experience compound
random events, presented to them in the form of combined junctions. A carefully designed ICT environment was developed enabling
the students to interact with different representations of such structures. Data for the analysis was gathered from two interview
sessions. The analysis of the interaction is based on constructivist principles on learning; i.e. we adopted a student-oriented
perspective, taking into consideration the different ways students try to make sense of chance encounters.
Our results show how some students give priority to geometrical and physical concerns, and we discuss how seeking causal explanations
of random phenomena may have encouraged this. With respect to numerically oriented models a division strategy appears to stand
out as the preferred one. 相似文献