Optimized growth and dielectric properties of barium titanate thin films on polycrystalline Ni foils

Barium titanate(BTO) thin films were deposited on polycrystalline Ni foils by using the polymer assisted deposition(PAD) technique.The growth conditions including ambient and annealing temperatures were carefully optimized based on thermal dynamic analysis to control the oxidation processing and interdiffusion.Crystal structures,surface morphologies,and dielectric performance were examined and compared for BTO thin films annealed under different temperatures.Correlations between the fabrication conditions,microstructures,and dielectric properties were discussed.BTO thin films fabricated under the optimized conditions show good crystalline structure and promising dielectric properties with εr～ 400 and tan δ < 0.025 at 100 kHz.The data demonstrate that BTO films grown on polycrystalline Ni substrates by PAD are promising in device applications.     

Tunable structural color of anodic tantalum oxide films

Tantalum(Ta) oxide films with tunable structural color were fabricated easily using anodic oxidation.The structure,components,and surface valence states of the oxide films were investigated by using gazing incidence X-ray diffractometry,X-ray photoelectron microscopy,and surface analytical techniques.Their thickness and optical properties were studied by using spectroscopic ellipsometry and total reflectance spectrum.Color was accurately defined using L*a*b* scale.The thickness of compact Ta2O5 films was linearly dependent on anodizing voltage.The film color was tunable by adjusting the anodic voltage.The difference in color appearance resulted from the interference behavior between the interfaces of air-oxide and oxide-metal.     

窄带傅里叶变换光谱仪中平稳高斯噪声的理论分析

在本文所研究的空间调制型傅里叶变换光谱仪中, 在窄的光谱带宽内进行探测可以有效提高光谱的分辨率. 为了研究光源辐射噪声对系统的影响, 本文将辐射噪声归纳为一种高斯窄带的平稳随机过程, 利用线性系统分析方法, 根据统计学原理推导了辐射噪声作为随机变量通过干涉系统前后的输入信噪比与输出信噪比. 然后, 对于一个具有窄带矩形光谱的系统进行了计算仿真, 得出了信噪比增益随着光程差在不同自相关度和互相关度取值时的变化情况. 仿真结果表明, 不同光程差下的信噪比增益在相关度空间是一单调的平滑曲面, 增益极值始终沿着相关度圆的半径和周线移动, 并且经过一个光程差又回到初始的位置. 根据对信噪比增益的分析, 可以将噪声的相关度取值控制在某一范围之内, 并作为系统光源设计与测试的依据.     

不同激发波长对Sr3Al2O6∶Eu2+,Dy3+红色长余辉发光材料发射光谱的影响

采用高温固相法合成了Sr3Al2O6∶Eu2+,Dy3+长余辉发光材料。用X射线衍射仪及荧光分光光度计对材料物相及光谱性能进行了分析。结果表明:所得样品为Sr3Al2O6的纯相,在360nm波长的激发下,得到波峰为537nm的宽带发射光谱;在468nm波长的激发下,得到波峰为590nm的宽带发射光谱;在波长为394nm的激发下,537和590nm的峰同时出现。根据晶格场效应和电子云膨胀效应,对不同激发波长对Sr3Al2O6∶Eu2+,Dy3+发射光谱的影响进行了解释。结果表明:在Sr3Al2O6∶Eu2+,Dy3+中发光中心因其5d能级劈裂幅度不同及4f65d1能带重心不同而导致发光颜色的不同。     

氢化物发生—原子荧光法测定不同产地绞股蓝及其根际土壤中As,Hg,Se

通过优化了的氢化物发生—原子荧光法测定了7个省产绞股蓝及其根际土壤中As,Hg,Se三种元素的含量,研究结果表明:7个省产绞股蓝中As,Hg,Se的含量存在较大差异,但As和Hg两种重金属元素含量均低于《药用植物及制剂进出口绿色行业标准》中As和Hg的限量标准。Se元素含量同根际土壤中Se元素含量显示极显著相关性,故湖北恩施富硒区产绞股蓝中Se含量明显高于其他6省产绞股蓝。研究结果可以初步判定,绞股蓝中Se元素主要来源于土壤,而As和Hg元素的积累则不同于Se元素,还可能受到大气气溶胶的干、湿沉降等因素的影响。     

Geometric phases in qubit-oscillator system beyond conventional rotating-wave approximation

In this work we investigated the geometric phases of a qubit-oscillator system beyond the conventional rotating- wave approximation. We find that in the limiting of weak coupling the results coincide with that obtained under rotating-wave approximation while there exists an increasing difference with the increase of coupling constant. It was shown that the geometric phase is symmetric with respect to the sign of the detuning of the quantized field from the one-photon resonance under the conventional rotating-wave approximation while a red-blue detuning asymmetry occurs beyond the conventional rotating-wave approximation.     

基于滑移网格与RNG湍流模型计算泵内的动静干扰

本文利用三维Navier-Stockes方程和RNG湍流模型,在转动与静止部件间采用滑移网格技术建立交互界面,对泵内动静干扰引起的三维非定常湍流进行了计算,得到了旋转叶轮与固定导叶间流体的湍流特征。从计算结果可知,静叶与动叶间各点的压力脉动频率成分一致,且幅值沿周向呈正弦变化规律。这说明利用滑移网格技术及RNG湍流模型,可以模拟三维非定常动静干扰流动问题。     

短波碲镉汞光伏器件的低频噪声研究

对所研制的短波光伏碲镉汞器件进行了变温电流-电压特性和低频噪声研究，测试温度范围255—293K.实验结果表明随着温度的下降，器件的优值因子R₀A从45×10³Ωcm²增加到7×10⁴Ωcm².器件在低频区的主要噪 声成分是1/f噪声和产生-复合噪声，在高频区主要是散粒噪声.在测试的偏压内，器件的1/f噪声功率谱密度与流过器件的电流的平方成正比，器件的Hooge系数为3×10^-4—7×10^-4.从噪声 功率谱密度曲线分析中得到产生-复合噪声的特征时间常数τ，通过τ的温度特性得到了器件的深能级. 关键词： 碲镉汞 优值因子 低频噪声 深能级     

Delocalized fermions in underdoped cuprate superconductors

Low-temperature heat transport was used to investigate the ground state of high-purity single crystals of the lightly doped cuprate YBa2Cu3O6.33. Samples were measured with doping concentrations on either side of the superconducting phase boundary. We report the observation of delocalized fermionic excitations at zero energy in the nonsuperconducting state, which shows that the ground state of underdoped cuprates is a thermal metal. Its low-energy spectrum appears to be similar to that of the d-wave superconductor, i.e., nodal. The insulating ground state observed in underdoped La2-xSrxCuO4 is attributed to the competing spin-density-wave order.     

Critical point and the nature of the pseudogap of single-layered copper-oxide Bi2Sr2-xLaxCuO6+delta superconductors

We apply strong magnetic fields of H=28.5 to 43 T to suppress superconductivity (SC) in the cuprates Bi2Sr2-xLaxCuO6+delta (x=0.65, 0.40, 0.25, 0.15, and 0), and investigate the low temperature (T) normal state by 63Cu nuclear spin-lattice relaxation rate (1/T1) measurements. We find that the pseudogap (PG) phase persists deep inside the overdoped region but terminates at x approximately 0.05, which corresponds to the hole doping concentration of approximately 0.21. Beyond this critical point, the normal state is a Fermi liquid that persists as the ground state when superconductivity is removed by the magnetic field. A comparison of the superconducting state with the H-induced normal state in the x=0.40 (Tc=32 K) sample indicates that there remains substantial part of the Fermi surface even in the fully developed PG state, which suggests that the PG and SC are coexisting matters.