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Two stable supramolecular loops (1 and 2) were successfully constructed by the molecular recognition of cucurbit[8]uril (CB[8]) and the homoditopic bispyridinium derivatives (3 and 4). Interestingly, the interconversion of molecular loops and [2]pseudorotaxanes could be reversibly switched under neutral and acidic condition, exhibiting the controlled electrochemical and spectroscopic behaviors. 相似文献
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A convenient one-pot Mannich-type-cyclization-oxidation tandem process has been developed for the synthesis of 1,3,5-trisubstituted pyrazoles derivatives from aldehydes, hydrazines and alkynes using p-toluenesulfonic acid monohydrate (PTSA) as a multifunctional catalyst. This method provides a flexible and rapid route to 1,3,5-trisubstituted pyrazoles. 相似文献
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闭路循环动态针捕集-气相色谱法分析地下水中的硝基苯和苯胺 总被引:1,自引:0,他引:1
动态针捕集(Needle trap,NT)是一种集采样、提取、浓缩、进样于一体的免溶剂分析技术,适于痕量有机目标组分的采样分析.本研究通过对比6种采样技术,研究了基于超声的闭路循环动态顶空-NT分析地下水中的硝基苯及苯胺的方法,确定了NT对地下水目标物顶空采样的最佳条件;通过对比GC普通分流/不分流进样口和一种多模式OPTIC2进样口,优化NT的解吸条件,得出的OPTIC2进样口对目标物响应值高且峰形尖锐.填充一层吸附剂的NT对目标物的残留低于0.79%,苯胺的检出限为2.9~3.7μg/L,硝基苯的检出限为0.7~1.9 μg/L.苯胺和硝基苯的回收率在83%~113%之间. 相似文献
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Yang Y Zhang YM Chen Y Zhao D Chen JT Liu Y 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(14):4208-4215
A multiple supramolecular assembly, in which a folic acid-modified β-cyclodextrin (1) acted as a target unit, an adamantanyl porphyrin (2) acted as a linker unit, and graphene oxide acted as a carrier unit, was successfully fabricated through non-covalent interactions and comprehensively investigated by means of UV/Vis, fluorescence, and X-ray photoelectron spectroscopies, and electron microscopy. Significantly, the graphene oxide unit could associate with the anticancer drug doxorubicin through π-π interactions, and the folic acid-modified β-cyclodextrin unit could recognize the folic acid receptors in cancer cells. Owing to the cooperative contribution of these three units, the resulting multiple supramolecular assembly, after association with doxorubicin, exhibited better drug activity and much lower toxicity than free doxorubicin in vivo. 相似文献
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Seeing time-reversal transmission characteristics through kinetic anti-ferromagnetic Ising chain 下载免费PDF全文
As an example of our new approach to complex near-field (NF) scattering of electromagnetic waves, the time-reversal (TR) transmission process on an NF current-element array is mapped to the statistical process on a kinetic Ising transmission chain. Equilibrium statistical mechanics and non-equilibrium Monte Carlo (MC) dynamics help us to find signal jamming, aging, annihilating, creating, and TR symmetry breaking on the chain with inevitable background noises; and these results are general in NF systems where complex electromagnetic scattering arises. 相似文献
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A new data envelopment analysis method for priority determination and group decision making in the analytic hierarchy process 总被引:1,自引:0,他引:1
The DEAHP method for weight deviation and aggregation in the analytic hierarchy process (AHP) has been found flawed and sometimes produces counterintuitive priority vectors for inconsistent pairwise comparison matrices, which makes its application very restrictive. This paper proposes a new data envelopment analysis (DEA) method for priority determination in the AHP and extends it to the group AHP situation. In this new DEA methodology, two specially constructed DEA models that differ from the DEAHP model are used to derive the best local priorities from a pairwise comparison matrix or a group of pairwise comparison matrices no matter whether they are perfectly consistent or inconsistent. The new DEA method produces true weights for perfectly consistent pairwise comparison matrices and the best local priorities that are logical and consistent with decision makers (DMs)’ subjective judgments for inconsistent pairwise comparison matrices. In hierarchical structures, the new DEA method utilizes the simple additive weighting (SAW) method for aggregation of the best local priorities without the need of normalization. Numerical examples are examined throughout the paper to show the advantages of the new DEA methodology and its potential applications in both the AHP and group decision making. 相似文献
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Transformation fieM method (TFM) is developed to estimate the anisotropic dielectric properties of crystal composites having arbitrary shapes and dielectric properties of crystal inclusions, whose principal dielectric axis are different from those of anisotropic crystal matrix. The complicated boundary-value problem caused by inclusion shapes is circumvented by introducing a transformation electric field into the crystal composites regions, and the effective anisotropic dielectric responses are formulated in terms of the transformation field. Furthermore, the numerical results show that the effective anisotropie dielectric responses of crystal composites periodically vary as a function of the rotating angle between the principal dielectric axes of inclusion and matrix crystal materials. It is found that at larger inclusion volume fraction the inclusion shapes induce profound effect on the effective anisotropic dielectric responses. 相似文献
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