环境对MgB_2氧化过程中MgO晶须生长形状的影响

用扫描电镜研究了在 Mg B2 氧化过程中环境对 Mg O晶须生长形状的影响。仅有 Mg B2 时 ,在 80 0℃左右空气气氛中 ,可生长出纳米尺寸的 Mg O晶须。若把 Mg B2 添加到氧化铝陶瓷基体中 ,则生长成竹节状晶须。Mg O晶须生长形状的差别可能是由于氧浓度以及位错等因素造成的。     

Mid-infrared generation based on a periodically poled LiNbO3 optical parametric oscillator

We report a nanosecond Nd:YVO_4-pumped optical parametric oscillator (OPO) based on periodically poled LiNbO_3 (PPLN). Tuning is achieved in this experiment by varying the temperature and period of the PPLN. The design of double-pass singly resonant oscillator (DSRO) and confocal cavity enables the OPO threshold to be lowered considerably, resulting in a simple, compact, all-solid-state configuration with the mid-infrared idler powers of up to 466mW at 3.41μm.     

2,9-disubstituted 1,10-phenanthroline nickel complexes: Syntheses,characterization, and their ethylene oligomerization

Nickel complexes 1–4 ligated with 2,9-disubstituted-1,10-phenanthroline were synthesized and characterized by FT-IR spectra and elemental analysis. The molecular structure of complex 2 was confirmed by X-ray crystal diffraction analysis. Activated with methylaluminoxane (MAO), those complexes showed moderate activities for ethylene oligomerization. Published in Kinetika i Kataliz, 2007, Vol. 48, No. 5, pp. 710–714. This article was submitted by the authors in English.     

一种改进的进化规划算法

本对于全局优化问题提出一个改进的进化规划算法，该算法以概率p接收基于电磁理论求出合力方向作为随机搜索方向，以概率1-p接收按正态分布产生的随机搜索方向。改进算法不仅克服了传统进化规划算法随机搜索的盲目性，而且保留了传统进化规划算法全局搜索性。本算法应用于几个典型例题，数值结果表明本算法是可行的，有效的。     

负载型CO3[Fe（CN）6]2及CN^—加氢反应的研究

双金属催化剂是一类重要的多相催化剂。其中d电子在催化活性方面起着重要的作用.本文在Co_3[Fe(CN)_6]_2的工作基础上,进一步研究了该配合物在硅胶、氧化铝、以及氧化镁上的热性质,同时考察了CN~-在Co-Fe体系双端基配位的活化加氢,探讨了载体的影响.     

非完整约束奇异广义力学系统的Poincaré-Cartan积分

对受高阶微商非完整约束并用奇异Lagrange量描述的广义力学系 统，基于广义Apell-Четаев约束条件，并考虑到系统的内在约束，导出了该非完整 约 束奇异广义力学系统的广义Poincaré-Cartan积分不变量. 并证明了该不变量与非完整约束 奇异广义力学系统的广义正则方程等价.     

A novel methodology for the synthesis of 1-desoxy-Δ-tetrahydrocannabinol (THC) analogues

A versatile and efficient sequence was developed for the synthesis of 1-desoxy-Δ⁸-THC analogues and is demonstrated by the synthesis of sulfonamide analogues with an acetylene group at the C-2^′ position in the side chain. In this procedure the 1-desoxy-Δ⁸- THC ring structure is built first and the synthesis of the side chain is then developed.     

Sorption of Zn(II) and Cd(II) by chelating resins: Comparison of three resins

Ion-exchange resins, especially chelating resins are used for pre-concentration of metal ions in trace analysis as well as for radiochemical separations following neutron activation of a variety of environmental samples. As part of a systematic study of the sorption characteristics of chelating resins, sorption of Zn(II) and Cd(II) by three chelating resins were studied for various acid conditions in nitrate and chloride media. Both Zn(II) and Cd(II) showed similar behavior. Under higher acid conditions, maximum sorption occurred in 3M HCl solutions. Under low acid conditions, the sorption increased with pH. Chelex 100 gave the highest sorption among the three resins. This revised version was published online in July 2006 with corrections to the Cover Date.