Crystallographic report: Bis[bis(N,N‐dibenzyldithiocarbamato)cadmium(II)]

The centrosymmetric structure of {Cd[S₂CN(CH₂Ph)₂]₂}₂ features both bridging and chelating dithiocarbamate ligands so that a square pyramidal S₅ coordination geometry results. Copyright © 2004 John Wiley & Sons, Ltd.     

The influence of hard‐segments on two‐phase structure and shape memory properties of PCL‐based segmented polyurethanes

Poly(ε‐caprolactone)‐based segmented polyurethanes (PCLUs) were prepared from poly(ε‐caprolactone) diol, diisocyanates (DI), and 1,4‐butanediol. The DIs used were 4,4′‐diphenylmethane diisocyanate (MDI), 2,4‐toluenediisocyanate (TDI), isophorone diisocyanate (IPDI), and hexamethylene diisocyanate (HDI). Differential scanning calorimetry, small‐angle X‐ray scattering, and dynamic mechanical analysis were employed to characterize the two‐phase structures of all PCLUs. It was found that HDI‐ and MDI‐based PCLUs had higher degree of microphase separation than did IPDI‐ and TDI‐based PCLUs, which was primarily due to the crystallization of HDI‐ and MDI‐based hard‐segments. As a result, the HDI‐based PCLU exhibited the highest recovery force up to 6 MPa and slowest stress relaxation with increasing temperature. Besides, it was found that the partial damage in hard‐segment domains during the sample deformation was responsible for the incomplete shape‐recovery of PCLUs after the first deformation, but the damage did not develop during the subsequent deformation. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 557–570, 2007     

Crystallographic report: Crystal structure of tetra(4‐methyl‐5‐imidazole‐carboxyaldehyde)zinc(II) diperchlorate

The central zinc(II) atom in the title complex is tetrahedrally coordinated by four nitrogen atoms derived from 4‐methyl‐5‐imidazolecarboxyaldehyde ligands with Zn? N in the range 2.007(3) to 2.026(4) Å. Copyright © 2003 John Wiley & Sons, Ltd.     

Operating Parameters Optimization of Buffer Gas in Optically Pumped Submillimeter Wave Laser

Based on the basic theory of molecular vibration relaxation and semi-classical density matrix theory, operating parameters optimization of buffer gas in the process of miniature pulsed optically pumped submillimeter wave laser was systemically studied and the theoretical calculated result was tested by experiments. The result would do favor to develop and study high-power and wide-range tunable miniature and high-efficient pulsed optically pumped submillimeter wave laser and also had some instruction to its application.     

暗中空光束角动量与中性原子的相互作用及其应用

综述了暗中空光束自旋与轨道角动量的一些性质及其与中性原子之间的相互作用,并简单介绍了暗中空光束及其角动量在原子光学和玻色_爱因斯坦凝聚(BEC)以及各种原子光学器件研制方面的应用.     

Miniature InGaAsP/InP phase modulator for integrated opto-electronics

Miniature, etching ridge InGaAsP/InP Phase Modulator with highly efficient phase shifting efficiency of 60°/V.mm and 43°/V.mm for TE and TM modes, respectively, and 3 dB bandwidth of 650 MHz at 1.52 μm are reported. It is well suited for integrated opto-electronics. Some functions depending on bandwidth of the devices are discussed.     

THE COMRENSATED COMPACTNESS METHOD APPLIED TO QUASILINEAR PARABOLIC EQUATIONS OF HIGHER ORDER WITH BOUBLY STRONG DEGENERATION

This paper applies the compensated compactnessmethod to the study of a class of quasilinear parbolic equations of higher order with doubly strong degeneration. Some existence and uniqueness results are proved under certain conditions.     

一个包含Smarandache函数的方程

对于任意正整数n,我们用S(n)表示Smarandache函数,即S(n)=min{m:n|m!}.本文的主要目的是运用初等方法研究方程∑_(d|n)S(d)=n的可解性,并给出它的所有正整数解.     

Synthesis of cellulose carbamate by supercritical CO2-assisted impregnation: Structure and rheological properties

Cellulose carbamate, an environmentally friendly material presents an interesting alternative to petroleum-based polymers because of its renewable, biodegradable, biocompatible nature and its solubility in conventional solvents. In synthesis process of cellulose carbamate, urea was firstly impregnated into the cellulose pulp by supercritical CO₂(scCO₂), followed by the esterification of cellulose. The structure of cellulose carbamate was characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The rheological properties of these cellulose carbamates in 9% sodium hydroxide solution were investigated, using a range of the nitrogen content, concentrations and shear rates.     

高密度氩气的原子间相互作用与状态方程

本文从高密度气体的原子间相互作用出发进行思考,在修改范德瓦耳方程的基础上,提出了一种新的适用于高密度气体的状态方程,并用以对氩气临界区的等温压缩线进行计算,结果与实验值很符合.