全文获取类型
收费全文 | 204篇 |
免费 | 17篇 |
专业分类
化学 | 154篇 |
晶体学 | 1篇 |
力学 | 8篇 |
数学 | 10篇 |
物理学 | 48篇 |
出版年
2023年 | 2篇 |
2022年 | 8篇 |
2021年 | 4篇 |
2020年 | 7篇 |
2019年 | 7篇 |
2018年 | 4篇 |
2017年 | 2篇 |
2016年 | 9篇 |
2015年 | 3篇 |
2014年 | 15篇 |
2013年 | 14篇 |
2012年 | 17篇 |
2011年 | 13篇 |
2010年 | 8篇 |
2009年 | 7篇 |
2008年 | 11篇 |
2007年 | 9篇 |
2006年 | 11篇 |
2005年 | 14篇 |
2004年 | 15篇 |
2003年 | 4篇 |
2002年 | 7篇 |
2001年 | 2篇 |
2000年 | 9篇 |
1999年 | 4篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有221条查询结果,搜索用时 31 毫秒
31.
Sonochemical degradation of dilute aqueous solutions of 2-, 3- and 4-chlorophenol and pentachlorophenol has been investigated under air or argon atmosphere. The degradation follows first-order kinetics in the initial state with rates in the range 4.5-6.6 microM min-1 under air and 6.0-7.2 microM min-1 under argon at a concentration of 100 microM of chlorophenols. The rate of OH radical formation from water is 19.8 microM min-1 under argon and 14.7 microM min-1 under air in the same sonolysis conditions. The sonolysis of chlorophenols is effectively inhibited, but not completely, by the addition of t-BuOH, which is known to be an efficient OH radical scavenger in aqueous sonolysis. This suggests that the main degradation of chlorophenols proceeds via reaction with OH radicals; a thermal reaction also occurs, although its contribution is small. The addition of appropriate amounts of Fe(II) ions accelerates the degradation. This is probably due to the regeneration of OH radicals from hydrogen peroxide, which would be formed from recombination of OH radicals and which may contribute a little to the degradation. The ability to inhibit bacterial multiplication of pentachlorophenol decreases with ultrasonic irradiation. 相似文献
32.
C.I. Calle P.J. Mackey M.D. Hogue M.R. Johansen H. Yim P.B. Delaune J.S. Clements 《Journal of Electrostatics》2013,71(3):257-259
Electrodynamic Dust Shields (EDS) have been in development at NASA as a dust mitigation method for lunar and Martian missions. An active dust mitigation strategy, such as that provided by the EDS, that can remove dust from surfaces, is of crucial importance to the planetary exploration program. We report on the development of a flight experiment to fully expose four EDS panels to the space environment. This flight experiment is part of the Materials International Space Station experiment X (MISSE-X), an external platform on the International Space Station that will expose materials to the space environment. 相似文献
33.
AbstractIn the course of our continuing investigation of bioactive secondary metabolites from marine-derived fungal strains, a racemate of a novel diphenolic derivative named (±)-tylopilusin D (1) along with ten previously known secondary metabolites (2–11) were isolated from a marine-derived fungal strain Aspergillus sp. SF-5929. Their structures were elucidated mainly by analysis of NMR and MS data. In addition, the inhibitory effects of the isolated compounds against protein tyrosine phosphatase 1B (PTP1B) activity were evaluated, and compounds 1, 2, and 5–7 inhibited PTP1B activity with IC50 values ranging from 3.3 to 8.1?µM. Kinetics studies suggested that compounds 1, 2, and 5 had noncompetitive inhibitory effects against PTP1B. 相似文献
34.
35.
Plasmonic Hotspots in Air: An Omnidirectional Three‐Dimensional Platform for Stand‐Off In‐Air SERS Sensing of Airborne Species
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Gia Chuong Phan‐Quang Dr. Hiang Kwee Lee Hao Wen Teng Charlynn Sher Lin Koh Barnabas Qinwei Yim Dr. Eddie Khay Ming Tan Wee Lee Tok Dr. In Yee Phang Prof. Dr. Xing Yi Ling 《Angewandte Chemie (International ed. in English)》2018,57(20):5792-5796
Molecular‐level airborne sensing is critical for early prevention of disasters, diseases, and terrorism. Currently, most 2D surface‐enhanced Raman spectroscopy (SERS) substrates used for air sensing have only one functional surface and exhibit poor SERS‐active depth. “Aerosolized plasmonic colloidosomes” (APCs) are introduced as airborne plasmonic hotspots for direct in‐air SERS measurements. APCs function as a macroscale 3D and omnidirectional plasmonic cloud that receives laser irradiation and emits signals in all directions. Importantly, it brings about an effective plasmonic hotspot in a length scale of approximately 2.3 cm, which affords 100‐fold higher tolerance to laser misalignment along the z‐axis compared with 2D SERS substrates. APCs exhibit an extraordinary omnidirectional property and demonstrate consistent SERS performance that is independent of the laser and analyte introductory pathway. Furthermore, the first in‐air SERS detection is demonstrated in stand‐off conditions at a distance of 200 cm, highlighting the applicability of 3D omnidirectional plasmonic clouds for remote airborne sensing in threatening or inaccessible areas. 相似文献
36.
A reliable multiplex assay procedure to detect human genetic mutations in the breast cancer susceptibility gene BRCA1 using zip-code microarrays and single base extension (SBE) reactions is described. Multiplex PCR amplification was performed
to amplify the genomic regions containing the mutation sites. The PCR products were then employed as templates in subsequent
multiplex SBE reactions using bifunctional primers carrying a unique complementary zip sequence in addition to a mutation-site-specific
sequence. The SBE primers, terminating one base before their mutation sites, were extended by a single base at a mutation
site with a corresponding biotin-labeled ddNTP. Hybridization of the SBE products to zip-code microarrays was followed by
staining with streptavidin–Cy3, leading to successful genotyping of several selected BRCA1 mutation sites with wild-type and heterozygote mutant samples from breast cancer patients. This work has led to the development
of a reliable DNA microarray-based system for the diagnosis of human genetic mutations.
Cheulhee Jung and Seong-Chun Yim contributed equally to this work. 相似文献
37.
Cho MH Kim CY Moon K Chung KB Yim CJ Ko DH Sohn HC Jeon H 《The Journal of chemical physics》2008,129(3):034705
Medium energy ion scattering and high-resolution transmission electron microscopy are used to investigate the depth of the interfacial reaction of Hf-silicate film. The interfacial reaction is critically affected by the film thickness and the mole fraction of HfO(2) in silicate film. The interfacial compressive strain generated at the surface of the Si substrate is dependent on the film thickness during the postannealing process in film with a thickness of approximately 4 nm. Finally, the phase separation phenomenon demonstrates critically different behaviors at different film thicknesses and stoichiometries because the diffusion of Si from interface to surface is dependent on these factors. Moreover, the oxidation by oxygen impurity in the inert ambient causes SiO(2) top formation. 相似文献
38.
Heong‐Seup Yim Ho‐Kyun Kim Jeum‐Jong Kim Deok‐Heon Kweon Yong‐Jin Yoon Sang‐Gyeong Lee Jung‐Ho Kim 《Journal of heterocyclic chemistry》2007,44(4):909-914
39.
MF Miller IA Franchi AS Sexton CT Pillinger 《Rapid communications in mass spectrometry : RCM》1999,13(13):1211-1217
The use of infrared laser-assisted fluorination to release oxygen from milligram quantities of silicates or other oxide mineral grains is a well-established technique. However, relatively few studies have reported the optimisation of this procedure for oxygen-17 isotope measurements. We describe here details of an analytical system using infrared (10 μm) laser-assisted fluorination, in conjunction with a dual inlet mass spectrometer of high resolving power ( approximately 250) to provide (17)O and (18)O oxygen isotope measurements from 0.5-2 mg of silicates or other oxide mineral grains. Respective precisions (1) of typically 0.08 and 0.04 per thousand are obtained for the complete analytical procedure. Departures from the mass-dependent oxygen isotope fractionation line are quantified by Delta(17)O; our precision (1) of such measurements on individual samples is shown to be +/-0.024 per thousand. In turn, this permits the offset between parallel, mass-dependent fractionation lines to be characterised to substantially greater precision than has been possible hitherto. Application of this system to investigate the (17)O versus (18)O relationship for numerous terrestrial whole-rock and mineral samples, of diverse geological origins and age, indicates that the complete data set may be described by a single, mass-dependent fractionation line of slope 0.5244+/- 0.00038 (standard error). Copyright 1999 John Wiley & Sons, Ltd. 相似文献
40.