Charmed meson production in quark exchange model

Dynamical calculations of charmed meson production rates (via quark exchange) are presented, replacing previous kinematic predictions. Agreement with recent data on the ratio of production rates for different two-charmed-meson final states is reached, and other features of the calculated rates are also discussed.     

Forced vibration of the pre-stressed bi-layered plate-strip with finite length resting on a rigid foundation

Within the scope of the piecewise homogeneous body model utilizing Three-Dimensional Linearized Theory of Elastic Waves in Initially Stressed Bodies the time-harmonic dynamical stress field in the pre-stressed bi-layered plate-strip with finite length resting on the rigid foundation is investigated. The materials of the layers are assumed to be isotropic. The FEM modeling is developed for the solution to the corresponding boundary-value-contact problem. The numerical results regarding the influence of the finiteness of the layers’ length on the stress distribution on the interface planes are presented and discussed. In particular, it is shown that with increasing the plate length the results obtained for the considered case approach to the corresponding ones attained for the bi-layered plate with infinite length.     

The NH---FC dipole orientation effect for pendant exocyclic CH(2)F

[structure: see text] DFT and MMFF force field calculations for 2 (R = H) predict that two conformers dominate in water (>/=95%) and both sustain a geometry in which the C-F and H-N dipoles align oppositely in a near-planar arrangement. The (1)H NMR spectra (D(2)O and DMSO-d(6)) and X-ray structure for 2 (R = SO(2)NHEt) confirm the predictions in all essentials. A novel single-conformer system is proposed.     

The effect of the proton on electropolymerization of the thiophene

Electropolymerization of thiophene was investigated in neutral and acidic medium from the standpoint of film formation and conductivity. Results obtained from voltammetric investigations have shown that proton affects both the electropolymerization of thiophene and its conductivity. This effect was explained by theoretical calculations using molecular mechanic (MM+, MM2) and semi-empirical (AM1) methods. From these calculations, it is seen that proton is significantly important in the stabilization and growth of the polymer. Proton is added to the sulfur atom in the polymer, which has a basic character because of its lone-pair electrons. With the addition of proton, the effect of the lone-pair electrons to the delocalization existing in the ring and the contribution to the conductivity of polythiophene is removed. Thus, the conjugation in the ring is reduced to the π-system in carbon skeleton and the structure of the protonated polythiophene resembles to that of polyacetylene.     

Quantum theory of longitudinal dielectric response properties of a two-dimensional plasma in a magnetic field

An analysis of dynamic and nonlocal longitudinal dielectric response properties of a two-dimensional Landau-quantized plasma is carried out, using a thermodynamic Green's function formulation of the RPA with a two-dimensional thermal Green's function for electron propagation in a magnetic field developed in closed form. The longitudinal-electrostatic plasmon dispersion relation is discussed in the low wavenumber regime with nonlocal corrections, and Bernstein mode structure is studied for arbitrary wavenumber. All regimes of magnetic field strength and statistics are investigated. The class of integrals treated here should have broad applicability in other two-dimensional and finite slab plasma studies.The two-dimensional static shielding law in a magnetic field is analyzed for low wavenumber, and for large distances we find $\text{V(}\text{r}\text{) ～}\text{Q}\text{k}{}_0{}^2\text{r}{}^3$. The inverse screening length $\text{k}{}_0\text{=}\text{2πe}{}^2\text{??}\text{?ξ}$ (? = density, ξ = chemical potential) is evaluated in all regimes of magnetic field strength and all statistical regimes. k₀ exhibits violent DHVA oscillatory behavior in the degenerate zero-temperature case at higher field strengths, and the shielding is complete when $\text{ξ = r′}\text{l}\text{z.shtsls;}\text{ω}$, but there is no shielding when $\text{ξ ≠ r′}\text{l}\text{z.shtsls;}\text{ω}{}_{\mathrm{c}}$. A careful analysis confirms that there is no shielding at large distances in the degenerate quantum strong field limit $\text{l}\text{z.shtsls;}\text{ω}{}_{\mathrm{c}}\text{> ξ}$. Since shielding does persist in the nondegenerate quantum strong field limit $\text{l}\text{z.shtsls;}\text{ω}{}_{\mathrm{c}}\text{> KT}$, there should be a pronounced change in physical properties that depend on shielding if the system is driven through a high field statistical transition. (It should be noted that the static shielding law of semiclassical and classical models has no dependence on magnetic field in two dimensions, as in three dimensions.) Finally, we find that the zero field two-dimensional Freidel-Kohn “wiggle” static shielding phenomenon is destroyed by the dispersal of the zero field continuum of electron states into the discrete set of Landau-quantized orbitals due to the imposition of the magnetic field.     

A stability estimate for an elliptic problem

We investigate the Caucy problem for linear elliptic operators withC ^∞-coefficients at a regular domain ℝ ⊂ ℝ, which is a classical example of an ill-posed problem. The Cauchy data are given at the manifold Γ⊂∂Ω and our goal is to obtain a stability estimate inH ₄(Ω).     

Synthesis and potent antimicrobial activity of some novel N-(alkyl)-2-phenyl-1H-benzimidazole-5-carboxamidines

A series of 22 novel 1,2-disubstituted-1H-benzimidazole-N-alkylated-5- carboxamidine derivatives were synthesized and evaluated for in vitro antibacterial activity against S. aureus and methicillin resistant S. aureus (MRSA), E. coli, E. faecalis and for antifungal activity against C. albicans. Compound 59 [1-(2,4-dichlorobenzyl)-N- (2-diethylaminoethyl)-1H-benzimidazole-5-carboxamidine], with a 3,4-dichlorophenyl group at the C-2 position, displayed the greatest activity (MIC = 3.12 microg/mL against both some bacteria and the fungus C. albicans).     

Convenient one-pot formation of highly functionalized 5-bromo-2-aminothiazoles,potential endocannabinoid hydrolase MAGL inhibitors

Highly functionalized 5-bromo-2-amino-1,3-thiazoles bearing various substituents could be easily prepared by a rapid and efficient one-pot method, using simple starting materials and mild conditions while avoiding the use of metal catalysts or inconvenient reagents such as elemental halogens. These useful products can serve as starting materials for other reactions or as pharmacologically interesting compounds. In our work we have shown that the resulting 5-bromothiazole compounds could lead to monoacylglycerol lipase (MAGL) inhibition in the μM range.     

Synthesis,photophysics, and photochemistry of peripherally Schiff base-zinc complex substituted zinc phthalocyanine

The content of this work is based on the introduction of the salicylhydrazone-zinc complexes into the phthalocyanine core. The reaction of the salicylhydrazone substituted ZnPc (1) with the related zinc(II) salt in basic conditions in DMF yielded bis[bis(salicyhydrazone)phenoxy)zinc(II)] phthalocyaninato zinc(II) (5) in which two salicylhydrazone-Zn complexes are linked through oxygen bridges to the macrocyclic core as three-nuclear complex. The novel compound synthesized in this study was fully characterized by general spectroscopic techniques such as FT-IR, UV-vis, ¹H NMR, ¹³C NMR, elemental analysis and mass spectroscopy. In addition, spectral, photophysical (fluorescence quantum yields), and photochemical (generation of singlet oxygen and photo stability under light irradiation) properties of newly synthesized phthalocyanine (5) and the starting Pcs molecules used to obtain this molecule were investigated in DMSO solutions, comparatively.